Absorption and desorption of dichloromethane vapor by water drops in air. An experimental test of scavenging theory     

S. Lopez  J. H. Topalian  S. K. Mitra  D. C. Montague 《Journal of Atmospheric Chemistry》1989,8(2):175-188

An experimental study of the scavenging of dichloromethane vapor by water drops falling at terminal velocity, has been carried out in the UCLA precipitation shaft, in order to test the predictions of theoretical washout models. Whereas good agreement between theory and experiment was found for drops of radius 0.332 mm, computed gas uptake rates for 1.253 and 2.21 mm radius drops were much slower than those measured, just as reported previously for the washout of both sulfur dioxide and acetaldehyde. An analysis shows that theory can be reconciled with all of the experimental data by replacing the compound specific aqueous phase Fickian molecular diffusion coefficient used in the theory, by an effective diffusivity, having a constant value, (3×10^-4 cm² s^-1), independent of the physical and chemical nature of the absorbed species, for all drops of equivalent radii greater than 0.9 mm.  相似文献   

Holocene moraine and paleosol stratigraphy, Bugaboo Glacier, British Columbia   总被引：3，自引：0，他引：3  

GERALD OSBORN  ERIC T. KARLSTROM 《Boreas: An International Journal of Quaternary Research》1989,18(4):311-322

Sequences of tills, buried paleosols, wood and tephra in lateral moraines provide a record of Holocene advances and retreats of the Bugaboo Glacier in British Columbia. The oldest paleosol is tentatively classified as a Spodosol (Cryorthod). It incorporates Mazama tephra (6,800 B.P.) and charcoal and humus dated at 3,390 and 4.400B.P., respectively, and records early and middle Holocene warming and/or drying. This paleosol overliesa latest Pleistocene or early Holocene till associated with a nearby end moraine and assigned to the regionally known 'Crowfoot Advance'. Less-developed paleosols (Cryumbrepts) are formed on Neoglacial tills deposited shortly before 3,000 B. P., between c. 2,500 to 1,900 B. P., and between c. 900 B.P. and the 19th century. The paleosols and surface soils form microcatenas with morphological variations due to differences in original topography and vegetation. The chronology derived from these paleosols and tills generally agrees with, but increases the resolution of, what is known of Holocene glacier histories in the Canadian Cordillera.  相似文献   

Depositional framework and controls on mixed carbonate-siliciclastic gravity flows: Pennsylvanian-Permian shelf to basin transect, south-western Great Basin, USA   总被引：1，自引：0，他引：1  

ROBERT P. MILLER  PAUL L. HELLER 《Sedimentology》1994,41(1):1-20

Mixed carbonate-siliciclastic sediment gravity flow deposits of Late Pennsylvanian to Early Permian age are exposed in the Death Valley - Owens Valley region of east-central California. The Mexican Spring unit constitutes the upper part of the Keeler Canyon Formation and is characterized by turbidites, debris flow deposits and megabreccias, all of mixed carbonate-siliciclastic composition. The mixed composition of the Keeler Canyon Formation provides an opportunity to link facies architecture to controls on depositional system development. Depositional relationships indicate that the deposits represent a non-channellized base of slope carbonate apron system with inner, outer and basinal facies associations. These gravity flow deposits are characterized by repeated stacked, small scale (<15 m) coarsening and thickening upward cycles with superimposed medium scale (>100 m) coarsening and thickening upward cycles. Contemporaneous outer shelf and upper slope deposits of the Tippipah Limestone are exposed at Syncline Ridge on the Nevada Test Site. The deposits consist of carbonate buildups directly overlain by cross bedded, quartz-rich sandstone and conglomerate which filled channels that traversed across the previously existing carbonate shelf. Detritus was transported to the west, down the upper slope by gully systems that fed the temporally persistent base of slope apron of the upper part of the Keeler Canyon Formation. This style of deposition differs from point-sourced siliciclastic submarine fan depositional systems. However, the Keeler Canyon system has lithofacies similar to some sandy siliciclastic turbidite systems, such as the delta-fed submarine ramp facies model, which is a line-sourced, shelf-fed system that is not supply limited. The mixed clastic apron systems of the Keeler Canyon Formation differ from classical carbonate aprons in that the former is characterized by an abundance of sedimentary cycles. Controls on the development of these cycles and of the facies distribution may have resulted from changes in type and rate of sediment supply, relative sea level changes and/or tectonic events. Interpretation of the data is focused on relative changes in sea level as the most significant control on development of the depositional system. Relative sea level changes serve two important functions: (1) they provide a mechanism for bringing coarse siliciclastic and bioclastic grains together on the outer shelf, and (2) shelf margin collapse may be initiated during relative lowstands allowing for transport of the sediment to the deep basin and development of deep basinal cycles. Therefore, an abundance of mixed clastic gravity flow deposits such as these in the rock record may be an indicator of periods of high frequency changes in relative sea level, which is a characteristic of Late Palaeozoic sea level history.  相似文献   

Roberts Rift, Canyonlands, Utah, A Natural Hydraulic Fracture Caused by Comet or Asteroid Impact     

Peter W. Huntoon  Eugene M. Shoemaker 《Ground water》1995,33(4):561-569

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An investigation of ulvospinel composition and cation migration during maghemitization in DSDP,Leg 61, titanomagnetites     

M.B. Steiner 《Physics of the Earth and Planetary Interiors》1982,30(4):331

Titanomagnetites of basalts and diorites from an off-axis volcanic episode in the Pacific Ocean (Leg 61, DSDP) were studied for their ulvospinel composition and for changes in the iron-titanium ratio with progressive low-temperature oxidation. Thermomagnetic analysis and microscopy indicate that these Fe/Ti spinels show relatively little low-temperature oxidation, despite their Cretaceous age. Microprobe investigation shows that the Fe/Ti spinels have a wide range of ulvospinel content directly reflecting the range of parent rock chemistries. This is an important demonstration that ulvospinel contents are not constant but vary within a restricted range of compositions, namely at least x =0.5 to x=0.75 (Fe_2?xTi_xO₄). Recognition of this fact is important in attempting to elucidate changes in cation ratio as a result of progressive low-temperature oxidation.Examination of samples of different oxidation states for cation ratio changes as a result of low-temperature oxidation revealed lower titanium in the more oxidized samples and Ti enrichment in the less oxidized ones. This is probably a reflection of changing x values with progressive crystallization of individual sills, and thus unrelated to cation ratio changes with oxidation.In more than 100 grains analyzed, no evidence was found for a more oxidized shell on the exteriors of grains, suggesting that the oxidation process did not proceed uniformly with respect to grain geometry.  相似文献   

The system Fe-Si-O: Oxygen buffer calibrations to 1,500K   总被引：1，自引：0，他引：1  

J. Myers  H. P. Eugster 《Contributions to Mineralogy and Petrology》1983,82(1):75-90

The five solid-phase oxygen buffers of the system Fe-Si-O, iron-wuestite (IW), wuestite-magnetite (WM), magnetite-hematite (MH), quartz-iron-fayalite (QIF) and fayalite-magnetite-quartz (FMQ) have been recalibrated at 1 atm pressure and temperatures from 800°–1,300° C, using a thermogravimetric gas mixing furnace. The oxygen fugacity, \(f_{{\text{O}}_{\text{2}} }\) was measured with a CaO-doped ZrO₂ electrode. Measurements were made also for wuestite solid solutions in order to determine the redox behavior of wuestites with O/Fe ratios varying from 1.05 to 1.17. For FMQ, additional determinations were carried out at 1 kb over a temperature range of 600° to 800° C, using a modified Shaw membrane. Results agree reasonably well with published data and extrapolations. The reaction parameters K, ΔG _r ^o , ΔH _r ^o , and ΔS _r ^o were calculated from the following log \(f_{{\text{O}}_{\text{2}} }\) /T relations (T in K): $$\begin{gathered} {\text{IW }}\log f_{{\text{O}}_{\text{2}} } = - 26,834.7/T + 6.471\left( { \pm 0.058} \right) \hfill \\ {\text{ }}\left( {{\text{800}} - 1,260{\text{ C}}} \right), \hfill \\ {\text{WM }}\log f_{{\text{O}}_{\text{2}} } = - 36,951.3/T + 16.092\left( { \pm 0.045} \right) \hfill \\ {\text{ }}\left( {{\text{1,000}} - 1,300{\text{ C}}} \right), \hfill \\ {\text{MH }}\log f_{{\text{O}}_{\text{2}} } = - 23,847.6/T + 13.480\left( { \pm 0.055} \right) \hfill \\ {\text{ }}\left( {{\text{1,040}} - 1,270{\text{ C}}} \right), \hfill \\ {\text{QIF }}\log f_{{\text{O}}_{\text{2}} } = - 27,517.5/T + 6.396\left( { \pm 0.049} \right) \hfill \\ {\text{ }}\left( {{\text{960}} - 1,140{\text{ C}}} \right), \hfill \\ {\text{FMQ }}\log f_{{\text{O}}_{\text{2}} } = - 24,441.9/T + 8.290\left( { \pm 0.167} \right) \hfill \\ {\text{ }}\left( {{\text{600}} - 1,140{\text{ C}}} \right). \hfill \\ \end{gathered}$$ These experimentally determined reaction parameters were combined with published 298 K data to determine the parameters G_f, H_f, and S_f for the phases wuestite, magnetite, hematite, and fayalite from 298 K to the temperatures of the experiments. The T? \(f_{{\text{O}}_{\text{2}} }\) data for wuestite solid solutions were used to obtain activities, excess free energies and Margules mixing parameters. The new data provide a more reliable, consistent and complete reference set for the interpretation of redox reactions at elevated temperatures in experiments and field settings encompassing the crust, mantle and core as well as extraterrestrial environments.  相似文献   

A statistical method to evaluate homogeneity of structural populations     

Stanley M. Miller 《Mathematical Geosciences》1983,15(2):317-328

For any specific rock unit in a discontinuous rock mass, the determination of structural domain boundaries is important because geologic and hydrologic properties vary from one domain to another. A domain can be considered as a structural population characterized by a distinct pattern of structure orientations (i.e., fracture, bedding, or foliation orientations).Boundaries are usually determined by comparing samples of structural data, each of which consists of a Schmidt plot that commonly displays at least 150 poles to fractures. When fracture orientations appear dispersed and random on the plots, visual comparisons are not sufficient to determine whether the samples were obtained from the same structural domain. An appropriate x ² test has been adapted to this situation and is capable of evaluating the homogeneity of structural populations. The method uses a contingency table analysis based on the frequencies of fracture poles that occur in corresponding patches on the Schmidt plots being compared.  相似文献   

The weathering of a late Tertiary volcanic ash: Importance of organic solutes     

Ronald C. Antweiler  James I. Drever 《Geochimica et cosmochimica acta》1983,47(3):623-629

The weathering of a late Tertiary volcanic ash near Jackson, Wyoming, was studied by sampling water percolating through the ash with suction lysimeters, and by examination of the associated solid phases. Soluble organic compounds derived from vegetation control the release and transport of solutes by complexing Al and Fe, and by causing low pH values. The concentrations of Na, K, Ca, and Mg, as well as those of Al and Fe correlate with the dissolved organic carbon concentrations (DOC) and follow an annual cycle with a maximum in spring. DOC concentrations averaged 5O mg C per liter, and values as high as 260 mg/l were observed. Al and Fe concentrations ranged as high as 5 mg/l. The dissolved organic matter was largely in the form of humic acids, although minor amounts of oxalate, acetate, and formate were also present. The pH of the percolating waters ranged from 4.3 to 6.5 with a mean of 5.2.During laboratory weathering experiments with the same ash in the absence of dissolved organic compounds, pH values ranged from 7.3 to 9.5, dissolved Al and Fe concentrations were below the detection limit, and there was little resemblance between the compositions of the solutions and the compositions observed in the field. Any model attempting to describe weathering in a comparable setting must incorporate biological mechanisms as the dominant controls.  相似文献   

A comparative allometric study of the morphometry of the gills of an alkalinity adapted cichlid fish,Oreochromis alcalicus grahami,of Lake Magadi,Kenya     

J. N. Maina  S. M. Kisia  C. M. Wood  A. B. Narahara  H. L. Bergman  P. Laurent  P. J. Walsh 《International Journal of Salt Lake Research》1996,5(2):131-156

A morphometric analysis of the gills ofOreochromis alcalicus grahami has been carried out on specimens from ecologically distinct lagoons and a water-holding tank of Lake Magadi, a highly alkaline salt lake situated in a volcanically active region of the southern part of the Great Rift Valley in Kenya. The data were compared with those fromOreochromis niloticus, a close relative that lives in fresh water and with data from other fresh water and marine fish. Our primary goal was to identify the possible adaptive features which enable the fish to survive in an environment characterized by severely fluctuating levels of oxygen, a condition exacerbated by factors such as high temperature, alkalinity and osmolarity. The specimens ofO. a. grahami from the south-western lagoons of the lake had gills better adapted for gas exchange with a body mass specific diffusing capacity for oxygen which was about 2 times greater than that of the gills of the specimens from the fish spring lagoons and 2.5 times that of those from the water-holding tanks. Some parameters of the gills ofO. a. grahami, e.g. the gill filament length and number of gill filaments are significantly greater than those ofO. niloticus but the number of secondary lamellae, area of secondary lamellae and the diffusing capacity of the gills are similar in the two species. Compared with most other fish, the gills ofO. a. grahami appear to be particularly well adapted for gas exchange especially by having a thin water-blood barrier. Perhaps in no other extant fish have the gills had to be so exquisitely designed to meet environmental extremes and regulate complex and at times conflicting functions such as gas exchange, iono-regulation, acid-base balance and nitrogenous waste excretion as inO. a. grahami  相似文献   

Evidence for temporal variations of coronal emission line intensity and profile     

D. H. Liebenberg  R. J. Bessey  B. Watson 《Solar physics》1976,50(1):109-112

The time sequence of line profiles of Fe xiv emission obtained at the 1965 solar eclipse is examined for temporal variations of intensity and profile. Although no variations are found in some regions examined, two regions with intensity and profile line width variations are found. A simple temperature wave is consistent with observations.Work performed under the auspices of the U.S. Energy Research and Development Administration.Work accomplished at the Department of Physics and Astronomy, University of Wyoming, Laramie, Wyoming.  相似文献