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在人体胃肠液的酸度条件下,采用正辛醇-水分配体系模拟药物在人体肠胃中的分配情况,研究了中药和补铁制剂中铁的形态及其在人体内的吸收情况,并探讨了中药不同比例的配伍、胃肠酸度及还原性物质的存在对水溶态铁和醇溶态铁的影响。结果表明,药物溶液中的铁形态与药物本身特性和配伍情况有关,酸度及配伍对药物中铁的溶出率和溶液中铁的形态有较大影响,人体对铁的吸收与胃肠酸度和还原性物质的存在有关。 相似文献
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由于取心成本昂贵, 从岩心中获得天然缝、诱导缝和其他构造特征的准确信息显得尤为重要。岩心裂缝识别中的一项重要任务是判识天然缝和诱导缝。文中综合论述了天然缝和诱导缝的物理特征, 重点分析了天然缝形态及发育过程和诱导缝的多种成因模式, 并以鄂尔多斯盆地延长组岩心中裂缝为例进行分析。文中引用了国外对裂缝研究常用的专业术语, 指出裂缝面形态结构是追踪模式Ⅰ裂缝(节理)从扩展初始点到终止处的运动学的关键, 这在岩心裂缝和露头裂缝分析中是非常有用的。 相似文献
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通过Crust 2.0模型构建有限元三维数值模型,以地表观测温度、深部反演温度和地表热流作为约束,计算了长江经济带地区岩石圈温度结构;在温度结构的基础上,通过GPS观测数据得到的地表应变率和选取代表性岩石物性,计算了长江经济带岩石圈流变强度和等效粘滞性系数。结果表明:长江经济带地区岩石圈表现出明显的横向不均匀性,其中四川盆地表现为低温、高强度和高粘滞性的特征,相同深度,四川盆地核心区比周围地块的温度低100~300℃,强度和粘滞性分别比周缘高1~2个数量级;在温度、强度和粘滞性的过渡地带构造活动性比较强烈。结合深部地球物理观测综合分析认为,长江经济带东、西部分别受到太平洋板块深俯冲和印度-欧亚大陆板块碰撞的影响,其深部影响范围分别达到四川盆地的东、西边界,深部动力学过程可能导致了岩石圈的横向不均匀性。 相似文献
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海南岛位于我国最南端,地下潜水有松散岩类孔隙潜水、火山岩类裂隙孔洞水、碳酸盐岩类裂隙溶洞水和基岩裂隙水四种基本类型。采用DRASTIC评价方法,对区内地下潜水的污染状况进行了调查评价,并将其防污性能划分为4个等级区：防污性能较好、防污性能中等、防污性能一般、防污性能较差。提出了在定区域内禁止一切不能引起地下水污染的活动,消灭污染源等措施。 相似文献
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海南岛位于我国环太平洋构造--岩浆成矿带的重要地段。根据岩石和同位素特征分析,认为海南岛海西—印支期的中酸性侵入岩可分为S型和I型两种成因的花岗岩,燕山期为I型花岗岩。由于复式岩体多次多阶段侵位,晚阶段的岩浆活动对早阶段岩石进一步改造并溶萃其中的成矿物质,形成大量的富含成矿物质的流体,构造应力体制转换及反复多次应力集中—释放过程式,在有利的空间位置成矿。根据中酸性侵入岩的控矿作用和对海南岛成矿规律的认识及DPIS成矿预测系统对岛内成矿远景区的预测,划分了与中酸性侵入岩有关矿床的成矿远景区,指明了多金属矿找矿方向。 相似文献
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热液金矿成矿元素运移和沉淀机理研究综述 总被引：2，自引：0，他引：2
对热液金矿含金热液的流体来源、金的赋存形式、金的迁移和沉淀机理进行了总结。岩浆热液、大气水及变质热液是含金热液的主要来源。金的迁移过程与金的赋存状态有较为密切的关系。金以热液迁移为主,金在热液中的赋存形式主要为金-硫络合物及金-氯络合物,这其中最为重要的是Au(HS)2-、AuHS以及AuCl2-。但是对火山气体及含金流体包裹体的研究表明,金还可以通过气体的方式迁移,并有可能形成具有经济意义的矿床。金在气体中的主要赋存形式为AuCl.(H2O)3-5和AuS.(H2S)1-2或者是AuHS.(H2S)1-2,其溶解度与气体中H2O、HCl和H2S的逸度成正比。CO2对金的迁移也具有重要作用,能够使金迁移得更远。纳米金的发现,拓宽了找金思路并进一步证明了气体及胶体对金迁移的重要性。金的沉淀与含金介质物理化学条件的改变有关,其主要沉淀机制包括:①温压条件的改变;②流体沸腾及相分离;③流体-围岩反应及流体混合。 相似文献
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The acidic and neutral NSO compounds in a series of Duvernay-sourced oils in Canada, which are believed to have migrated extensively over relatively long distances such as along the Rimbey-Meadowbrook reef trends, were characterized by negative-ion electrospray (ESI) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). Heteroatomic compounds were characterized according to their class (number of nitrogen, oxygen and sulfur heteroatoms), degree of aromaticity [rings plus double bonds (DBE)] and carbon number distribution. The N1, N1O1, N1O2, N1S1, O1 and O2 classes were identified in Duvernay-sourced oils. With increasing migration distance, the relative abundance of O2, N1O1 and N1O2 showed a significant decrease, while the O1 class increased from < 10% to nearly 30% of the total. With increasing migration along the Rimbey-Meadowbrook reef trend, pyrrolic nitrogen compounds (N1 class) shows an enrichment of alkylcarbazoles (DBE = 9) relative to alkylbenzocarbazoles (DBE = 12), and of higher homologous relative to the lower homologous. O1 compounds show a relative enrichment of those with low DBE values. Additionally, the N1O1 and N1S1 compounds show a relative enrichment of those with high DBE values, and of higher homologues compared to the lower homologues, indicating great potential for developing new migration indices. 相似文献
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We have examined, using a 12 Tesla FTICR-MS instrument, the impact of varying thermal maturity level on a suite of 9 related crude oils charged from source rocks covering most of the liquid petroleum generating portion of the oil window (0.68–1.11% vitrinite reflectance equivalent (%Re)). The sample suite was analyzed as whole oils under three different conditions, electrospray ionization (ESI) in positive and negative ion mode to analyze basic and acidic components, respectively, and atmospheric pressure photoionization (APPI) in positive ion mode, for sulfur and hydrocarbon species.Increasing oil maturity level had a strong influence on the composition of all compound classes in the oils with several major observations evident:The relative apparent abundances of all heteroatom containing compound classes detected in this study, using all ionization modes, decrease systematically with increasing oil maturation levels. Both aromatic hydrocarbons, detectable in APPI mode, and NSO compound classes (detectable in both ESI and APPI modes), as broad classes, are becoming more aromatic (shift to a greater predominance of higher DBE group members) and dealkylated (decreasing average molecular mass of individual compound groups), with increasing maturation level in the oil suite. Several putative oil maturity level dependent, molecular ratios were identified in the study. Of particular note, the relative abundance ratios of heteroatom compound classes tentatively identified as alkylated carbazoles, quinolines and benzothiophenes, compared to their benzannulated homologues are very sensitive to maturation level. Several groups of compounds show interesting and specific carbon number distributions, suggesting there may be hints of specific molecular markers in the FTICR-MS data. One observation of note is the strong increase in the relative abundance of protonated hydrocarbon components with DBE 5. We speculate this might reflect the presence of previously unreported higher molecular weight diamondoid (diamantane) species in oils with up to 40 carbon atoms or more, at advanced maturity levels. Such species may prove very valuable as molecular markers in highly mature fluids, such as those currently being produced from some shale reservoirs. Covariation of quantitative GC–MS data for alkylated hetero aromatic sulfur and nitrogen compounds in this oil suite, together with the corresponding FTICR-MS data from compounds believed to be, based on accurate mass, alkylated sulfur and alkylated nitrogen compounds, suggests that FTICR-MS already has some very rudimentary quantitation capabilities. 相似文献
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