Laminated tufa sediments formed from overflow karst springs: Controls on their deposition and carbon–oxygen isotope records          下载免费PDF全文

David Domínguez‐Villar  Juan A. Vázquez‐Navarro  Kristina Krklec  Sonja Lojen  Ian J. Fairchild 《Sedimentology》2017,64(5):1274-1288

Tufa sediments are freshwater carbonates that precipitate in karst regions after degassing of carbon dioxide from groundwater in contact with the atmosphere. When laminated, these carbonates can provide high‐resolution records for the study of climate, hydrological and environmental conditions at the time of their precipitation. The formation of these carbonates directly depends on the hydrological regime, and in karst regions discontinuous discharges are often recorded. This study investigates the record of recent laminated tufa sediments precipitated downstream overflow springs in Trabaque Canyon (central Spain). The hydrological dynamics of the karst system were monitored for over three years and a stable isotope record was obtained from laminated tufa carbonates precipitated from an overflow spring. Additionally, a hydrological model of overflow springs was generated and a tufa δ¹⁸O record under constrained parameters was simulated. Temperature is the dominant control of the variation in tufa δ¹³C and δ¹⁸O values within each lamina, although when comparing different laminae, δ¹³C_DIC and δ¹⁸O of river water are also major controls. The positive correlation between tufa δ¹³C values and water temperature is caused by the fractionation occurred by carbon dioxide degassing due to the thermal dependence of carbon dioxide solubility. Additionally, the system recorded a temperature‐independent degassing process caused by the large gradient between groundwater and atmospheric carbon dioxide that is limited to the proximity of the spring. This study cautions on the risk of assuming continuous deposition when studying laminated tufa sediments and highlights the potential of their stable isotope records to provide hydrological information of their aquifers during the past.  相似文献   

Granulite sulphides as tracers of lower crustal origin and evolution: An example from the Slave craton, Canada     

Sonja Aulbach  Cristen Krauss  Robert A. Creaser  Thomas Stachel  Larry M. Heaman  Sergei Matveev  Thomas Chacko 《Geochimica et cosmochimica acta》2010,74(18):5368-5381

We carried out a detailed study of sulphide minerals, a ubiquitous mineral group in lower crustal mafic to peraluminous granulite xenoliths from the Diavik kimberlites, to assess their use in constraining the origin and tectonothermal evolution of the deep crust, and to obtain additional data on the composition of lower crust beneath ancient continents. Sulphides are overwhelmingly pyrrhotite with minor Ni (0.7-3.9 at.%), Co (0.1-0.7 at.%), and Cu contents (0.4-3.9 at.%). Sulphide modes in mafic granulites range from 0.14 to 0.55 vol%, translating into bulk rock S contents from ∼600 to 2000 ppm, similar to S contents in other mafic igneous rocks and indicating preservation of primary igneous S contents. In mafic granulites, Re and Os abundances in sulphides range from 42.5 to 726 ppb and 3.2 to 180 ppb, respectively, whereas those in peraluminous granulites are distinctly lower (36.1-282 ppb and 1.8-7.2 ppb, respectively), suggestive of Re and Os loss to fractionating sulphides in the more evolved precursors of these rocks.The significant within-sample variability of ¹⁸⁷Os/¹⁸⁸Os and correlation with ¹⁸⁷Re/¹⁸⁸Os indicates the preservation of primary Re-Os isotope systematics and time-integrated decay of the measured ¹⁸⁷Re. Within the large uncertainties inherent in the nature of the samples and technique, sulphides in some granulites may record major tectonothermal events in the central Slave craton spanning several billion years of evolution. Multiple generations of sulphide can occur in a single sample. These data attest to the heterogeneous composition and complex history of the Slave craton lower crust.  相似文献   

Isotopic fractionation and reaction kinetics between Cr(III) and Cr(VI) in aqueous media     

Sonja Zink  Ronny Schoenberg  Michael Staubwasser 《Geochimica et cosmochimica acta》2010,74(20):5729-125

The redox-sensitive stable isotope geochemistry of chromium bears the potential to monitor the attenuation of chromate pollution and to investigate changes in environmental conditions in the present and the past. The use of stable Cr isotope data as a geo-environmental tracer, however, necessitates an understanding of the reaction kinetics and Cr fractionation behaviour during redox transition and isotope exchange. Here, we report stable chromium isotope fractionation data for Cr(VI) reduction, Cr(III) oxidation and isotopic exchange between soluble Cr(III) and Cr(VI) in aqueous media. The reduction of Cr(VI) to Cr(III) with H₂O₂ under strongly acidic conditions shows a near-equilibrium isotope fractionation of Δ^53/52Cr_{(Cr(III)-Cr(VI))} of −3.54 ± 0.35‰. At pH neutrality, however, the reduction experiments show a kinetic isotope fractionation Δ^53/52Cr_{(Cr(III)-Cr(VI))} of −5‰ for the extent of reduction of up to 85% of the chromium. The oxidation of Cr(III) to Cr(VI) in alkaline media, using H₂O₂ as the oxidant, cannot be explained by a single, unidirectional reaction. Our experiments indicate that the involvement of the unstable intermediates Cr(IV) and Cr(V) and their disproportionation during redox reactions between Cr(III) and Cr(VI) influence the overall fractionation factor, depending on the prevailing pH conditions and the reaction rates. No detectable isotope exchange between soluble Cr(VI) and Cr(III) species at pH values of 5.5 and 7 was revealed over a timescale of days to weeks. This means that, at least within such a time frame, the isotopic composition of Cr(VI) in a natural system will not be influenced by equilibration with any Cr(III) and thus reveal the true extent of reduction, given that the Cr isotope composition of the source Cr(VI) and the fractionation factor for the prevailing conditions are known.  相似文献   

International Young Scientists’ perspective on global change issues     

Sonja Wipf  Francisco J. Meza 《Climatic change》2009,94(1-2):1-4

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Modelling and analysis of attenuation anisotropy in multi-azimuth VSP data from the Clair field     

Sonja Maultzsch  Mark Chapman  Enru Liu  Xiang-Yang Li 《Geophysical Prospecting》2007,55(5):627-642

Anisotropic variations in attenuation are of interest since they can give information on the fracture system and may be more amenable to measurement than absolute attenuation values. We examine methods for detecting changes in relative attenuation with azimuth from VSP data, and validate the techniques on synthetic data. Analysis of a multi‐azimuth walkaway VSP data set from a fractured hydrocarbon reservoir indicates that such azimuthal variations in P‐wave attenuation are observable. The effects are localized in the reservoir, and analysis allows the prediction of a fracture strike direction, which agrees with geological information. The observed effects can be modelled under reasonable assumptions, which suggests the validity of the link between the anisotropic attenuation and the fracturing.  相似文献   

On the conditions of sheet injections and eruptions in stratovolcanoes     

Agust Gudmundsson  Sonja L. Brenner 《Bulletin of Volcanology》2005,67(8):768-782

Nearly all eruptions in stratovolcanoes (composite volcanoes, central volcanoes) are supplied with magma through fractures. Consequently, a primary physical condition for an eruption to occur in a stratovolcano is that a magma-driven fracture is able to propagate to the surface. Magma-filled fractures, frozen or fluid, are referred to as sheet intrusions. More specifically, they are named dykes when subvertical, and inclined (or cone) sheets when inclined. Field observations indicate that most sheet intrusions do not reach the surface to feed eruptions but rather become arrested at various crustal depths. For this reason periods of volcanic unrest with sheet injections are much more common than volcanic eruptions. Whether a sheet intrusion becomes arrested or, alternatively, propagates to the surface depends primarily on the stress field in the stratovolcano. A stratovolcano normally consists of layers of contrasting mechanical properties, such as soft (low Youngs modulus) pyroclastic units and stiff (high Youngs modulus) lava flows. We present numerical models indicating that volcanoes composed of such layers commonly develop stress fields encouraging sheet and dyke arrest. The models indicate that a necessary condition for a sheet intrusion to reach the surface and feed a volcanic eruption is that the stress field along the sheet pathway becomes homogenised. We propose that much of the activity in a stratovolcano during a volcanic cycle encourages stress-field homogenisation. Field studies show that the sheet intrusions in individual stratovolcanoes have various dips: some are vertical dykes, others inclined sheets, and still others horizontal sills. Analytical models indicate that the dip of a sheet reaching the surface can have great effects on the magma transport during an eruption. This effect is normally greater for a flat volcano such as a collapse caldera than for a stratovolcano that forms a topographic high. We conclude that the shallower the dip of a sheet intrusion, the less will be its volumetric magma transport to the surface of a stratovolcano.Editorial responsibility: D Dingwell  相似文献   

Impact of marine pollution on society: edited by Virginia K. Tippie and Dana R. Kester Centre for Ocean Studies,Praeger, New York, 1982, 313 pp, $27.95     

Sonja Boehmer-Christiansen 《Marine Policy》1983,7(2):130-131

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Propagation pathways and fluid transport of hydrofractures in jointed and layered rocks in geothermal fields     

Agust Gudmundsson  Ingrid Fjeldskaar  Sonja L. Brenner 《Journal of Volcanology and Geothermal Research》2002,116(3-4)

Palaeofluid-transporting systems, observed as networks of mineral-filled veins in deeply eroded parts of extinct geothermal fields, indicate that hydrofractures commonly supply fluids to geothermal fields. Here we examine well-exposed vein networks that occur at crustal depths of around 1.5 km below the initial surface of the Tertiary lava pile in North Iceland. The veins are located in the damage zone of a major fault zone that dissects basaltic lava flows, the most common host rocks of geothermal fields in Iceland. The lava flows contain numerous weaknesses, particularly columnar (cooling) joints and contacts. For hydrofractures to supply fluids to geothermal fields, the fractures must be able to propagate, and transport fluids, to the surface. We explore hydrofracture pathway formation using boundary-element models of hydrofractures with fluid overpressure varying linearly from 10 MPa at the fracture centre to 0 MPa at the fracture tip (or the fluid front). The hydrofractures propagate through a vertically jointed and horizontally layered pile of lava flows with a general rock-matrix Young’s modulus of 1×10¹⁰ Pa and a Poisson’s ratio of 0.25. The joints and contacts between layers are modelled as internal springs, each with a stiffness (‘strength’) of 6 MPa/m. The location and sizes of discontinuities, as well as the location of the hydrofracture tip, vary between the models. The results indicate that tensile stresses generated at the tip of an overpressured hydrofracture can open up horizontal and vertical discontinuities out to a considerable distance from the tip, and that these discontinuities eventually link up to form the hydrofracture pathway. Analytical models indicate that for a hot spring of a given yield associated with a fault, the dimensions of the fluid-transporting part of the fault are likely to be similar for a typical normal fault and a strike-slip fault. Also, a hot spring of yield 180 l/s (the maximum in the low-temperature fields of Iceland) can be supplied through a hydrofracture of aperture 3 mm and trace length 1.2 m. These dimensions are very similar to those of typical veins in the studied networks. Buoyancy, rather than excess pressure in the fluid source, appears to be the primary driving force of hydrofractures in the geothermal fields of Iceland.  相似文献   

The effect of fluid saturation in an anisotropic multi-scale equant porosity model   总被引：5，自引：0，他引：5  

Mark Chapman  Sonja Maultzsch  Enru Liu  Xiang-Yang Li 《Journal of Applied Geophysics》2003,54(3-4):191

It is recognised that exchange of fluid between fractures and the rock matrix can have a strong impact on a rock's anisotropic elastic properties. A recent theoretical advance considers the effect of the scale length of the fractures. We show that under certain circumstances, this model can be simplified. The simplified model matches laboratory data. A prediction of the model is that frequency-dependent effects are important for fluid substitution in the anisotropic case.  相似文献   

Climate action for food security in South Asia? Analyzing the role of agriculture in nationally determined contributions to the Paris agreement     

T. S. Amjath-Babu  Pramod K. Aggarwal  Sonja Vermeulen 《Climate Policy》2019,19(3):283-298

The Nationally Determined Contributions (NDCs) submitted under the Paris Agreement propose a country’s contribution to global mitigation efforts and domestic adaptation initiatives. This paper provides a systematic analysis of NDCs submitted by South Asian nations, in order to assess how far their commitments might deliver meaningful contributions to the global 2°C target and to sustainable broad-based adaptation benefits. Though agriculture-related emissions are prominent in emission profiles of South Asian countries, their emission reduction commitments are less likely to include agriculture, partly because of a concern over food security. We find that income-enhancing mitigation technologies that do not jeopardize food security may significantly augment the region’s mitigation potential. In the case of adaptation, analysis shows that the greatest effort will be directed towards protecting the cornerstones of the ‘green revolution’ for ensuring food security. Development of efficient and climate-resilient agricultural value chains and integrated farming bodies will be important to ensuring adaptation investment. Potentially useful models of landscape level climate resilience actions and ecosystem-based adaptation are also presented, along with estimates of the aggregate costs of agricultural adaptation. Countries in the region propose different mixes of domestic and foreign, and public and private, adaptation finance to meet the substantial gaps.

Key policy insights

• Though substantial potential for mitigation of agricultural emissions exists in South Asia, governments in the region do not commit to agricultural emissions reductions in their NDCs.

• Large-scale adoption of income-enhancing technologies is the key to realizing agricultural mitigation potential in South Asia, whilst maintaining food security.

• Increasing resilience and profitability through structural changes, value chain interventions, and landscape-level actions may provide strong options to build adaptive capacity and enhance food security.

• Both private finance (autonomous adaptation) and international financial transfers will be required to close the substantial adaptation finance gap

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