In a reconnaissance study, trace amounts of Cd, Cu, Pb, and Zn were determined in “A-zone” soil from 22 locations in the Dayton,
Ohio, area. Soil samples were collected at high-volume air monitoring sites in urban, suburban, and rural areas. Measurable
amounts of the elements were found in all of the samples. Positive correlations occur between each metal and particulate matter,
with correlation coefficients of aboutr=0.70, at the 99% confidence level. Natural background values for the elements were measured in soil from rural areas. Theoretical
background values, which are very close to those measured, were calculated from the individual regression equations. Natural
background levels do not exceed 1.00 ppm Cd, 15 ppm Cu, 25 ppm Pb, and 55 ppm Zn. The heavy metal contents of most soils in
the area exceed background by factors of up to 3.0 for Cd, up to 4.5 for Cu, up to 11 for Pb, and up to 4.5 for Zn.
Significant positive correlations among the metals suggest a common source (or sources) for at least some, if not most, of
the heavy metals. For the most part, the highest metal values are found in soils near coal-burning plants. Fly ash from a
local plant contains substantial amounts of the elements. The high lead values are largely due to vehicular exhaust. However,
there is evidence that the metals can also come from the normal deterioration of vehicles.
It appears that airborne pollution is an important source of heavy metals in Dayton area soils. 相似文献
Published strength profiles predict strength discontinuities within and/or at the base of continental crust during compression. We use finite element models to investigate the effect of strength discontinuities on continental collision dynamics. The style of deformation in model crust during continued subduction of underlying mantle lithosphere is controlled by: (1) experimental flow-law data; (2) the crustal geotherm; (3) strain localization by erosion; (4) strain-softening and other localization effects. In the absence of erosion and other factors causing strain localization, numerical models with typical geothermal gradients and frictional/ductile rheologies predict diffuse crustal deformation with whole-scale detachment of crust from mantle lithosphere. This prediction is at odds with earlier model studies that only considered frictional crustal rheologies and showed asymmetric, focused crustal deformation. Without localization, model deformation is not consistent with that observed in small collisional orogens such as the Swiss Alps. This suggests that strain localization by a combination of erosion and rheological effects such as strain softening must play a major role in focusing deformation, and that strength profiles derived under constant strain rates and uniform material properties cannot be used to infer crustal strength during collision dynamics. 相似文献
Increases in chlorinated and brominated halocarbons are believed to be responsible for the depletion of stratospheric ozone observed over much of the globe in the past decade or so. Ozone depletion is in turn believed to lead to a negative radiative forcing, tending to cool the stratosphere and the surface. We show that the increasing atmospheric concentrations of ozone-depleting halocarbons and onset of related ozone depletion likely led to a negative forcing of the climate system in the 1980s that slowed significantly the rate of change of total anthropogenic radiative forcing due to the combined effect of all greenhouse gases over that decade. Within the next decade, emissions of these halocarbons are expected to rapidly decrease, with corresponding impacts on ozone and radiative forcing. As the emissions of ozone-depleting gases are reduced and eventually phased out, the rate of ozone depletion is expected to decrease and eventually reverse. All other things being equal, we show that the change from deepening ozone depletion in the 1980s to ozone increases in the future should lead to a pronounced increase in the decadal rate of change of anthropogenic greenhouse forcing of the next few decades, perhaps to levels unprecedented in this century. 相似文献
Detection of agricultural chemicals in ground water has prompted numerous studies. Federal, state, and regional studies were conducted in the last 10 years in order to assess the occurrence of agricultural chemicals in ground water. The results of the studies present the number or percentage of samples with agricultural chemicals above the drinking water standard or health advisory levels as well as samples with detections of one or more compounds. Data comparison from one state or region to another are frequently referred to by regulatory and agency personnel involved in water quality and agriculture issues. Unless the history of pesticide use, method of chemical analyses, detection limits, statistical design of the sampling plan, well type, well depth, geology of the formation material, and typical land use around the wellhead are known, such comparisons can be misleading. Reporting the limitations or presenting a disclaimer should be a key element for a study so that "apples and oranges" are not compared. 相似文献
We report new helium isotope results for 49 basalt glass samples from the Mid-Atlantic Ridge between 1°N and 47°S.3He/4He in South Atlantic mid-ocean ridge basalts (MORB) varies between 6.5 and 9.0 RA (RA is the atmospheric ratio of1.39 × 10−6), encompassing the range of previously reported values for MORB erupted away from high3He/4He hotspots such as Iceland. He, Sr and Pb isotopes show systematic relationships along the ridge axis. The ridge axis is segmented with respect to geochemical variations, and local spike-like anomalies in3He/4He, Pb and Sr isotopes, and trace element ratios such as(La/Sm)N are prevalent at the latitudes of the islands of St. Helena, Tristan da Cunha and Gough to the east of the ridge. The isotope systematics are consistent with injection beneath the ridge of mantle “blobs” enriched in radiogenic He, Pb and Sr, derived from off-axis hotspot sources. The variability in3He/4He along the ridge can be used to refine the hotspot source-migrating-ridge sink model.
MORB from the 2–7°S segment are systematically the least radiogenic samples found along the mid-ocean ridge system to date. Here the depleted mantle source is characterized by87Sr/86Sr of 0.7022, Pb isotopes close to the geochron and with206Pb/204Pb of 17.7, and3He/4He of 8.6–8.9 RA. The “background contamination” of the subridge mantle, by radiogenic helium derived from off-ridge hotspots, displays a maximum between 20 and 24°S. The HePb and HeSr isotope relations along the ridge indicate that the3He/4He ratios are lower for the hotspot sources of St. Helena, Tristan da Cunha and Gough than for the MORB source, consistent with direct measurements of3He/4He ratios in the island lavas. Details of the HeSrPb isotope systematics between 12 and 22°S are consistent with early, widespread dispersion of the St. Helena plume into the asthenosphere, probably during flattening of the plume head beneath the thick lithosphere prior to continental breakup. The geographical variation in theHe/Pbratio deduced from the isotope systematics suggests only minor degassing of the plume during this stage. Subsequently, it appears that the plume component reaching the mid-Atlantic ridge was partially outgassed of He during off-ridge hotspot volcanism and related melting activity.
Overall, the similar behavior of He and Pb isotopes along the ridge indicates that the respective mantle sources have evolved under conditions which produced related He and Pb isotope variations. 相似文献
Samples of sediment collected from the Severn floodplain between Worcester and Gloucester following the severe flooding in January and February 1990, were analysed for their grain size distribution. The results show that most sand was deposited within 20 m of the channel bank, but that fine sand may contribute to flood sediment across the width of the floodplain. James' (1985) numerical model of overbank sedimentation attempts to predict the transfer of sediment to the floodplain during flooding. Geometrical and hydraulic data relating to the Severn flood are used as input for a computer program of James' (1985) model. The pattern of sediment concentrations predicted by the model was compared with that obtained from statistical analysis of the flood sediment. The patterns were found to be similar, so James' (1985) model was considered to predict in a relative sense the distribution of flood sediment. 相似文献