The disc evolution of V2051 Oph on decline from superoutburst     

Sonja Vrielmann  Warren Offutt 《Monthly notices of the Royal Astronomical Society》2003,338(1):165-175

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How hydrofractures become arrested     

Agust Gudmundsson  & Sonja L. Brenner 《地学学报》2001,13(6):456-462

Fluids in the earth's crust are commonly transported by hydrofractures, such as dykes and mineral veins, many of which become arrested at various crustal depths. Hydrofractures are commonly arrested – some showing blunt tips – at contacts between soft (low Young's modulus) and stiff (high Young's modulus) layers. For example, many dyke tips are arrested at contacts between soft pyroclastic rocks and stiff basaltic lava flows, and vein tips at contacts between soft marl and stiff limestone. Theoretical models indicate that overpressured, buoyant hydrofractures in homogeneous, isotropic host rocks should normally reach the surface. In layered host rocks, however, abrupt changes in Young's moduli, horizontal discontinuities, and layers with unusually high fracture-perpendicular stresses encourage hydrofracture arrest. It is proposed that for layer-parallel loading, stiff layers favour hydrofracture arrest during active compression but soft layers during extension. It is concluded that for hydrofracture propagation to occur, the stress field along its potential pathway must be essentially homogenous.  相似文献   

The scientific basis of marine pollution control     

Sonja Boehmer-Christiansen 《Marine Policy》1982,6(1):2-10

The author examines the scientific basis of the work of the Joint Group of Experts on the Scientific Aspects of Marine Pollution (GESAMP). Problems of definition and methodology are discussed, and the work of GESAMP working groups on, among others, Marine Waste Disposal, Coastal Water Quality Criteria and the Impact of Oil on the Marine Environment are reported. The author concludes that marine pollution control at the international level has not been able to make much practical headway because political expectations have outstripped scientific and administrative possibilities.  相似文献   

Continuous 60-year stable isotopic and earth-alkali element records in a modern laminated tufa (Jaruga,river Krka,Croatia): Implications for climate reconstruction     

Sonja Lojen  Andrej Trkov  Janez Ščančar  Juan A. Vázquez-Navarro  Neven Cukrov 《Chemical Geology》2009,258(3-4):242-250

A continuous 60-year record (1938–1998) of stable isotope compositions of carbon and oxygen, as well as trace metal (Mg, Sr, Ba) concentrations in a laminated calcite crust precipitated in a short artificial tunnel on a non-equilibrium groundwater-fed karstic river is presented. Chemical and isotopic records have been compared to hydrometeorological data, available for the last 48 years. An attempt is made to relate isotopic and geochemical variations in the crust to environmental parameters, such as temperature, precipitation and changes in vegetation cover, as well as to postdepositional recrystallisation of the older crust material. Isotopic composition of the crust is largely influenced by non-equilibrium precipitation, which favours the incorporation of isotopically depleted C and O into the carbonate. Furthermore, because of the complicated hydrological situation, there is no observable correlation between the stable oxygen isotope composition of water and temperature. The result is that the ¹⁸O isotopic thermometers overestimate the measured precipitation temperatures. Temperatures calculated from Mg/Ca ratios of water and the carbonate match the δ¹⁸O palaeotemperatures within ± 2.4 °C in the older part of the crust, precipitated before the onset of industrial pollution of the river. It was demonstrated that the application of Mg palaeothermometry in natural systems, where the Mg/Ca ratio of water is influenced not only by temperature, but also by other environmental parameters such as precipitation, surface runoff, groundwater retention time and anthropogenic influences, is subject to a large uncertainty, up to 10 °C.  相似文献   

Laminated tufa sediments formed from overflow karst springs: Controls on their deposition and carbon–oxygen isotope records          下载免费PDF全文

David Domínguez‐Villar  Juan A. Vázquez‐Navarro  Kristina Krklec  Sonja Lojen  Ian J. Fairchild 《Sedimentology》2017,64(5):1274-1288

Tufa sediments are freshwater carbonates that precipitate in karst regions after degassing of carbon dioxide from groundwater in contact with the atmosphere. When laminated, these carbonates can provide high‐resolution records for the study of climate, hydrological and environmental conditions at the time of their precipitation. The formation of these carbonates directly depends on the hydrological regime, and in karst regions discontinuous discharges are often recorded. This study investigates the record of recent laminated tufa sediments precipitated downstream overflow springs in Trabaque Canyon (central Spain). The hydrological dynamics of the karst system were monitored for over three years and a stable isotope record was obtained from laminated tufa carbonates precipitated from an overflow spring. Additionally, a hydrological model of overflow springs was generated and a tufa δ¹⁸O record under constrained parameters was simulated. Temperature is the dominant control of the variation in tufa δ¹³C and δ¹⁸O values within each lamina, although when comparing different laminae, δ¹³C_DIC and δ¹⁸O of river water are also major controls. The positive correlation between tufa δ¹³C values and water temperature is caused by the fractionation occurred by carbon dioxide degassing due to the thermal dependence of carbon dioxide solubility. Additionally, the system recorded a temperature‐independent degassing process caused by the large gradient between groundwater and atmospheric carbon dioxide that is limited to the proximity of the spring. This study cautions on the risk of assuming continuous deposition when studying laminated tufa sediments and highlights the potential of their stable isotope records to provide hydrological information of their aquifers during the past.  相似文献   

Granulite sulphides as tracers of lower crustal origin and evolution: An example from the Slave craton, Canada     

Sonja Aulbach  Cristen Krauss  Robert A. Creaser  Thomas Stachel  Larry M. Heaman  Sergei Matveev  Thomas Chacko 《Geochimica et cosmochimica acta》2010,74(18):5368-5381

We carried out a detailed study of sulphide minerals, a ubiquitous mineral group in lower crustal mafic to peraluminous granulite xenoliths from the Diavik kimberlites, to assess their use in constraining the origin and tectonothermal evolution of the deep crust, and to obtain additional data on the composition of lower crust beneath ancient continents. Sulphides are overwhelmingly pyrrhotite with minor Ni (0.7-3.9 at.%), Co (0.1-0.7 at.%), and Cu contents (0.4-3.9 at.%). Sulphide modes in mafic granulites range from 0.14 to 0.55 vol%, translating into bulk rock S contents from ∼600 to 2000 ppm, similar to S contents in other mafic igneous rocks and indicating preservation of primary igneous S contents. In mafic granulites, Re and Os abundances in sulphides range from 42.5 to 726 ppb and 3.2 to 180 ppb, respectively, whereas those in peraluminous granulites are distinctly lower (36.1-282 ppb and 1.8-7.2 ppb, respectively), suggestive of Re and Os loss to fractionating sulphides in the more evolved precursors of these rocks.The significant within-sample variability of ¹⁸⁷Os/¹⁸⁸Os and correlation with ¹⁸⁷Re/¹⁸⁸Os indicates the preservation of primary Re-Os isotope systematics and time-integrated decay of the measured ¹⁸⁷Re. Within the large uncertainties inherent in the nature of the samples and technique, sulphides in some granulites may record major tectonothermal events in the central Slave craton spanning several billion years of evolution. Multiple generations of sulphide can occur in a single sample. These data attest to the heterogeneous composition and complex history of the Slave craton lower crust.  相似文献   

Isotopic fractionation and reaction kinetics between Cr(III) and Cr(VI) in aqueous media     

Sonja Zink  Ronny Schoenberg  Michael Staubwasser 《Geochimica et cosmochimica acta》2010,74(20):5729-125

The redox-sensitive stable isotope geochemistry of chromium bears the potential to monitor the attenuation of chromate pollution and to investigate changes in environmental conditions in the present and the past. The use of stable Cr isotope data as a geo-environmental tracer, however, necessitates an understanding of the reaction kinetics and Cr fractionation behaviour during redox transition and isotope exchange. Here, we report stable chromium isotope fractionation data for Cr(VI) reduction, Cr(III) oxidation and isotopic exchange between soluble Cr(III) and Cr(VI) in aqueous media. The reduction of Cr(VI) to Cr(III) with H₂O₂ under strongly acidic conditions shows a near-equilibrium isotope fractionation of Δ^53/52Cr_{(Cr(III)-Cr(VI))} of −3.54 ± 0.35‰. At pH neutrality, however, the reduction experiments show a kinetic isotope fractionation Δ^53/52Cr_{(Cr(III)-Cr(VI))} of −5‰ for the extent of reduction of up to 85% of the chromium. The oxidation of Cr(III) to Cr(VI) in alkaline media, using H₂O₂ as the oxidant, cannot be explained by a single, unidirectional reaction. Our experiments indicate that the involvement of the unstable intermediates Cr(IV) and Cr(V) and their disproportionation during redox reactions between Cr(III) and Cr(VI) influence the overall fractionation factor, depending on the prevailing pH conditions and the reaction rates. No detectable isotope exchange between soluble Cr(VI) and Cr(III) species at pH values of 5.5 and 7 was revealed over a timescale of days to weeks. This means that, at least within such a time frame, the isotopic composition of Cr(VI) in a natural system will not be influenced by equilibration with any Cr(III) and thus reveal the true extent of reduction, given that the Cr isotope composition of the source Cr(VI) and the fractionation factor for the prevailing conditions are known.  相似文献   

International Young Scientists’ perspective on global change issues     

Sonja Wipf  Francisco J. Meza 《Climatic change》2009,94(1-2):1-4

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Modelling and analysis of attenuation anisotropy in multi-azimuth VSP data from the Clair field     

Sonja Maultzsch  Mark Chapman  Enru Liu  Xiang-Yang Li 《Geophysical Prospecting》2007,55(5):627-642

Anisotropic variations in attenuation are of interest since they can give information on the fracture system and may be more amenable to measurement than absolute attenuation values. We examine methods for detecting changes in relative attenuation with azimuth from VSP data, and validate the techniques on synthetic data. Analysis of a multi‐azimuth walkaway VSP data set from a fractured hydrocarbon reservoir indicates that such azimuthal variations in P‐wave attenuation are observable. The effects are localized in the reservoir, and analysis allows the prediction of a fracture strike direction, which agrees with geological information. The observed effects can be modelled under reasonable assumptions, which suggests the validity of the link between the anisotropic attenuation and the fracturing.  相似文献   

On the conditions of sheet injections and eruptions in stratovolcanoes     

Agust Gudmundsson  Sonja L. Brenner 《Bulletin of Volcanology》2005,67(8):768-782

Nearly all eruptions in stratovolcanoes (composite volcanoes, central volcanoes) are supplied with magma through fractures. Consequently, a primary physical condition for an eruption to occur in a stratovolcano is that a magma-driven fracture is able to propagate to the surface. Magma-filled fractures, frozen or fluid, are referred to as sheet intrusions. More specifically, they are named dykes when subvertical, and inclined (or cone) sheets when inclined. Field observations indicate that most sheet intrusions do not reach the surface to feed eruptions but rather become arrested at various crustal depths. For this reason periods of volcanic unrest with sheet injections are much more common than volcanic eruptions. Whether a sheet intrusion becomes arrested or, alternatively, propagates to the surface depends primarily on the stress field in the stratovolcano. A stratovolcano normally consists of layers of contrasting mechanical properties, such as soft (low Youngs modulus) pyroclastic units and stiff (high Youngs modulus) lava flows. We present numerical models indicating that volcanoes composed of such layers commonly develop stress fields encouraging sheet and dyke arrest. The models indicate that a necessary condition for a sheet intrusion to reach the surface and feed a volcanic eruption is that the stress field along the sheet pathway becomes homogenised. We propose that much of the activity in a stratovolcano during a volcanic cycle encourages stress-field homogenisation. Field studies show that the sheet intrusions in individual stratovolcanoes have various dips: some are vertical dykes, others inclined sheets, and still others horizontal sills. Analytical models indicate that the dip of a sheet reaching the surface can have great effects on the magma transport during an eruption. This effect is normally greater for a flat volcano such as a collapse caldera than for a stratovolcano that forms a topographic high. We conclude that the shallower the dip of a sheet intrusion, the less will be its volumetric magma transport to the surface of a stratovolcano.Editorial responsibility: D Dingwell  相似文献