Evidence of technetium and iodine release from a sodalite-bearing ceramic waste form     

《Applied Geochemistry》2016

Sodalites have been proposed as a possible host of certain radioactive species, specifically ⁹⁹Tc and ¹²⁹I, which may be encapsulated into the cage structure of the mineral. To demonstrate the ability of this framework silicate mineral to encapsulate and immobilize ⁹⁹Tc and ¹²⁹I, single-pass flow-through (SPFT) tests were conducted on a sodalite-bearing multi-phase ceramic waste form produced through a steam reforming process. Two samples made using a steam reformer samples were produced using non-radioactive I and Re (as a surrogate for Tc), while a third sample was produced using actual radioactive tank waste containing Tc and added Re. One of the non-radioactive samples was produced with an engineering-scale steam reformer while the other non-radioactive sample and the radioactive sample were produced using a bench-scale steam reformer. For all three steam reformer products, the similar steady-state dilute-solution release rates for Re, I, and Tc at pH (25 °C) = 9 and 40 °C were measured. However, it was found that the Re, I, and Tc releases were equal or up to 4.5x higher compared to the release rates of the network-forming elements, Na, Al, and Si. The similar releases of Re and Tc in the SPFT test, and the similar time-dependent shapes of the release curves for samples containing I, suggest that Re, Tc, and I partition to the sodalite minerals during the steam reforming process.  相似文献   

Contamination,bioaccessibility and human health risk of heavy metals in exposed-lawn soils from 28 urban parks in southern China's largest city,Guangzhou     

《Applied Geochemistry》2016

The total concentrations and oral bioaccessibility of heavy metals in surface-exposed lawn soils from 28 urban parks in Guangzhou were investigated, and the health risks posed to humans were evaluated. The descending order of total heavy metal concentrations was Fe > Mn > Pb > Zn > Cu > Cr > Ni > Cd, but Cd showed the highest percentage bioaccessibility (75.96%). Principal component analysis showed that Grouped Cd, Pb, Cr, Ni, Cu and Zn, and grouped Cr and Mn could be controlled two different types of human sources. Whereas, Ni and Fe were controlled by both anthropogenic and natural sources. The carcinogenic risk probabilities for Pb and Cr to children and adults were under the acceptable level (<1 × 10⁻⁴). Hazard Quotient value for each metal and Hazard Index values for all metals studied indicated no significant risk of non-carcinogenic effects to children and adults in Guangzhou urban park soils.  相似文献   

Reactivity of micas and cap-rock in wet supercritical CO2 with SO2 and O2 at CO2 storage conditions     

《Applied Geochemistry》2016

Seal or cap-rock integrity is a safety issue during geological carbon dioxide capture and storage (CCS). Industrial impurities such as SO₂, O₂, and NOx, may be present in CO₂ streams from coal combustion sources. SO₂ and O₂ have been shown recently to influence rock reactivity when dissolved in formation water. Buoyant water-saturated supercritical CO₂ fluid may also come into contact with the base of cap-rock after CO₂ injection. Supercritical fluid-rock reactions have the potential to result in corrosion of reactive minerals in rock, with impurity gases additionally present there is the potential for enhanced reactivity but also favourable mineral precipitation.The first observation of mineral dissolution and precipitation on phyllosilicates and CO₂ storage cap-rock (siliciclastic reservoir) core during water-saturated supercritical CO₂ reactions with industrial impurities SO₂ and O₂ at simulated reservoir conditions is presented. Phyllosilicates (biotite, phlogopite and muscovite) were reacted in contact with a water-saturated supercritical CO₂ containing SO₂, or SO₂ and O₂, and were also immersed in the gas-saturated bulk water. Secondary precipitated sulfate minerals were formed on mineral surfaces concentrated at sheet edges. SO₂ dissolution and oxidation resulted in solution pH decreasing to 0.74 through sulfuric acid formation. Phyllosilicate dissolution released elements to solution with ∼50% Fe mobilized. Geochemical modelling was in good agreement with experimental water chemistry. New minerals nontronite (smectite), hematite, jarosite and goethite were saturated in models. A cap-rock core siltstone sample from the Surat Basin, Australia, was also reacted in water-saturated supercritical CO₂ containing SO₂ or in pure supercritical CO₂. In the presence of SO₂, siderite and ankerite were corroded, and Fe-chlorite altered by the leaching of mainly Fe and Al. Corrosion of micas in the cap-rock was however not observed as the pH was buffered by carbonate dissolution. Ca-sulfate, and Fe-bearing precipitates were observed post SO₂-CO₂ reaction, mainly centered on surface cracks and an illite rich illite-smectite precipitate quantified. Water saturated impure supercritical CO₂ was observed to have reactivity to rock-forming biotite, muscovite and phlogopite mineral separates. In the cap-rock core however carbonates and chlorite were the main reacting minerals showing the importance of assessing actual whole core.  相似文献   

Sulfur speciation with high performance liquid chromatography as a tool for El Chichón volcano,crater lake monitoring     

《Journal of South American Earth Sciences》2016

The monitoring of sulfur species in crater lakes has proven to be useful for forecasting episodes of volcanic unrest in certain active volcanoes, including Poás, Costa Rica; Kusatsu-Shirane, Japan; and Mt. Ruapehu, New Zealand. In this study, we have improved the current geochemical monitoring of El Chichón volcano through the setting of optimal high-performance liquid chromatography conditions (HPLC) for the analysis of S²⁻, SO₃²⁻, S₂O₃²⁻, S₄O₆²⁻ and SO₄²⁻ using a common chromatographic system. The procedure was applied to the analysis of lake samples taken in March, July and October of 2014 and April of 2015. The results were promising, since nearly all species were detected (with the exception of S₂O₃²⁻) in measurable amounts, including S²⁻ (<0.85–5.05 mg/L), SO₃²⁻ (<2.77–26.1 mg/L), S₄O₆²⁻ (108.27–303.82 mg/L) and SO₄²⁻ (489.58–676.26 mg/L). The spatial distribution of these species along the lakeshore showed zones of increased concentrations to the east and southeast of the lake, which provides information on the distribution of faults or cracks that feed hydrothermal fluids to the lake. This method thus provides additional information linked to the volcanic and hydrothermal activity of the volcano.  相似文献   

镇雄赵家沟滑坡特征及基于坡体结构的失稳机理研究     

曾庆利  王炜风  陈宏宇  薛鑫宇  袁广祥 《工程地质学报》2016,24(4):510-518

2013年1月11日云南省镇雄县发生特大山体滑坡灾害,造成赵家沟村民小组46人遇难和严重经济损失。基于数次滑坡现场调查和勘查所获得的基础数据,本文对滑坡特征及变形失稳机理进行了较系统的研究。（1）滑坡发育在崩坡积体中,坡体自后缘向前缘具有黏粒含量、密实度增加而孔隙度、透水性减小的特点;（2）滑坡后缘为飞仙关组强风化粉砂岩与崩坡积体的接触界面,滑动带为崩坡积体内含砾粉质黏土坡积层;（3）滑坡发生前,坡体后缘已发育张拉裂缝,前缘已发生小型鼓胀破坏,属典型蠕滑-拉裂变形破坏模式;（4）滑坡具有分块先后滑动特点,左、右及后缘边界坡体在主滑体后发生滑动,滑移过程中也存在分区现象;（5）滑带土为低液限含砾黏性土,呈液化流塑状态,抗剪强度低;（6）启程高速是斜坡应变能长期积累、瞬间释放的结果,滑程高速与滑坡体冲击液化有关,部分滑体存在临空飞行现象。建议加强滑源区两侧裂缝的变形监测和乌蒙山区类似坡体的灾害预警。  相似文献   

河岸带潜流层温度示踪流速计算方法          下载免费PDF全文

李英玉  赵坚  吕辉  陈斌 《水科学进展》2016,27(3):423-429

为揭示低温水影响下的河岸带潜流层的温度场和流场分布特性,利用野外水温水位实时监测试验,研究河岸带潜流层温度场在不同季节、不同空间位置上的分布特性,并利用水温资料计算获得地下水流速。结果表明:河岸带潜流层温度场在夏季和冬季分别呈现出"上暖下冷"和 "上冷下暖"的温度分层现象;通过对温度示踪方法的4种计算方法进行分析比较,得到Hatch相位法计算的地下水流速具有较高的准确性,在2014年12月15—31日时段内流速大小为1.03×10-4~7.96×10-4m/s,在空间上,断面深度增加,地下水流速降低,且不同深度流速曲线接近平行。  相似文献   

流域坡面汇流研究现状述评          下载免费PDF全文

申红彬  徐宗学  张书函 《水科学进展》2016,27(3):467-475

对当前坡面汇流计算方法的研究进展进行了较为系统的总结与分析,并对坡面汇流的非线性效应以及城市低影响开发中的雨水入渗与蓄集对坡面汇流的控制作用进行了简要分析。从模型简单实用的角度出发,认为以流域时间-面积关系与线性水库相串联的ModClark法等为代表的概念性分布式坡面汇流模型具有良好的发展前景;考虑到基于等流时单元的变动等流时线法在反映雨强非线性影响中存在的问题,认为根据水文响应单元在不同雨强条件下汇流时间的变化,调整其汇流参数以反映坡面汇流的非线性效应,对于流域坡面汇流的分布式模拟更具有实际意义;针对目前低影响开发设施长时间序列大空间尺度的室外降雨径流监测资料普遍较为缺乏的现状,给出了后期应积极选择合适的技术以加强低影响开发性能监测工作的建议。  相似文献   

Limited differences among habitats in deep‐sea macro‐infaunal communities off New Zealand: implications for their vulnerability to anthropogenic disturbance          下载免费PDF全文

Daniel Leduc  Ashley A. Rowden  Malcolm R. Clark  David A. Bowden  Andrew R. Thurber 《Marine Ecology》2016,37(4):845-866

The spread of human activities into the deep sea may pose a high risk to benthic communities and affect ecosystem integrity. The deep sea is characterized by physical and biological heterogeneity and different habitat types are likely to differ in their vulnerability to anthropogenic impacts. However, across‐habitat comparisons are rare, and no comprehensive ecological risk assessment has yet been developed. To address this gap in our knowledge, we compared macro‐infaunal community structure in four habitats (slope, canyons, seamounts and methane seeps) at depths between 700 and 1500 m in the Hikurangi Margin and Bay of Plenty regions off New Zealand. The most striking contrast in community structure was between the two study regions, due to an order of magnitude difference in macro‐infaunal abundance that we believe was caused by differences in surface productivity and food availability at the sea bed. We found differences in structural and functional attributes of macro‐infaunal communities among some habitats in the Hikurangi Margin (slope, canyon and seep), but not in the Bay of Plenty. We posit that differences between canyon and slope communities on the Hikurangi Margin are due to enhanced food availability inside canyons compared with adjacent slope habitats. Seep communities were characterized by elevated abundance of both symbiont‐bearing and heterotrophic taxa, and were the most distinct, and variable, among the habitats that we considered on the Hikurangi Margin. Communities of seamounts were not distinct from slope or canyon communities on the Hikurangi Margin, probably reflecting similar environmental conditions in these habitats. The communities of deep‐sea canyon and seep habitats on the Hikurangi Margin were sufficiently dissimilar from each other and from slope habitats to warrant separate management consideration. By contrast, the low dissimilarity between communities of canyon and slope habitats in the Bay of Plenty suggests that habitat‐based management is not required in this region, for macro‐infauna at least. Although the two study regions share similar species pools, populations of the Hikurangi Margin region may be less vulnerable than the sparser populations of the Bay of Plenty due to the higher availability of potential colonizers and faster population growth. Thus regions, and habitats in some regions, should be subject to separate ecological risk assessment to help identify the key risks and consequences of human activities, and to inform options for reducing or mitigating impacts.  相似文献   

Dynamic assessment of pollution risk of groundwater source area in Northern China          下载免费PDF全文

LIU Shu-yuan  WANG Hong-qi 《地下水科学与工程》2016,4(4):333-343

Based on the dynamic analysis and research of pollution risk of groundwater sources, this paper creates the dynamic assessment method of pollution risk of groundwater source area under the theory of “source-pathway-receptor”, and applies this method to one typical fissure karst groundwater source area in northern China. Following the 30-year petroleum pollutant migration simulation and pollution risk assessment of groundwater source area, this study finds that the very high risk zone is mainly located in Q Petrochemical Company and the surrounding area and the area adjacent to River Z. Within this period of thirty years, the pollution risk of groundwater source area has showed a dynamic trend that features an inverted “V” shape. The ratio of very high risk zone to the total area will be 18.1%, 17.47% and 16.62% during the tenth year, the twentieth year and the thirtieth year separately, and will reach the highest level of 19.45% during the fifteenth year. Meanwhile, the vertical migration distance of pollutant centre concentration changed from the surface soil at the outset to the deepest point of about 250 meters underground during the tenth year. The results of this risk assessment indicate the dynamic feature of pollution risk. The dilution, degradation and migration of petroleum pollutants in groundwater system contribute to an ultimate decline in pollution risk.  相似文献   

Towards an EU Action Plan on Cetacean Bycatch     

《Marine Policy》2016

For decades, cetacean bycatch has been a major conservation and welfare concern in Europe, with high numbers of harbour porpoises, dolphins and whales continuing to die each year. Despite binding legal requirements to reduce bycatch, there has been limited effective monitoring or mitigation. Bycatch is also an important welfare issue. At this critical juncture, with discussion of incorporating monitoring and mitigation of bycatch of protected species in Europe into the Data Collection Framework and Technical Measures Framework taking place to help deliver the reformed Common Fisheries Policy (CFP), a clear, effective strategy could identify the steps that are required by all EU Member States to reduce bycatch towards zero. Here, implementation of current monitoring and mitigation obligations are reviewed. Recommendations are made for the provision of clear EU guidance in order to improve and unify population surveillance and bycatch monitoring, with enhanced implementation and enforcement from Member States. A more regionalised evidence-based approach to monitoring and mitigation is in line with the move to more regionalised management under the CFP, with Member States robustly showing that bycatch levels are decreasing over a set period of time (e.g. 5 years) by a specified amount. To this end, an EU Action Plan on Cetacean Bycatch, comparable to the existing 2012 Action Plan for reducing incidental catches of seabirds in fishing gear, might be beneficial and could ultimately form a model for an international Food and Agricultural Organisation (FAO) Cetacean Bycatch Reduction Action Plan.  相似文献