Initial Characterisation of SK01 Sanidine: A Candidate 40Ar/39Ar Reference Material     

Youjuan Li  Brian R. Jicha  Wanfeng Zhang  Wen Chen  Brad S. Singer  Dewen Zheng  Huaiyu He 《Geostandards and Geoanalytical Research》2023,47(3):657-668

The precision and accuracy of ⁴⁰Ar/³⁹Ar dates are ultimately linked to co-irradiated reference materials of known age. Here we provide new data from the SK01 sanidine, which was analysed in three different laboratories to evaluate it as a ⁴⁰Ar/³⁹Ar reference material. Aliquots of 5 mg, incrementally heated in two laboratories, yielded indistinguishable results with a weighted mean age of 27.58 ± 0.06 Ma (95% confidence level). Single-crystal step heating and single-crystal total fusion analyses of SK01 sanidine were undertaken in the third laboratory to further test the intracrystalline homogeneity. For the seven step-heating analyses, six crystals yielded nearly concordant age spectra with ⁴⁰Ar/³⁹Ar ages ranging from 26.853 ± 0.094 Ma to 26.963 ± 0.067 Ma, whereas one crystal gave an older age of 27.774 ± 0.071 Ma with a slightly discordant age spectrum. Twenty-three single-crystal total fusion analyses yielded ⁴⁰Ar/³⁹Ar ages ranging from 27.070 ± 0.108 Ma to 27.736 ± 0.062 Ma with a dispersion of ~ 3.8%. The older ages from single-crystal total fusion dates are interpreted to reflect an inherited or excess argon component in some crystals. This is an initial characterisation of the SK01 sanidine, and additional work needs to be conducted to further evaluate the age dispersion so that it can be utilised as a ⁴⁰Ar/³⁹Ar reference material.  相似文献   

Global Simulation of Magnetospheric Space Weather Effects of the Bastille Day Storm   总被引：1，自引：0，他引：1  

Raeder  J.  Wang  Y.L.  Fuller-Rowell  T.J.  Singer  H.J. 《Solar physics》2001,204(1-2):323-337

We present results from a global simulation of the interaction of the solar wind with Earth's magnetosphere, ionosphere, and thermosphere for the Bastille Day geomagnetic storm and compare the results with data. We find that during this event the magnetosphere becomes extremely compressed and eroded, causing 3 geosynchronous GOES satellites to enter the magnetosheath for an extended time period. At its extreme, the magnetopause moves at local noon as close as 4.9 R _E to Earth which is interpreted as the consequence of the combined action of enhanced dynamic pressure and strong dayside reconnection due to the strong southward interplanetary magnetic field component B _z, which at one time reaches a value of −60 nT. The lobes bulge sunward and shield the dayside reconnection region, thereby limiting the reconnection rate and thus the cross polar cap potential. Modeled ground magnetic perturbations are compared with data from 37 sub-auroral, auroral, and polar cap magnetometer stations. While the model can not yet predict the perturbations and fluctuations at individual ground stations, its predictions of the fluctuation spectrum in the 0–3 mHz range for the sub-auroral and high-latitude regions are remarkably good. However, at auroral latitudes (63° to 70° magnetic latitude) the predicted fluctuations are slightly too high. Supplementary material to this paper is available in electronic form at http://dx.doi.org/10.1023/A:1014228230714  相似文献   

On the effect of latitude dependent base conditions on the structure of the solar wind     

I. W. Roxburgh  C. Singer 《Solar physics》1975,41(1):241-245

The isothermal solar wind equations are solved for the case where the coronal conditions vary with latitude. It is found that the solutions are not uniquely determined by the base density but require knowledge of the injection angle of the fluid. Even for the case of spherically symmetric density at the corona, the solutions are not unique and form a one parameter set, but the latitude variation decreases rapidly with increasing heliocentric distance.  相似文献   

Interplanetary dust particles near Jupiter     

S.Fred Singer  John E. Stanley 《Icarus》1976,27(2):197-205

We calculate the expected counting rate of a flat micrometeoroid detector of finite sensitivity passing in hyperbolic orbit near a planet. We assume that the distribution of particle sizes, s, can be expressed as a power law spectrum of index p, i.e. dN(s) = Cs^?pds, and also that the particles encounter the sphere of influence of the planet with a certain speed v_∞. The results of the calculations are then compared with the results returned by Pioneer 10 in its flyby of Jupiter. The observed increase in impact rate near Jupiter can be completely explained in terms of gravitational “focusing” of particles which are in heliocentric orbits; i.e., they are not in orbit about Jupiter. The absolute concentration of particles near the orbit of Jupiter is of the same order as at 1 AU: the exact ratio being a function of particle speed and spectral index. Data from one flyby are insufficient to determine a unique value for both the spectral index, p, and the particle velocity, v_∞, but limits can be set. For reasonable encounter speeds (corresponding to eccentricities and inclinations of dust particles experienced near the Earth), the particles near Jupiter are characterized by a spectrum of index p ～ 3. The spectral index which best fits the data increases with increasing encounter speeds.  相似文献   

Biogenic nanoparticulate UO₂: Synthesis, characterization, and factors affecting surface reactivity     

David M. Singer  François Farges  Gordon E. Brown Jr. 《Geochimica et cosmochimica acta》2009,73(12):3593-150

The surface reactivity of biogenic, nanoparticulate UO₂ with respect to sorption of aqueous Zn(II) and particle annealing is different from that of bulk uraninite because of the presence of surface-associated organic matter on the biogenic UO₂. Synthesis of biogenic UO₂ was accomplished by reduction of aqueous uranyl ions, by Shewanella putrefaciens CN32, and the resulting nanoparticles were washed using one of two protocols: (1) to remove surface-associated organic matter and soluble uranyl species (NAUO2), or (2) to remove only soluble uranyl species (BIUO2). A suite of bulk and surface characterization techniques was used to examine bulk and biogenic, nanoparticulate UO₂ as a function of particle size and surface-associated organic matter. The N₂-BET surface areas of the two biogenic UO₂ samples following the washing procedures are 128.63 m² g⁻¹ (NAUO2) and 92.56 m² g⁻¹ (BIUO2), and the average particle sizes range from 5-10 nm based on TEM imaging. Electrophoretic mobility measurements indicate that the surface charge behavior of biogenic, nanoparticulate UO₂ (both NAUO2 and BIUO2) over the pH range 3-9 is the same as that of bulk. The U L_III-edge EXAFS spectra for biogenic UO₂ (both NAUO2 and BIUO2) were best fit with half the number of second-shell uranium neighbors compared to bulk uraninite, and no oxygen neighbors were detected beyond the first shell around U(IV) in the biogenic UO₂. At pH 7, sorption of Zn(II) onto both bulk uraninite and biogenic, nanoparticulate UO₂ is independent of electrolyte concentration, suggesting that Zn(II) sorption complexes are dominantly inner-sphere. The maximum surface area-normalized Zn(II) sorption loadings for the three substrates were 3.00 ± 0.20 μmol m⁻² UO₂ (bulk uraninite), 2.34 ± 0.12 μmol m⁻² UO₂ (NAUO2), and 2.57 ± 0.10 μmol m⁻² UO₂ (BIUO2). Fits of Zn K-edge EXAFS spectra for biogenic, nanoparticulate UO₂ indicate that Zn(II) sorption is dependent on the washing protocol. Zn-U pair correlations were observed at 2.8 ± 0.1 Å for NAUO2 and bulk uraninite; however, they were not observed for sample BIUO2. The derived Zn-U distance, coupled with an average Zn-O distance of 2.09 ± 0.02 Å, indicates that Zn(O,OH)₆ sorbs as bidentate, edge-sharing complexes to UO₈ polyhedra at the surface of NAUO2 nanoparticles and bulk uraninite, which is consistent with a Pauling bond-valence analysis. The absence of Zn-U pair correlations in sample BIUO2 suggests that Zn(II) binds preferentially to the organic matter coating rather than the UO₂ surface. Surface-associated organic matter on the biogenic UO₂ particles also inhibited particle annealing at 90 °C under anaerobic conditions. These results suggest that surface-associated organic matter decreases the reactivity of biogenic, nanoparticulate UO₂ surfaces relative to aqueous Zn(II) and possibly other environmental contaminants.  相似文献   

Radar Backscatter from Underdense Meteors and Diffusion Rates     

Werner Singer  Ralph Latteck  Luis Federico Millan  Nick J. Mitchell  Jens Fiedler 《Earth, Moon, and Planets》2008,102(1-4):403-409

Many meteoroids burn up between about 120 km and 70 km, deposit metals and dust and form ionized trails which are detected by radars. Model studies about the influence of neutral or positively charged background dust on the ambipolar diffusion indicate that significant smaller decay times should be observed for weak meteor echoes compared to strong meteor echoes which can affect the estimation of temperatures. The variation of meteor decay times in dependence on echo strength, height, and season was studied using radar observations at 69° N, 22° S, and 67° S. Significantly reduced decay times were found for weak echoes below about 88 km at low latitudes throughout the year, and at high latitudes with the exception of summer. In summer at high latitudes, decreasing decay times of weak and strong meteors are observed at altitudes below about 85 km during the appearance of noctilucent clouds. The impact of reduced decay times on the estimation of neutral temperatures from decay times is discussed.  相似文献   

Some aspects of the Ca and Sr weathering cycle in the Lake Kinneret (Lake Tiberias) drainage basin     

A. Singer  J. Navrot 《Chemical Geology》1973,12(3):209-218

Sr/Ca ratios in the clay (< 2 μ) weathering products of basalt rocks from the Lake Kinneret drainage basin were found to be very similar to the ratios in the rocks, indicating similar depletion intensities for the two elements. In the clays from the scoriae and some lapilli tuffs the ratios were found to be somewhat higher than in the corresponding rocks, indicating preferential retention of strontium in the clays. The ratio in drainage water from these areas was much lower than that obtained by mass balance calculations.The Sr/Ca ratio in Jordan river water draining primarily limestone areas is 2.3 · 10^?3. Very high Sr/Ca ratios in Lake Kinneret water were attributed to the influence of saline sublacustrine springs. The carbonate fraction from recent lake sediments was shown to have the Sr/Ca ratios characteristic for calcite precipitated biogenically in marine environments. The relative enrichment in strontium of the lake water was explained by the intensive precipitation of carbonates with low strontium distribution coefficients.  相似文献   

Spatial and temporal analysis of hillslope–channel coupling and implications for the longitudinal profile in a dryland basin          下载免费PDF全文

Katerina Michaelides  Rory Hollings  Michael Bliss Singer  Mary H. Nichols  Mark A. Nearing 《地球表面变化过程与地形》2018,43(8):1608-1621

The long‐term evolution of channel longitudinal profiles within drainage basins is partly determined by the relative balance of hillslope sediment supply to channels and the evacuation of channel sediment. However, the lack of theoretical understanding of the physical processes of hillslope–channel coupling makes it challenging to determine whether hillslope sediment supply or channel sediment evacuation dominates over different timescales and how this balance affects bed elevation locally along the longitudinal profile. In this paper, we develop a framework for inferring the relative dominance of hillslope sediment supply to the channel versus channel sediment evacuation, over a range of temporal and spatial scales. The framework combines distinct local flow distributions on hillslopes and in the channel with surface grain‐size distributions. We use these to compute local hydraulic stresses at various hillslope‐channel coupling locations within the Walnut Gulch Experimental Watershed (WGEW) in southeast Arizona, USA. These stresses are then assessed as a local net balance of geomorphic work between hillslopes and channel for a range of flow conditions generalizing decadal historical records. Our analysis reveals that, although the magnitude of hydraulic stress in the channel is consistently higher than that on hillslopes, the product of stress magnitude and frequency results in a close balance between hillslope supply and channel evacuation for the most frequent flows. Only at less frequent, high‐magnitude flows do channel hydraulic stresses exceed those on hillslopes, and channel evacuation dominates the net balance. This result suggests that WGEW exists mostly (~50% of the time) in an equilibrium condition of sediment balance between hillslopes and channels, which helps to explain the observed straight longitudinal profile. We illustrate how this balance can be upset by climate changes that differentially affect relative flow regimes on slopes and in channels. Such changes can push the long profile into a convex or concave condition. © 2018 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.  相似文献   

Reconciling discrepant chronologies for the geomagnetic excursion in the Mono Basin,California: Insights from new 40Ar/39Ar dating experiments and a revised relative paleointensity correlation     

William S. Cassata  Brad S. Singer  Joseph C. Liddicoat  Robert S. Coe 《Quaternary Geochronology》2010,5(5):533-543

Lacustrine sediments of the Wilson Creek Formation in the Mono Basin, California, record a paleomagnetic field excursion constrained by ¹⁴C and ⁴⁰Ar/³⁹Ar geochronology to have occurred within the last 50 ka. However, ¹⁴C and ⁴⁰Ar/³⁹Ar ages are discordant, making it difficult to distinguish which of two possible excursions during this period, the Mono Lake or Laschamp, is recorded in the Mono Basin. New ⁴⁰Ar/³⁹Ar age determinations from sanidine, as well as the first biotite and obsidian ages, for three of the nineteen rhyolitic ashes intercalated with these sediments are presented and compared to previous ¹⁴C and ⁴⁰Ar/³⁹Ar data sets. Although the sanidine ages of the three ashes are stratigraphically consistent with each other and previously determined ⁴⁰Ar/³⁹Ar ages for other ashes in the Wilson Creek Formation, each is significantly older than ¹⁴C ages obtained from stratigraphically equivalent beds, relative paleointensity field correlations, oxygen isotope records, and glacial histories. These data indicate an absence of juvenile, eruptive crystals and most likely reflect the incorporation of crystals from older volcanic centers or underlying sediment. We examine the strengths and weaknesses of all available geochronologic data for the section exposed at Wilson Creek to arrive at an internally consistent set of age constraints. Using these constraints we propose two new relative paleointensity correlations for the section, both of which indicate that the excursion recorded in the Mono Basin occurred at ～30–34 ka on the Greenland Ice Sheet Project 2 (GISP2) ice core time scale.  相似文献   

Artificial neural network forward modelling and inversion of electrokinetic logging data     

N. Ardjmandpour  C. Pain  J. Singer  J. Saunders  E. Aristodemou  J. Carter 《Geophysical Prospecting》2011,59(4):721-748

An artificial neural network method is proposed as a computationally economic alternative to numerical simulation by the Biot theory for predicting borehole seismoelectric measurements given a set of formation properties. Borehole seismoelectric measurements are simulated using a finite element forward model, which solves the Biot equations together with an equation for the streaming potential. The results show that the neural network method successfully predicts the streaming potentials at each detector, even when the input pressures are contaminated with 10% Gaussian noise. A fast inversion methodology is subsequently developed in order to predict subsurface material properties such as porosity and permeability from streaming potential measurements. The predicted permeability and porosity results indicate that the method predictions are more accurate for the permeability predictions, with the inverted permeabilities being in excellent agreement with the actual permeabilities. This approach was finally verified by using data from a field experiment. The predicted permeability results seem to predict the basic trends in permeabilities from a packer test. As expected from synthetic results, the predicted porosity is less accurate. Investigations are also carried out to predict the zeta potential. The predicted zeta potentials are in agreement with values obtained through experimental self potential measurements.  相似文献