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131.
132.
Isotope fractionation during the evaporation of silicate melt and condensation of vapor has been widely used to explain various isotope signals observed in lunar soils, cosmic spherules, calcium–aluminum-rich inclusions, and bulk compositions of planetary materials. During evaporation and condensation, the equilibrium isotope fractionation factor (α) between high-temperature silicate melt and vapor is a fundamental parameter that can constrain the melt’s isotopic compositions. However, equilibrium α is difficult to calibrate experimentally. Here we used Mg as an example and calculated equilibrium Mg isotope fractionation in MgSiO3 and Mg2SiO4 melt–vapor systems based on first-principles molecular dynamics and the high-temperature approximation of the Bigeleisen–Mayer equation. We found that, at 2500 K, δ25Mg values in the MgSiO3 and Mg2SiO4 melts were 0.141?±?0.004 and 0.143?±?0.003‰ more positive than in their respective vapors. The corresponding δ26Mg values were 0.270?±?0.008 and 0.274?±?0.006‰ more positive than in vapors, respectively. The general \(\alpha - T\) equations describing the equilibrium Mg α in MgSiO3 and Mg2SiO4 melt–vapor systems were: \(\alpha_{{{\text{Mg}}\left( {\text{l}} \right) - {\text{Mg}}\left( {\text{g}} \right)}} = 1 + \frac{{5.264 \times 10^{5} }}{{T^{2} }}\left( {\frac{1}{m} - \frac{1}{{m^{\prime}}}} \right)\) and \(\alpha_{{{\text{Mg}}\left( {\text{l}} \right) - {\text{Mg}}\left( {\text{g}} \right)}} = 1 + \frac{{5.340 \times 10^{5} }}{{T^{2} }}\left( {\frac{1}{m} - \frac{1}{{m^{\prime}}}} \right)\), respectively, where m is the mass of light isotope 24Mg and m′ is the mass of the heavier isotope, 25Mg or 26Mg. These results offer a necessary parameter for mechanistic understanding of Mg isotope fractionation during evaporation and condensation that commonly occurs during the early stages of planetary formation and evolution.  相似文献   
133.
Global abrupt climate change from Marinoan snowball Earth to greenhouse Earth, recorded as cap carbonate overlain on diamictite, had shed the first light on Cambrian bio-radiation. The most documented cap carbonate sections are typical with comprehensive δ13C negative values and ubiquitous sedimentary structures, such as tepee-like, sheet-crack etc., which are associated with successive glacial eustatic variation caused by isostatic rebound in shallow-water facies. Here we report a deep-water basinal cap carbonate section with strong negative δ13C values in the southern margin of the Qinling Orogen, Heyu, Chengkou County, Chongqing in China, which consists of massive dolostone with abundant carbonaceous laminae. However, it lacks the sedimentary structure as mentioned above and is overlain by thin-bedded silicious shales and cherts. A K-bentonite bed was discovered within the base of cap carbonates, about 0.7 m above the top of the Marinoan diamictite. Magmatic zircons that were separated from the K-bentonite bed yield a SIMS concordia U–Pb age of 634.1 ± 1.9 Ma (1σ, MSWDCE = 0.31, ProbabilityCE = 1.000, n = 20). The age is in good agreement with previously reported TIMS U–Pb ages for the termination of Marinoan glaciation and provides a geochronological constraint for the Ediacaran successions in the Qinling Orogen.  相似文献   
134.
Batch experiments were conducted to comparatively evaluate the inhibition effects and mechanisms of a low-concentration (1%) proline solution cover on the release of pollutants from high-sulfur coal gangue. High-sulfur coal gangue was continuously immersed in a proline solution and in deionized water (as a control treatment) for 540 days. The results showed that the coal gangue in the control treatment was oxidized and generated leachate with poor water qualities, i.e., the leachate exhibited lower pH values, higher redox potential values, higher pollutant concentrations (SO42?, Fe, Mn, Cu, and Zn), and high levels of acidophilic sulfur-oxidizing bacteria. However, compared to the control treatment, the addition of the proline solution (1%) significantly improved the water quality of the leachate by significantly reducing the Eh values, the pollutant concentrations (SO42?, Fe2+, Fe, Mn, Cu, and Zn), and the activity of acidophilic sulfur-oxidizing bacteria and by significantly increasing the pH value to neutral. The proline treatment significantly inhibited the oxidation of coal gangue and the release of pollutants, mainly by inhibiting the activity of acidophilic sulfur-oxidizing bacteria and by altering the heavy metal fractions and the mineralogical characteristics. Therefore, in engineering practice, workers should consider using an environmental friendly aqueous proline solution cover to achieve the in-situ control of pollutant releases from coal gangue dumps.  相似文献   
135.
136.
During the Cambrian, gypsum-bearing evaporites formed in the Sichuan Basin, SW China. These rocks are important for oil and gas sealing, but details of their distribution and origin are not well established. This study examines the regional distribution and origin of the gypsum-bearing evaporites using a comprehensive analysis of drilling data from 34 wells, 5 measured cross-sections in the basin and surrounding area, and 96 maps of area-survey data. Results show that in the stratigraphic succession, the gypsum-bearing evaporites occur mainly in the Lower Cambrian Longwangmiao Formation, the Middle Cambrian Douposi Formation, and the Middle-Upper Cambrian Xixiangchi Group. Geographically, the rocks are found mainly in the southeastern part of the basin, and the distribution of deposits shows an overall SW-NE trend. The sedimentary environments for evaporite formation were evaporative lagoon and inter-platform basin in a platform setting. Gypsum was generated by the underwater concentration of sea water in a strongly evaporative environment. Both an evaporative restricted platform and a mixeddeposition restricted platform model appear to be applicable to the development of gypsum in the Sichuan Basin. The gypsum-bearing evaporites with the best sealing capacity are located mostly in the southeastern part of the basin. These constraints can be applied directly to regional exploration, and have implications for the regional paleogeography and paleoclimate.  相似文献   
137.
The dynamic change of mining-induced stress is the main reason for large deformation of surrounding rock. To investigate the influence of mining-induced stress and deformation is important for appropriate supportive design. It also helps to raise the safety and productivity of longwall mining operations. In this paper, Weijiagou Coal Mine in Southwest China was selected as the case study. In order to research on the deformation and breakage of overlying strata, physical modeling test was carried out on the self-developed rotatable physical similar test system. By using digital image correlation (DIC) technique, the deformation of strata and development of cracks in the process of coal seam excavation were acquired, meanwhile, mining-induced stress was also monitored by pressure cell and strainmeter. According to the mechanical structure of stope, the height of the destressed zone has a significant influence on stress distribution. In order to minimize the discrepancy between the physical model test and theoretical analysis, the dimension of the plastic zone of roadway was added into the mining panel width, and the gap between the experimental and theoretical results reduced.  相似文献   
138.
罗振华 《地质与勘探》2018,54(1):174-182
为缓解能源紧张,页岩气作为储量丰富的非常规能源在我国正大力开发,而我国页岩气开发起步较晚,受管理与技术限制,页岩气开发造成的综合环境影响问题还得不到有效解决。针对页岩气开发存在的环境问题,本文基于我国页岩气开发现状,借鉴美国页岩气开发的成功经验,从自然环境与人文环境两方面对页岩气开发综合环境影响因素进行分析,建立了页岩气开发综合环境影响评价指标体系;同时为降低评价过程主观因素的影响,简化评估过程,本文引入突变级数法建立了页岩气开发综合环境影响评估模型,运用数值替换方法区分页岩气开发综合环境影响等级。最后将评价体系与评估模型应用到实际案例中,得到的评价结果与实际情况基本符合,为页岩气开发项目的综合环境评价提供了很好的理论依据。  相似文献   
139.
Abstract

A super-resolution enhancement algorithm was proposed based on the combination of fractional calculus and Projection onto Convex Sets (POCS) for unmanned aerial vehicles (UAVs) images. The representative problems of UAV images including motion blur, fisheye effect distortion, overexposed, and so on can be improved by the proposed algorithm. The fractional calculus operator is used to enhance the high-resolution and low-resolution reference frames for POCS. The affine transformation parameters between low-resolution images and reference frame are calculated by Scale Invariant Feature Transform (SIFT) for matching. The point spread function of POCS is simulated by a fractional integral filter instead of Gaussian filter for more clarity of texture and detail. The objective indices and subjective effect are compared between the proposed and other methods. The experimental results indicate that the proposed method outperforms other algorithms in most cases, especially in the structure and detail clarity of the reconstructed images.  相似文献   
140.
Zhu  Qian  Luo  Yulin  Zhou  Dongyang  Xu  Yue-Ping  Wang  Guoqing  Tian  Ye 《Natural Hazards》2021,105(2):2161-2185
Natural Hazards - Droughts have caused many damages in many countries and might be aggravated around the world. Therefore, it is urgent to predict and monitor drought accurately. Soil moisture and...  相似文献   
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