Magnetic and structural study of the Eaux-Chaudes intrusion: understanding the Variscan deformation in the Western Axial Zone (Pyrenees)     

Esther Izquierdo-Llavall  Teresa Román-Berdiel  Antonio M. Casas  Belén Oliva-Urcia  Inmaculada Gil-Pe?a  Ruth Soto  Antonio Jabaloy 《International Journal of Earth Sciences》2012,101(7):1817-1834

The present study provides new magnetic and microstructural data for the Eaux-Chaudes granodioritic massif (Western Axial Zone, Pyrenees) and contributes to the understanding of its geometry, internal structure and emplacement mechanism. Moreover, the geological cross-sections and field data allow to reconstruct the evolution of the whole area from Variscan to Alpine times and to integrate the emplacement of the igneous body in the context of the Variscan orogeny. The Eaux-Chaudes pluton (301?±?9?Ma) is mainly composed by granodiorite, describing a normal compositional zoning and an approximately concentric arrangement that is consistent with the zonation of the low-field magnetic susceptibility. Magnetic foliation is subhorizontal in the inner part of the intrusion and becomes parallel to the petrographical contacts along pluton margins, roughly describing the geometry of the intrusion. Magnetic lineations are dominantly subhorizontal, with E–W to ENE–WSW directional maximum. The general parallelism between Variscan structures of the host rock and the geometry and magmatic fabric of the intrusion reveals a late syn-Variscan emplacement. The tectonic regime registered during magma emplacement is in agreement with an N–S shortening and an E–W stretching direction, consistent with the transpressive regime deduced for other Pyrenean intrusions. Alpine overprint produced a slight tilting in the southern part of the intrusion, but it can be considered that the original Variscan structure is basically unchanged.  相似文献   

Transient release of Ni,Mn and Fe from mixed metal sulphides under oxidising and reducing conditions     

C. Naylor  W. Davison  M. Motelica-Heino  L. M. van der Heijdt  G. A. van den Berg 《Environmental Earth Sciences》2012,65(7):2139-2146

The potential release of metals from anoxic sediments exposed to oxygen was investigated by using a synthetic preparation of metal sulphides dominated by solid phase FeS. The technique of DGT (diffusive gradients in thin-films) was used to measure sulphide and Fe, Mn and Ni in the anoxic metal-sulphide slurry, which had a pH of 6.4. Speciation calculations based on these data showed there was moderate supersaturation with respect to amorphous FeS in the solution phase. Measurements made using DGT with a range of diffusion layer thicknesses showed that when Fe, Mn and Ni are removed from solution there is fairly rapid (minutes) release from the solid phase, that is reasonably well sustained. This presumed desorptive release will be responsible for elevated concentrations of some metals in solution when sediments are resuspended. Oxidation of the slurry by bubbling with air rapidly (hours) removed Fe, Mn and Ni from the pore water solution. While Fe concentrations in solution remained low after the removal, Mn and Ni were transiently released. These results were consistent with initial rapid oxidation of Fe(II) to oxyhydroxides, which remove Mn(II) and Ni by adsorption. The slower oxidation of FeS then releases Mn and Ni, but these too are eventually removed by adsorption to iron oxyhydroxides. These data suggest that oxidation of metal sulphides will contribute to the release of metals from sediment disturbed by dredging or remedial aeration, but it is likely to be short lived, with complete removal within a day.  相似文献   

Ecological status of seagrass ecosystems: An uncertainty analysis of the meadow classification based on the Posidonia oceanica multivariate index (POMI)     

Bennett S  Roca G  Romero J  Alcoverro T 《Marine pollution bulletin》2011,62(8):1616-1621

Quantifying the uncertainty associated with monitoring protocols is essential to prevent the misclassification of ecological status and to improve sampling design. We assessed the Posidonia oceanica multivariate index (POMI) bio-monitoring program for its robustness in classifying the ecological status of coastal waters within the Water Framework Directive. We used a 7-year data set covering 30 sites along 500 km of the Catalonian coastline to examine which version of POMI (14 or 9 metrics) maximises precision in classifying the ecological status of meadows. Five factors (zones within a site, sites within a water body, depth, years and surveyors) that potentially generate classification uncertainty were examined in detail. Of these, depth was a major source of uncertainty, while all the remaining spatial and temporal factors displayed low variability. POMI 9 matched POMI 14 in all factors, and could effectively replace it in future monitoring programs.  相似文献   

Determination of the near field distance for point and line sources acting on the surface of an homogeneous and viscoelastic half-space     

Robert Arcos  Jordi RomeuAndreu Balastegui  Teresa Pàmies 《Soil Dynamics and Earthquake Engineering》2011

A methodology to determine the near field region, defined as the region where volumetric waves significantly influence the surface vibration levels, is presented. This interference region between Rayleigh and volumetric waves is calculated for the case of an homogeneous and viscoelastic half-space excited by a surface point source and a surface infinite line source. This calculation is performed following an analytical approach. The effects of the mechanical properties of the ground on the dimensions of this interference region, characterized here by the near field distance, are also investigated. The results show near field distances for both infinite line and point sources and for five different real grounds, typical of the Barcelona (Spain) metropolitan area.  相似文献   

Density and magnetic models of the lithosphere along CELEBRATION 2000 profile CEL01     

Teresa Grabowska  Grzegorz Bojdys  Miroslav Bielik  Kristián Csicsay 《Acta Geophysica》2011,59(3):526-560

The paper presents 2D density and magnetic models of the crust and upper mantle along the DSS line profile of the CELEBRATION 2000 project that crosses the most important geological units in Central Europe. These are the Alps-Carpathians-Pannonian (ALCAPA) region, the SE part of the Paleozoic Platform (PLZ), the Trans-European Suture Zone (TESZ) and a fragment of the SW portion of the East European Craton (EEC). The density and magnetic models were constructed on the basis of a 2D model of P-wave velocity converted into density model, geological data as well as geothermal data and the results of integrated geophysical modelling for the lithosphere-asthenosphere boundary.  相似文献   

Wave groupiness and spectral bandwidth as relevant parameters for the performance assessment of wave energy converters     

Jean-Baptiste Saulnier  Alain Clément  Teresa Pontes  Pierpaolo Ricci 《Ocean Engineering》2011,38(1):130-147

To date the estimation of long-term wave energy production at a given deployment site has commonly been limited to a consideration of the significant wave height H_s and mean energy period T_e. This paper addresses the sensitivity of power production from wave energy converters to the wave groupiness and spectral bandwidth of sea states. Linear and non-linear systems are implemented to simulate the response of converters equipped with realistic power take-off devices in real sea states. It is shown in particular that, when the converters are not much sensitive to wave directionality, the bandwidth characteristic is appropriate to complete the set of overall wave parameters describing the sea state for the purpose of estimating wave energy production.  相似文献   

The study of metal contamination in urban topsoils of Mexico City using GIS   总被引：1，自引：0，他引：1  

María Teresa Rodríguez-Salazar  Ofelia Morton-Bermea  Elizabeth Hernández-Álvarez  Rufino Lozano  Victor Tapia-Cruz 《Environmental Earth Sciences》2011,62(5):899-905

This research presents and discusses information concerning the spatial distribution of heavy metals (Pb, Cu, Zn, Ba, Co, Cr, Ni and V) in the urban environments of Mexico City using geographical information system and statistical analysis. Superficial soil samples (n = 146) were analyzed. The highest contamination indices were found in the north and center zone of the metropolitan area. In contrast, the surrounding rural fields show a lower impact grade. The higher concentrations of Pb, Cu, Zn and Ba were observed as being related to high vehicular traffic, nevertheless other elements such as Co, Cr, Ni and V do not show anthropogenic influence and their content can be attributed to the parental rock. The results are compared with previous surveys carried out in 2003 in order to evaluate temporal deposition trends. No changes were found on reported concentrations except for Cu and Zn, whose concentration has increased in later years. The results suggest that spatial distribution analysis and results in comparison with previous studies could be useful for the management and sustainable development of the metropolitan area of Mexico City.  相似文献   

Molecular weight and chemical reactivity of dissolved trace metals (Cd,Cu, Ni) in surface waters from the Mississippi River to Gulf of Mexico     

Liang-Saw Wen  Peter H. Santschi  Kent W. Warnken  William Davison  Hao Zhang  Hsiu-Ping Li  Kuo-Tung Jiann 《Estuarine, Coastal and Shelf Science》2011

It is generally assumed that estuarine mixing is continuous for metals from terrestrial sources, gradually decreasing towards the open ocean endmember. Here we show that, chemical reactivity, determined by ion exchange method, and molecular weight distributions, obtained using cross-flow ultrafiltration, of dissolved Cd, Cu, and Ni in the surface waters of the Gulf of Mexico varied systematically across the estuarine mixing zone of the Mississippi River. Most size or chemical affinity fractions of dissolved metals (<0.4 μm) were linearly related to salinity (10.8–36.6), suggesting that the distribution of these elements was mainly controlled by continuous mixing processes. Dissolved concentrations across the salinity gradient ranged for Cd: 87–187 pM; Cu: 1.4–18.3 nM; and Ni: 2.6–18.8 nM, with highest values near the Mississippi river mouth, and lowest concentrations in a warm core ring in the Gulf of Mexico. Dissolved Cd was mostly present as a truly dissolved (<10 kDa, 97 ± 1%) and cationic fraction (Chelex-100 extractable, 94 ± 4%). A novel observation across the estuarine mixing zone was that colloidal metal concentrations were identical to either inert (for Cu, Ni) or AMPG-labile anionic (Cu, Cd) fractions. The difference in behavior between Cu and the other two metals might indicate differences in the biopolymeric nature of the metal–organic chelates. In particular, the anionic-organic Cd fractions accounted for just 3 ± 1%, on average. However, for Cu, it was 24 ± 4%, and for Ni, it was 9 ± 6%. The fractions of the total dissolved metal fractions that were “inert” averaged 31 ± 10% for Cu and 29 ± 12% for Ni. Small but noticeable amounts (6 ± 3%) of dissolved inert Cd fractions were also present. Apparent non-local transport processes, likely associated with cross-shelf sediment resuspension processes, could have been responsible for the relatively high concentrations of ‘inert’ and ‘anionic’ metal fractions in high salinity coastal waters, and accounting for the persistence of metals bound to humic substances in the Gulf of Mexico.  相似文献   

Sequential granite emplacement: a structural study of the late Variscan Strzelin intrusion, SW Poland     

Teresa Oberc-Dziedzic  Ryszard Kryza  Christian Pin  Stanisław Madej 《International Journal of Earth Sciences》2013,102(5):1289-1304

The Strzelin Massif in SW Poland (Central European Variscides) records a protracted igneous evolution, with three main magmatic stages: (1) tonalitic I, (2) granodioritic and (3) tonalitic II/granitic. In the northern part of this Massif, the Strzelin intrusion proper comprises three successively emplaced rock types: a medium-grained biotite granite (303 ± 2 Ma), a fine-grained biotite granite (283 ± 8 Ma) and a fine-grained biotite-muscovite granite; based on field evidence, the third variety postdates both types of the biotite granites. The structural data from the three granites, including their parallel, approximately E–W striking and steeply dipping lithological contacts and ENE–WSW trending subhorizontal magmatic lineations, suggest that the emplacement of all three successive granite varieties was controlled by an active, long-lived strike-slip fault, striking ESE–WNW, with a dextral sense of movement. After the emplacement of the youngest biotite-muscovite granite, the intrusion underwent brittle extension which produced “Q joints” striking NNW–SSE to N–S and dipping at 55–70° WSW to W, and showing evidence of broadly N–S directed sinistral displacements. The structural observations, supported by new geochronological data, indicate that the internal structure of the composite granitoid intrusion, including the faint magmatic foliation and lineation, formed in a long-lived strike-slip setting, different from the subsequent, post-emplacement extensional tectonics that controlled the development of brittle structures.  相似文献   

Effect of the addition of granitic powder to an acidic soil from Galicia (NW Spain) in comparison with lime   总被引：1，自引：1，他引：0  

Benita?Silva  Remigio?ParadeloEmail author  Nuria?Vázquez  Eduardo?García-Rodeja  María?Teresa?Barral 《Environmental Earth Sciences》2013,69(2):429-441

The impact of diffuse pollution, agricultural land use and climate change on the long-term response of subsurface–surface water quality is not well understood, but is a prerequisite for evaluation of water management options. The goal of this study is to model geochemical evolution of water chemistry from the infiltration through soil into the unsaturated zone, transport through bedrocks and granular aquifers to a river in order to identify zones of steep concentration gradients and high dynamics under transient flow conditions. A numerical model was constructed comprising a 2-D 1,500 m × 150 m vertical cross-section of typical sedimentary rock formations, a glacio-fluvial quaternary gravel aquifer in the valley and soil layers. The model coupled saturated/un-saturated flow and reactive transport under steady state and transient conditions. Geochemical interactions, include intra-aqueous kinetic reactions of oxygen with dissolved organic matter, as well as kinetics of carbonate dissolution/precipitation. This model section was chosen to provide insight in to the principal processes and time scales affecting water chemistry along different flow paths. The numerical simulator MIN3P was used, a finite volume program for variably saturated subsurface flow and multi-component reactive transport. The results show that subsurface water residence times range from approximately 2 to 2,000 years. Different zones are to be expected with respect to the development of mineral equilibria; namely, purely atmospherically influenced, as well as open and closed system carbonate dissolution. Short-term responses to daily averaged changes in precipitation, however, are only visible to some extent in the shallower and near-river parts of flow system and solute loads. This can most likely be explained by directional changes in flow paths, indicating that equilibrium geochemical condition predominate at the hillslope scale, i.e. water quality depends on transport pathways rather than on kinetic effects. The extent of reducing conditions is controlled by the presence of organic-rich layers (i.e. peat deposits), the dissolution kinetics of aquifer organic matter and the subsequent mixing with oxygenated water by hydrodynamic dispersion.  相似文献