Determination of Chlorine Contents in Geological Survey of Japan Reference Materials by Prompt Gamma Neutron Activation Analysis     

Takashi Sano  Takaaki Fukuoka  Toshiaki Hasenaka 《Geostandards and Geoanalytical Research》2004,28(3):443-448

We determined chlorine contents in nine GSJ (Geological Survey of Japan) reference materials (JB-1, 1a, 2, 3; JA-1, 2, 3; JR-1, 2) by prompt gamma neutron activation analysis, employing the standard addition method. Pressed powder disks of each reference material were used for neutron irradiation and gammaray measurement, after known quantities (25-200 μl) of sodium chloride solution were added. The influence of the nearby sodium peak overlap was checked, and fluctuations in the chlorine count rate were corrected using silicon as an internal standard. The slopes of calibration lines for seven reference materials (JB-1, 2, 3; JA-1, 2, 3; JR-2) and SiO₂ powders fall within 5% error, and their chlorine values were obtained from the intercepts. Chlorine contents in JB-1 a and JR-1 were also determined by using the calibration lines. Our chlorine values ranged from 26.1 to 934 μg g-¹, which agrees well with the previously reported values.  相似文献   

Trace element characteristics of the fluid liberated from amphibolite-facies slab: Inference from the metamorphic sole beneath the Oman ophiolite and implication for boninite genesis   总被引：3，自引：0，他引：3  

Tsuyoshi Ishikawa  Shiori Fujisawa  Kazuya Nagaishi  Toshiaki Masuda 《Earth and Planetary Science Letters》2005,240(2):355-377

Major and trace element compositions of amphibolites and quartzose rocks in the 230-m-thick metamorphic sole underlying the mantle section of the Oman ophiolite in Wadi Tayin area were determined to investigate the chemical characteristics of the hydrous fluid released from subducted amphiboltie-facies slab. The fluid-immobile element compositions indicate that protoliths of these rocks are mid-ocean ridge basalt-like tholeiite and deep-sea chert, which is consistent with the idea that these rocks represent Tethyan oceanic crust overridden during the early, intraoceanic thrusting stage of the Oman ophiolite emplacement. The rare-earth element (REE) and high field-strength element concentrations of the amphibolites show limited variations, within a factor of two except for a few evolved samples, throughout transect of the sole. On the other hand, concentrations of fluid-mobile elements, especially B, Rb, K and Ba, in amphibolites are highly elevated in upper 30 m of the sole (> 600 °C in peak metamorphic temperature), suggesting the equilibration with evolved, B-Rb-K-Ba-rich fluids during prograde metamorphism. The comparison with amphibolites in the lower 150 m (500 to 550 °C) demonstrates that the trace element spectra of the fluids equilibrated with the high-level amphibolites may vary as a function of metamorphic temperature. The fluids are characterized by striking enrichments of B, Rb, K and Ba and moderate to minor enrichments of Sr, Li, Be and Pb. At higher temperature (up to 700 °C), the fluids become considerably enriched in light REE and Nb in addition to the above elements. The estimated trace element spectra of the fluids do not coincide with the compositions of basalts from matured intra-oceanic arcs, but satisfactorily explain the characteristics of the low-Pb andesites and boninites found in the Oman ophiolite. Compositional similarity between the boninites of Oman and other localities suggests that the fluids estimated here well represent the amphibolite-derived fluids involved in the magmatism of immatured, hot, shallow subduction zones.  相似文献   

Interactions of uranium with bacteria and kaolinite clay     

Toshihiko Ohnuki  Takahiro Yoshida  Takuo Ozaki  Mohamad Samadfam  Naofumi Kozai  Kunio Yubuta  Toshiaki Mitsugashira  Takeshi Kasama  Arokiasamy J. Francis 《Chemical Geology》2005,220(3-4):237-243

We assessed the accumulation of uranium (VI) by a bacterium, Bacillus subtilis, suspended in a slurry of kaolinite clay, to elucidate the role of microbes on the mobility of U(VI). Various mixtures of bacteria and the koalinite were exposed to solutions of 8 × 10^− 6 M- and 4 × 10^− 4 M-U(VI) in 0.01 M NaCl at pH 4.7. After 48 h, the mixtures were separated from the solutions by centrifugation, and treated with a 1 M CH₃COOK for 24 h to determine the associations of U within the mixture. The mixture exposed to 4 × 10^− 4 M U was analyzed by transmission electron microscope (TEM) equipped with EDS. The accumulation of U by the mixture increased with an increase in the amount of B. subtilis cells present at both U concentrations. Treatment of kaolinite with CH₃COOK, removed approximately 80% of the associated uranium. However, in the presence of B. subtilis the amount of U removed was much less. TEM–EDS analysis confirmed that most of the U removed from solution was associated with B. subtilis. XANES analysis of the oxidation state of uranium associated with B. subtilis, kaolinite, and with the mixture containing both revealed that it was present as U(VI). These results suggest that the bacteria have a higher affinity for U than the kaolinite clay mineral under the experimental conditions tested, and that they can immobilize significant amount of uranium.  相似文献   

The urbanization process of Bohai Rim in the 1990s by using DMSP/OLS data     

HE Chunyang  LI Jinggang  CHEN Jing  SHI Peijun  CHEN Jin  PAN Yaozhong  LI Jing  ZHUO Li  Ichinose Toshiaki 《地理学报》2006,16(2):174-182

This paper firstly derived urban information from Defense Meteorological Satellite Program/Operational Linescan System (DMSP/OLS) data in 1992, 1996 and 1998 with the support of statistical data, and then developed three basic urban models of polygon-urbanization, line-urbanization and point-urbanization in urban agglomerations from viewpoint of spatial analysis. The conclusions are as follows: (1) Urban patch numbers in the Bohai Rim increased from 1659 to 2053 with an annual average increase number of about 66. Meanwhile, the small urban patches accounted for a larger proportion in the region and the patch density increased fast. In addition, the urban barycenter of the region showed a moving trend toward northwest from 1992 to 1998. Urbanization in the Bohai Rim in the 1990s is fast and obvious. (2) Urbanization in the Bohai Rim can be reflected by three basic processes, i.e., the polygon-urbanization around the big cities, the line-urbanization around the transportation lines and the point-urbanization emerging in large areas. Of them, the polygon-urbanization has been in dominance. It is obviously within an effective range of 3-4 km surrounding the urban patches. The line-urbanization and point-urbanization in the region was relatively small, both of which showed an obvious increasing trend.  相似文献   

Determination of Ti, K, Sm and Gd Values in Geological Survey of Japan Reference Materials by Prompt Gamma Neutron Activation Analysis     

Takashi Sano  Toshiaki Hasenaka  Hiroyuki Sawahata  Takaaki Fukuoka 《Geostandards and Geoanalytical Research》2006,30(1):31-37

Prompt gamma neutron activation analysis was applied to the determination of the titanium, potassium, samarium and gadolinium contents of nine Geological Survey of Japan (GSJ) reference materials (JB-1, 1a, 2, 3; JA-1, 2, 3; JR-1, 2). Firstly, the values in JB-1 were determined by the standard addition method: pressed powder disks of JB-1 were used for neutron irradiation and gamma-ray measurements, after known quantities of standard reagents had been added. Secondly, the contents of eight other reference materials were determined by comparison methods using JB-1 as the comparative standard. The precision of analyses were obtained by replicate determinations on these samples. The relative standard deviation was generally less than 5%. For most samples, analysed values agreed well (< 5%) with the recommended values.  相似文献   

Very high-density carbonic fluid inclusions in sapphirine-bearing granulites from Tonagh Island in the Archean Napier Complex, East Antarctica: implications for CO2 infiltration during ultrahigh-temperature (T>1,100 °C) metamorphism     

Toshiaki Tsunogae  M. Santosh  Yasuhito Osanai  Masaaki Owada  Tsuyoshi Toyoshima  Tomokazu Hokada 《Contributions to Mineralogy and Petrology》2002,143(3):279-299

The ultrahigh-temperature (UHT) metamorphism of the Napier Complex is characterized by the presence of dry mineral assemblages, the stability of which requires anhydrous conditions. Typically, the presence of the index mineral orthopyroxene in more than one lithology indicates that H₂O activities were substantially low. In this study, we investigate a suite of UHT rocks comprising quartzo-feldspathic garnet gneiss, sapphirine granulite, garnet-orthopyroxene gneiss, and magnetite-quartz gneiss from Tonagh Island. High Al contents in orthopyroxene from sapphirine granulite, the presence of an equilibrium sapphirine-quartz assemblage, mesoperthite in quartzo-feldspathic garnet gneiss, and an inverted pigeonite-augite assemblage in magnetite-quartz gneiss indicate that the peak temperature conditions were higher than 1,000 °C. Petrology, mineral phase equilibria, and pressure-temperature computations presented in this study indicate that the Tonagh Island granulites experienced maximum P-T conditions of up to 9 kbar and 1,100 °C, which are comparable with previous P-T estimates for Tonagh and East Tonagh Islands. The textures and mineral reactions preserved by these UHT rocks are consistent with an isobaric cooling (IBC) history probably following an counterclockwise P-T path. We document the occurrence of very high-density CO₂-rich fluid inclusions in the UHT rocks from Tonagh Island and characterize their nature, composition, and density from systematic petrographic and microthermometric studies. Our study shows the common presence of carbonic fluid inclusions entrapped within sapphirine, quartz, garnet and orthopyroxene. Analysed fluid inclusions in sapphirine, and some in garnet and quartz, were trapped during mineral growth at UHT conditions as 'primary' inclusions. The melting temperatures of fluids in most cases lie in the range of -56.3 to -57.2 °C, close to the triple point for pure CO₂ (-56.6 °C). The only exceptions are fluid inclusions in magnetite-quartz gneiss, which show slight depression in their melting temperatures (-56.7 to -57.8 °C) suggesting traces of additional fluid species such as N₂ in the dominantly CO₂-rich fluid. Homogenization of pure CO₂ inclusions in the quartzo-feldspathic garnet gneiss, sapphirine granulite, and garnet-orthopyroxene gneiss occurs into the liquid phase at temperatures in the range of -34.9 to +4.2 °C. This translates into very high CO₂ densities in the range of 0.95-1.07 g/cm³. In the garnet-orthopyroxene gneiss, the composition and density of inclusions in the different minerals show systematic variation, with highest homogenization temperatures (lowest density) yielded by inclusions in garnet, as against inclusions with lowest homogenization (high density) in quartz. This could be a reflection of continued recrystallization of quartz with entrapment of late fluids along the IBC path. Very high-density CO₂ inclusions in sapphirine associated with quartz in the Tonagh Island rocks provide potential evidence for the involvement of CO₂-rich fluids during extreme crustal temperatures associated with UHT metamorphism. The estimated CO₂ isochores for sapphirine granulite intersect the counterclockwise P-T trajectory of Tonagh Island rocks at around 6-9 kbar at 1,100 °C, which corresponds to the peak metamorphic conditions of this terrane derived from mineral phase equilibria, and the stability field of sapphirine + quartz. Therefore, we infer that CO₂ was the dominant fluid species present during the peak metamorphism in Tonagh Island, and interpret that the fluid inclusions preserve traces of the synmetamorphic fluid from the UHT event. The stability of anhydrous minerals, such as orthopyroxene, in the study area might have been achieved by the lowering of H₂O activity through the influx of CO₂ at peak metamorphic conditions (>1,100 °C). Our microthermometric data support a counterclockwise P-T path for the Napier Complex.  相似文献   

Statistical characteristics of the dynamical structure in flat galaxies     

M. Miyamoto  C. Satoh  M. Ohashi 《Astrophysics and Space Science》1980,67(1):147-171

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Bio-Optical Relationship of Case I Waters: The Difference between the Low- and Mid-Latitude Waters and the Southern Ocean     

Toru Hirawake  Hiroo Satoh  Takashi Ishimaru  Yukuya Yamaguchi  Motoaki Kishino 《Journal of Oceanography》2000,56(3):245-260

Both historic and currently operational chlorophyll algorithms of the satellite-borne ocean color sensors, such as SeaWiFS, were evaluated for in situ spectral radiation and chlorophyll data in some Case I waters, including the waters in the Indian Ocean sector of the Southern Ocean. Chlorophyll a concentration of the data set (n = 73) ranged from 0.04 to 1.01 mg m^–3. The algorithms had higher accuracy for the low- and mid-latitude waters (RMSE: 0.163–0.253), specifically the most recently developed algorithms of OCTS and Sea WiFS showed 0.163 and 0.170 of Root Mean Square Errors, respectively. However, these algorithms had large errors (0.422–0.621) for the Southern Ocean data set and underestimated the surface chlorophyll by more than a factor of 2.6. The absorption coefficients in the blue spectral region retrieved from remote sensing reflectance varied in a nonlinear manner with chlorophyll a concentration, and the value in the Southern Ocean was significantly lower than that in the low- and mid-latitude waters for each chlorophyll a concentration. The underestimation of chlorophyll a concentration in the Southern Ocean with these algorithms was caused by the lower specific absorption coefficient in the region compared with the low- and mid-latitude waters under the same chlorophyll a concentration.  相似文献   

Rapid development of arctic cyclone in June 2008 simulated by the cloud resolving global model NICAM     

Takuro Aizawa  H. L. Tanaka  Masaki Satoh 《Meteorology and Atmospheric Physics》2014,126(3-4):105-117

In this study, we conducted a numerical simulation of a rapid development of an arctic cyclone (AC) that appeared in June 2008 using a cloud resolving global model, Nonhydrostatic ICosahedral Atmospheric Model (NICAM). We investigated the three dimensional structure and intensification mechanism of the simulated AC that developed to the minimum sea level pressure of 971 hPa in the model. According to the result, the AC indicates a barotropic structure with a warm core in the lower stratosphere and a cold core in the troposphere. The development of the AC is accompanied by an intense mesoscale cyclone (MC) showing baroclinic structure with a marked local arctic front. The upper level warm core of the AC is formed by an adiabatic heating associated with the downdraft in the lower stratosphere. The rapid development of the AC is caused by the combination of the intensification of the upper level warm core and the merging with the baroclinically growing MC in the lower level. The merging of the AC and MC and the vertical vortex coupling with the upper air polar vortex are the most important mechanisms for the rapid development of the arctic cyclone.  相似文献   

The influences of various anthropogenic sources of deterioration on meiobenthos (Ostracoda) over the last 100 years in Suo-Nada in the Seto Inland Sea, southwest Japan     

Irizuki T  Takimoto A  Sako M  Nomura R  Kakuno K  Wanishi A  Kawano S 《Marine pollution bulletin》2011,62(10):2030-2041

This study focuses on the relationships of water and sediment quality with meiobenthos (Ostracoda) over the past 100 years, using a sediment core obtained from Suo-Nada in the Seto Inland Sea, Japan. We compared high-resolution ostracode results with geochemical and sedimentological data obtained from the study core as well as with rich environmental monitoring data that are available. R-mode cluster analysis revealed two bioassociations (BC, KA). Until the1960s, assemblages continued to show high diversity. They changed in approximately 1970, when excessive nutrients and organic matter began to be supplied, and most species decreased in number. All species of bioassociation BC were dominant again by the mid-1990s; however, those of bioassociation KA containing infaunal species did not increase and have been absent or rare since the 1970s because organic pollution of sediments has continued to date. This study provided robust baseline for ostracode-based long-term environmental monitoring in East Asia.  相似文献