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941.
The spin up and relaxation of an autumn upwelling event on the Beaufort slope is investigated using a combination of oceanic and atmospheric data and numerical models. The event occurred in November 2002 and was driven by an Aleutian low storm. The wind field was strongly influenced by the pack-ice distribution, resulting in enhanced winds over the open water of the Chukchi Sea. Flow distortion due to the Brooks mountain range was also evident. Mooring observations east of Barrow Canyon show that the Beaufort shelfbreak jet reversed to the west under strong easterly winds, followed by upwelling of Atlantic Water onto the shelf. After the winds subsided a deep eastward jet of Atlantic Water developed, centered at 250 m depth. An idealized numerical model reproduces these results and suggests that the oceanic response to the local winds is modulated by a propagating signal from the western edge of the storm. The disparity in wave speeds between the sea surface height signal—traveling at the fast barotropic shelf wave speed—versus the interior density signal—traveling at the slow baroclinic wave speed—leads to the deep eastward jet. The broad-scale response to the storm over the Chukchi Sea is investigated using a regional numerical model. The strong gradient in windspeed at the ice edge results in convergence of the offshore Ekman transport, leading to the establishment of an anti-cyclonic gyre in the northern Chukchi Sea. Accordingly, the Chukchi shelfbreak jet accelerates to the east into the wind during the storm, and no upwelling occurs west of Barrow Canyon. Hence the storm response is fundamentally different on the Beaufort slope (upwelling) versus the Chukchi slope (no upwelling). The regional numerical model results are supported by additional mooring data in the Chukchi Sea.  相似文献   
942.
Triaxial shear testing of polished slickensided surfaces   总被引:1,自引:1,他引:0  
A series of consolidated-drained triaxial tests were performed on precut and polished clay specimens to measure their drained residual strength. Two soils were tested during this research program: Rancho Solano Clay and San Francisco Bay Mud. Specimens were tested using a specially modified triaxial compression device which was developed to minimize the effects of end-platen restraint on the measured strengths. Special attention was paid to the influence of changing specimen area and membrane effects during the test. Triaxial test results were compared with baseline measurements of drained residual shear strength that were made for each of the clay soils using Bromhead ring shear tests and polished-specimen direct shear tests. Residual strength values measured in the triaxial device were higher than the drained residual strengths measured in the Bromhead ring shear apparatus and the direct shear device, indicating that this test approach is more challenging than the use of direct shear tests conducted on polished slickensided surfaces. Comparison of single stage and multistage triaxial test data indicates that multistage triaxial testing may work well for specimens that fail along a well-defined plane, provided that careful attention is given to the effects of end platen restraint, membrane restraint, and changes in specimen area during shear.  相似文献   
943.
Atlantic croaker is one of the most abundant demersal fish in Chesapeake Bay. Until recently, when substantial declines in abundance have occurred, high biomass supported elevated fisheries landings. Therefore, study of the diet of Atlantic croaker is important to understand its own dynamics and its role in the Chesapeake Bay ecosystem. Patterns in the diet of croaker varied annually, seasonally, and spatially, but were not strongly correlated with any measured environmental variables. Although the majority of the diet of croaker consisted of polychaetes and other benthic items, about 20% of the croaker diet by weight consisted of anchovy and other fishes. Croaker consumption of anchovy is likely a result of crepuscular feeding that has not been captured in previous studies that sampled during the day and with bottom trawls. Thus, croaker influences both the benthic and pelagic components of the Chesapeake Bay food web and incorporating such diel patterns in diet may increase the reliability of fishery ecosystem models.  相似文献   
944.

Background

Induced precipitation of phosphate minerals to scavenge trace elements from groundwater is a potential remediation approach for contaminated aquifers. The success of engineered precipitation schemes depends on the particular phases generated, their rates of formation, and their long term stability. The purpose of this study was to examine the precipitation of calcium phosphate minerals under conditions representative of a natural groundwater. Because microorganisms are present in groundwater, and because some proposed schemes for phosphate mineral precipitation rely on stimulation of native microbial populations, we also tested the effect of bacterial cells (initial densities of 105 and 107 mL-1) added to the precipitation medium. In addition, we tested the effect of a trace mixture of propionic, isovaleric, formic and butyric acids (total concentration 0.035 mM).

Results

The general progression of mineral precipitation was similar under all of the study conditions, with initial formation of amorphous calcium phosphate, and transformation to poorly crystalline hydroxylapatite (HAP) within one week. The presence of the bacterial cells appeared to delay precipitation, although by the end of the experiments the overall extent of precipitation was similar for all treatments. The stoichiometry of the final precipitates as well as Rietveld structure refinement using x-ray diffraction data indicated that the presence of organic acids and bacterial cells resulted in an increasing a and decreasing c lattice parameter, with the higher concentration of cells resulting in the greatest distortion. Uptake of Sr into the solids was decreased in the treatments with cells and organic acids, compared to the control.

Conclusions

Our results suggest that the minerals formed initially during an engineered precipitation application for trace element sequestration may not be the ones that control long-term immobilization of the contaminants. In addition, the presence of bacterial cells appears to be associated with delayed HAP precipitation, changes in the lattice parameters, and reduced incorporation of trace elements as compared to cell-free systems. Schemes to remediate groundwater contaminated with trace metals that are based on enhanced phosphate mineral precipitation may need to account for these phenomena, particularly if the remediation approach relies on enhancement of in situ microbial populations.  相似文献   
945.
A conceptual groundwater flow model was developed for the crystalline aquifers in southeastern part of the Eastern region, Ghana. The objective was to determine approximate levels of groundwater recharge, estimate aquifer hydraulic parameters, and then test various scenarios of groundwater extraction under the current conditions of recharge. A steady state groundwater flow model has been calibrated against measured water levels of 19 wells in the area. The resulting recharge is estimated to range from 8.97 × 10?5 m/d to 7.14 × 10?4 m/d resulting in a basin wide average recharge of about 9.6% of total annual precipitation, which results in a basin wide quantitative recharge of about 2.4 million m3/d in the area. This compares to recharge estimated from the chloride mass balance of 7.6% of precipitation determined in this study. The general groundwater flow in the area has also been determined to conform to the general northeast–southwest structural grain of the country. The implication is that the general hydrogeology is controlled by post genetic structural entities imposed on the rocks to create ingresses for sufficient groundwater storage and transport. Calibrated aquifer hydraulic conductivities range between 0.99 m/d and over 19.4 m/d. There is a significant contribution of groundwater discharge to stream flow in the study area. Increasing groundwater extraction will have an effect on stream flow. This study finds that the current groundwater extraction levels represent only 0.17% of the annual recharge from precipitation, and that groundwater can sustain future increased groundwater demands from population growth and industrialization.  相似文献   
946.
Since the launch of the first satellite in 1972, ecologists have been equipped with new tools to address the degradation of tropical forests, previously limited by field-based methods. This article is a review of the state of remote sensing technology in characterizing the degradation of tropical forest. The factors responsible for the structural and functional degradation of the tropical forest and its likely impacts are described in view of generating remote sensing based inputs. In order to assess the degradation and utility of geo-informatics tools, 32 parameters are identified. The research developments at different levels of information extraction from the historic to recent periods are elaborated, and future challenges are predicted. The article concludes that an additional momentum of research is required to answer many unresolved questions of tropical forest degradation.  相似文献   
947.
Benthic macroalgae form an important part of temperate marine ecosystems, exhibiting a complex three-dimensional character which represents a vital foraging and spawning ground for many juvenile fish species. In this research, image-based techniques for classification of multibeam backscatter are explored for the detection of benthic macroalgae at Cashes Ledge in the Gulf of Maine, USA. Two classifications were performed using QTC-Multiview, differentiated by application of a threshold filter, and macroalgal signatures were independently extracted from the raw sonar datagrams in Matlab. All classifications were validated by comparison with video ground-truth data. The unfiltered classification shows a high degree of complexity in the shallowest areas within the study site; the filtered demonstrates markedly less variation by depth. The unfiltered classification shows a positive agreement with the video ground-truth data; 82.6% of observations recording Laminaria sp., 39.1% of Agarum cribrosum and 100.0% (n = 3) of mixed macroalgae occur within the same acoustically distinct group of classes. These are discrete from the 8.1% recorded agreement with absences and nulls (>40 m) of macrophytes (n = 32) from a total of 86 ground-truth locations. The results of the water column data extraction (WCDE) show similar success, accurately predicting 78.3% of Laminaria sp. and 30.4% of A. cribrosum observations.  相似文献   
948.
The primary focus of this paper is to better understand carbon burial on the Louisiana continental margin using spatial scales that covered various shelf depositional areas far-field and near-field (sediment and organic carbon inputs relative to river mouth proximity) and covering a variety of sedimentation rates. Box-cores samples were collected in July 2003; cores were collected along two depositional transects extending westward and southward from the Southwest Pass (SW Pass). A key difference between the two transects sampled in this study was the greater occurrence of mobile muds derived from spillover from shallower regions along the westward 50 m isobaths. The dominant mechanism for mixing in the surface active zone (SAZ) on the inner Louisiana shelf was due to physical, not biological, forces. Burial efficiencies for organic carbon (57.2–91.5%) and total nitrogen (44.2–86.9%) ranged widely across all shelf stations. Lower burial efficiencies for bulk organic carbon, total nitrogen, and pigment biomarkers were associated with mobile muds west of Southwest Pass. Chlorophyll a concentrations were significantly higher than pheopigments at depth at the Mississippi River and Southwest Pass stations, making up 40.4 and 77.4% of total pigment concentrations in the (SAZ) and 46.2 and 63.2% in the accumulation zone (AZ), respectively. These results are in agreement with earlier plant pigment studies which showed that a large fraction of the phytodetritus delivered to the inner shelf was derived from coastal and river diatoms. The amount of lignin preserved with depth decreased with increasing residence time in the SAZ and diagenetic zone (DZ) along the canyon transect but not along the western transect. Trends for lignin concentration followed previously identified surface sediment trends indicating overall lower burial of refractory terrestrial material at depth with greater distance offshore.  相似文献   
949.
We studied the relationship between the dominant patterns of sea surface temperature (SST) variability in the North Pacific and the North Atlantic. The patterns are known as the Pacific Decadal Oscillation (PDO) and the Atlantic Multi-decadal Oscillation (AMO). In the analysis we used two different observational data sets for SST. Due to the high degree of serial correlation in the PDO and AMO time series, various tests were carried out to assess the significance of the correlations. The results demonstrated that the correlations are significant when the PDO leads the AMO by 1 year and when the AMO leads the PDO by 11–12 years. The possible physical processes involved are discussed, along with their potential implication for decadal prediction.  相似文献   
950.
A petrographic investigation revealed polyphase quartz cementation in the Finefrau Sandstone (Upper Carboniferous, Western Germany) and the Solling Sandstone (Lower Triassic, Central Germany). Three different cements could be distinguished in each sandstone based on their cathodoluminescence and trace element composition. The first quartz generation is suggested to have been formed during eogenesis due to dissolution and replacement of feldspar. The mesogenetic paragenesis comprises two generations of quartz and illite, which are accompanied by albite in the Solling Sandstone. Sharp luminescence zoning in quartz overgrowths points to distinct episodes of cementation in both sandstones. Significant amounts of Al, Li and H and traces of Ge and B have been detected in the quartz overgrowths. The Al‐content of the quartz cements in the Finefrau Sandstones exceeds that in the quartz cements in the Solling Sandstone by a factor of five. It is suggested that this compositional variation reflects the conditions in the pore‐water, such as temperature and pH. The Al‐concentration is generally correlated to the Li‐content with the exception of the latest quartz generation in the Finefrau Sandstones which is also most enriched in trace elements. The ratio of Li/Al varies between 0·11 and 0·25 in the two sandstones. The Li/H‐ratio, which ranges from 0·12 to 0·3, is controlled by the activity ratio of Li and H in the pore fluid. Clay minerals are the most important source for Li and high salinities favour the mobilization of Li during diagenesis. Thus, a relatively low salinity and low pH are responsible for the low Li/H‐ratio in the Finefrau Sandstone, while high salinity and neutral to alkaline pH results in a high Li/H‐ratio for the Solling Sandstone. The Ge‐contents are generally near the average of detrital quartz and indicate that pressure dissolution is a major source for quartz cementation. Different chemical compositions of distinct quartz generations indicate changes in the physico‐chemical conditions and point to mobilization of silica from different sources (for example, pressure solution and clay mineral transformations).  相似文献   
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