The Mordor Alkaline Igneous Complex,Central Australia: PGE-enriched disseminated sulfide layers in cumulates from a lamprophyric magma     

Stephen J. Barnes  J. A. C. Anderson  T. R. Smith  L. Bagas 《Mineralium Deposita》2008,43(6):641-662

The Mordor Alkaline Igneous Complex (MAIC) is a composite intrusion comprising a body of syenite and a funnel-shaped layered mafic–ultramafic intrusion of lamprophyric parentage, the Mordor Mafic–Ultramafic Intrusion or MMUI. The MMUI is highly unusual among intrusions of lamprophyric or potassic parentage in containing primary magmatic platinum-group element (PGE)-enriched sulfides. The MMUI sequence consists largely of phlogopite-rich pyroxenitic cumulates, with an inward dipping conformable layer of olivine-bearing cumulates divisible into a number of cyclic units. Stratiform-disseminated sulfide accumulations are of two types: disseminated layers at the base of cyclic units, with relatively high PGE tenors; and patchy PGE-poor disseminations within magnetite-bearing upper parts of cyclic units. Sulfide-enriched layers at cycle bases contain anomalous platinum group element contents with grades up to 1.5 g/t Pt+Pd+Au over 1-m intervals, returning to background values of low parts per billion (ppb) on a meter scale. They correspond to reversals in normal fractionation trends and are interpreted as the result of new magma influxes into a continuously replenished magma chamber. Basal layers have decoupled Cu and PGE peaks reflecting increasing PGE tenors up-section, due to increasing R factors during the replenishment episode, or progressive mixing of between resident PGE-poor magma and more PGE-enriched replenishing magma. The presence of PGE enriched sulfides in cumulates from a lamprophyric magma implies that low-degree partial melts do not necessarily leave sulfides and PGEs in the mantle restite during partial melting. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

The shoshonite porphyry Cu-Au association in the Goonumbla District,N.S.W., Australia     

Dipl.-Geol. D. Müller  D. I. Groves  P. S. Heithersay 《Mineralogy and Petrology》1994,51(2-4):299-321

Summary The Goonumbla porphyry copper-gold deposit in N.S.W., Australia, is hosted by late Ordovician (439.2 ± 1.2 Ma)shoshonitic igneous rocks. In terms of their petrography, the rocks vary from andesitic to dacitic lavas and tuffs which are partly intruded by monzonite stocks; they are characterized by high and variable Al₂O₃ (13.4–19.9 wt%), very high K₂O values (up to 6.8 wt%), and high K₂O/Na₂O ratios (0.58–1.48), which are typical for the shoshonite association. The rocks also have enriched LILE concentrations (Ba up to 1200 ppm, Sr up to 1350 ppm), low HFSE (TiO₂ < 0.67 wt%, Zr < 125 ppm, Nb < 10 ppm, Hf < 3.4 ppm), and very low LREE (La < 22.4 ppm, Ce < 31 ppm), which are typical for potassic volcanic rocks formed in alate oceanic-arc setting.Mineral chemistry of selected magmatic mica and apatite phenocrysts from host rocks reveals relatively high SrO and BaO contents (micas: 0.15 wt% and up to 0.28 wt%, respectively; apatites: up to 0.28 wt% and 0.19 wt%, respectively) and very high halogen concentrations. Micas are characterized by up to 3.9 wt% F and 0.14 wt% Cl, whereas apatites have up to 3.6 wt% F and 0.68 wt% Cl. These very high halogen contents compared to those from barren intrusions imply that the shoshonitic magmatism was the source of mineralization.Copper-gold mineralization consists mainly of bornite, chalcopyrite, chalcocite and minor pyrite and tetrahedrite. Native gold occurs mainly as minute grains within silicates of the host rocks, and more rarely as fine inclusions in the sulphides. Mineralization is accompanied by wallrock alteration comprising a spatially restricted potassic type and a regional propylitic alteration type.Thus, the porphyry copper-gold deposit in the Goonumbla district can be viewed as an additional example of a worldwide association between potassic/shoshonitic magmatism and base- and precious-metal mineralization. More specifically, it appears to be the oldest recorded example of a shoshontie-associated porphyry Cu-Au deposit from a late oceanic-arc setting, a possible modern analogue being Ladolam at Lihir Island, Papua New Guinea

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Die Shoshonit Porphyry Cu-Au Assoziation im Goonumbla Distrikt, N.S.W., Australien

Zusammenfassung Die Porphyry Cu-Au Vererzung im Goonumbla Distrikt in New South Wales, Australien, sitzt in oberordovizischen (ca. 439.2 ± 1.2 Ma) Shoshoniten auf. Das petrographische Spektrum dieser Gesteine reicht von andesitischen bis dazitischen Laven und Tuffen, die lokal von Monzonit-Stöcken intrudiert werden; die Gesteine besitzen hohe, aber variable Al₂O₃ Gehalte (13.4–19.9 Gew%), sehr hohe K₂O Gehalte (bis zu 6.8 Gew%) und hohe K₂O/Na₂O Verhältnisse (0.58–1.48), die typisch sind für Shoshonite. Außerdem weisen sie hohe Konzentrationen an LILE Elementen (Ba bis 1200 ppm, Sr bis 1350 ppm) auf und geringe Konzentrationen an HFSE (TiO₂ < 0.67 Gew%, Zr < 125 ppm, Nb < 10 ppm, Hf < 3.4 ppm) sowie an LREE (La < 22.4 ppm, Ce < 31 ppm), die als typisch gelten für potassische Vulkanite von ozeanischen Plattengrenzen.Die Mineralchemie von repräsentativen Glimmer- und Apatit-Phänokristallen ist charakterisiert durch hohe SrO und BaO Gehalte (Glimmer: 0.15 Gew%, bzw. bis 0.28 Gew%; Apatite: bis 0.28 Gew%, bzw. 0.19 Gew%). Sie enthalten ferner sehr hohe Halogen-Konzentrationen. Die Glimmer enthalten beispielsweise bis zu 3.9 Gew% F und 0.14 Gew% Cl, während Apatite bis zu 3.6 Gew% F und 0.68 Gew% Ci aufweisen. Dies erscheint nicht ungewöhnlich, weil Glimmer und Apatite von vererzten Mag matiten zumeist deutlich höhere Halogengehalte besitzen, als solche von unvererzten Magmatiten. Die hohen Halogen-Gehalte in Phänokristallen aus den Shoshoniten legen nahe, die Vulkanite als den Ursprung der Vererzung zu interpretieren.Die Cu-Au Vererzung besteht überwiegend aus den Sulfiden Bornit, Kupferkies, Kupferglanz und vereinzelt auftretendem Pyrit und Tetrahedrit. Gediegen Gold wird in der Regel nur als kleine Partikel innerhalb von Silikaten der shoshonitischen Wirtsgesteine und seltener als feine Einschlüsse in Sulfiden gefunden.Die Vererzung wird von hydrothermaler Alteration der Wirtsgesteine begleitet und zwei Alterationsarten lassen sich unterscheiden: eine potassische sowie eine regional zu beobachtende propylitische Alteration.Die Porphyry Cu-Au Lagerstätte im Goonumbla Gebiet ist ein Beispiel für die weltweit beobachtete Assoziation von Bunt- und Edelmetallvererzungen und potassisch/shoshonitischem Magmatismus. Der Goonumbla Distrikt stellt die älteste bisher bekannte Porphyry Cu-Au Lagerstätte aus einerspätgenetischen ozeanischen Plattengrenze dar. Einmodernes Beispiel für eine Cu-Au Lagerstätte vergleichbaren Typs ist Ladolam auf Lihir Island, Papua New Guinea.

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Carbon isotopic fractionation between CO2 vapour,silicate and carbonate melts: an experimental study to 30 kbar   总被引：5，自引：0，他引：5  

David P. Mattey  W. R. Taylor  D. H. Green  C. T. Pillinger 《Contributions to Mineralogy and Petrology》1990,104(4):492-505

The carbon isotopic fractionation between CO₂ vapour and sodamelilite (NaCaAlSi₂O₇) melt over a range of pressures and temperatures has been investigated using solid-media piston-cylinder high pressure apparatus. Ag₂C₂O₄ was the source of CO₂ and experimental oxygen fugacity was buffered at hematite-magnetite by the double capsule technique. The abundance and isotopic composition of carbon dissolved in sodamelilite (SM) glass were determined by stepped heating and the ¹³C of coexisting vapour was determined directly by capsule piercing. CO₂ solubility in SM displays a complex behavior with temperature. At pressures up to 10 kbars CO₂ dissolves in SM to form carbonate ion complexes and the solubility data suggest slight negative temperature dependence. Above 20 kbars CO₂ reacts with SM to form immiscible Na-rich silicate and Ca-rich carbonate melts and CO₂ solubility in Na-enriched silicate melt rises with increasing temperature above the liquidus. Measured values for carbon isotopic fractionation between CO₂ vapour and carbonate ions dissoived in sodamelilite melt at 1200°–1400° C and 5–30 kbars average 2.4±0.2, favouring¹³C enrichment in CO₂ vapour. The results are maxima and are independent of pressure and temperature. Similar values of 2 are obtained for the carbon isotopic fractionation between CO₂ vapour and carbonate melts at 1300°–1400° C and 20–30 kbars.  相似文献   

Geodetic versus geophysical perspectives of the 'gravity anomaly'   总被引：8，自引：0，他引：8  

R. I. Hackney  W. E. Featherstone 《Geophysical Journal International》2003,154(1):35-43

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Neoarchaean magmatism and metamorphism of the western granulites in the central domain of the Mozambique belt, Tanzania: U–Pb shrimp geochronology and PT estimates     

S. P. Johnson  H. N. C. Cutten  S. Muhongo  B. De Waele 《Tectonophysics》2003,375(1-4):125

U–Pb sensitive high resolution ion microprobe (SHRIMP) dating of zircons from charnockitic and garnet–biotite gneisses from the central portion of the Mozambique belt, central Tanzania indicate that the protolith granitoids were emplaced in a late Archaean, ca. 2.7 Ga, magmatic event. These ages are similar to other U–Pb and Pb–Pb ages obtained for other gneisses in this part of the belt. Zircon xenocrysts dated between 2.8 and 3.0 Ga indicate the presence of an older basement. Major and trace element geochemistry of these high-grade gneisses suggests that the granitoid protoliths may have formed in an active continental margin environment. Metamorphic zircon rims and multifaceted metamorphic zircons are dated at ca. 2.6 Ga indicating that these rocks were metamorphosed some 50–100 my after their emplacement. Pressure and temperature estimates on the charnockitic and garnet–biotite gneisses were obscured by post-peak metamorphic compositional homogenisation; however, these estimates combined with mineral textures suggest that these rocks underwent isobaric cooling to 800–850 °C at 12–14 kbar. It is considered likely that the granulite facies mineral assemblage developed during the ca. 2.6 Ga event, but it must be considered that it might instead represent a pervasive Neoproterozoic, Pan African, granulite facies overprint, similar to the ubiquitous eastern granulites further to the east.  相似文献   

Out of Africa: detrital zircon provenance of central Madagascar and Neoproterozoic terrane transfer across the Mozambique Ocean   总被引：1，自引：0，他引：1  

I. C. W. Fitzsimons  B. Hulscher 《地学学报》2005,17(3):224-235

The Neoproterozoic East African Orogen reflects closure of the Mozambique Ocean and collision of the Congo and Dharwar cratons. This palaeogeographical change and its environmental consequences are poorly understood, but new detrital zircon ages from Madagascar and published data from elsewhere provide evidence for multiple ocean basins and two-stage collision. We propose that central Madagascar rifted from the Congo Craton and crossed a Palaeomozambique Ocean to collide with the Dharwar Craton at c. 700 Ma, opening a Neomozambique Ocean in its wake. Closure of the Neomozambique Ocean at c. 600 Ma juxtaposed the Congo and Dharwar cratons and resulted in prolonged collisional orogenesis concluding at c. 500 Ma.  相似文献   

Late Archean to Paleoproterozoic evolution of the North China Craton: key issues revisited     

《Precambrian Research》2005,136(2):177-202

A recently proposed model for the evolution of the North China Craton envisages discrete Eastern and Western Blocks that developed independently during the Archean and collided along the Trans-North China Orogen during a Paleoproterozoic orogenic event. This model has been further refined and modified by new structural, petrological and geochronological data obtained over the past few years. These new data indicate that the Western Block formed by amalgamation of the Ordos Block in the south and the Yinshan Block in the north along the east-west-trending Khondalite Belt some time before the collision of the Western and Eastern Blocks. The data also suggest that the Eastern Block underwent Paleoproterozoic rifting along its eastern continental margin in the period 2.2–1.9 Ga, and was accompanied by deposition of the Fenzishan and Jingshan Groups in Eastern Shandong, South and North Liaohe Groups in Liaoning, Laoling and Ji’an Groups in Southern Jilin, and possibly the Macheonayeong Group in North Korea. The final closure of this rift system at ∼1.9 Ga led to the formation of the Jiao-Liao-Ji Belt. In the late Archean to early Paleoproterozoic, the western margin of the Eastern Block faced a major ocean, and the east-dipping subduction beneath the western margin of the Eastern Block led to the formation of magmatic arcs that were subsequently incorporated into the Trans-North China Orogen. Continued subduction resulted in a major continent-continent collision, leading to extensive thrusting and high-pressure metamorphism. The available age data for metamorphism and deformation in the Trans-North China Orogen indicate that this collisional event occurred at about 1.85 Ga ago, resulting in the formation of the Trans-North China Orogen and final amalgamation of the North China Craton.  相似文献   

Simplified multi-block constitutive model predicting earthquake-induced landslide triggering and displacement along slip surfaces of saturated sand     

《Soil Dynamics and Earthquake Engineering》2014

Slopes consisting of saturated sand have recently moved down-slope tens or hundreds of meters under the action of earthquakes. This paper presents a simplified but accurate method predicting the triggering and displacement of such landslides. For this purpose, a simplified constitutive model simulating soil response of saturated sands along slip surfaces is proposed and validated. Then, this constitutive model is coupled with the multi-block sliding system model to predict the triggering and displacement of such slides. The multi-block model considers a general mass sliding on a trajectory which consists of n linear segments. The steps needed to apply this method are described in detail. The method was applied successfully to predict the triggering, the motion and the final configuration of the well-documented (a) Higashi Takezawa, (b) Donghekou and (c) Nikawa earthquake-induced slides.  相似文献   

The petrology,geochronology and tectono-magmatic setting of igneous rocks in the Suckling-Dayman metamorphic core complex,Papua New Guinea     

《Gondwana Research》2020

Southeastern Papua New Guinea has hosted magmatism throughout the Cenozoic, with the latest phase being concurrent with active extension in the Woodlark Rift. There, the Suckling-Dayman metamorphic core complex (SDMCC) has exhumed middle-crustal rocks in the past few million years along a still-active low-angle normal fault, the Mai'iu Fault. Uplift of the SDMCC has exposed metasedimentary and metaigneous rocks of Late Cretaceous-Pleistocene age that record an evolution from oceanic spreading to subduction, to collision, and finally to subduction-inversion and extensional exhumation. We present new petrographic, whole-rock geochemical and geochronologic (zircon U–Pb LA-ICP-MS) data from the SDMCC to reconstruct its long-term evolution. The dominant footwall-lithology of the SDMCC, the Goropu Metabasalt, has a MORB composition. Detrital zircons from metasedimentary beds intercalated with these basalts yield U–Pb-based maximum estimates for deposition of ~103 and ~72 Ma, suggesting a Late Cretaceous spreading age of the oceanic protolith. Bulk compositions of low-grade tholeiitic meta-gabbroic and -tonalitic rocks (Yau Igneous Complex) that intrude the Goropu Metabasalt reveal both enriched and depleted light rare earth element patterns. Zircon U–Pb ages from the Yau Igneous Complex range between ~60 and ~57 Ma, providing a minimum age for the formation of the Goropu Metabasalt. Much younger syn-extensional granitoids in the mafic footwall of the SDMCC have calc-alkaline to high-K compositions and U–Pb ages on zircon between ~3.7 and ~2.0 Ma. Our data indicate that the Mai'iu Fault had re-activated a Paleogene thrust as an extensional detachment fault by 3.7 ± 0.2 Ma. U–Pb ages of detrital zircons in modern streams draining the footwall of the SDMCC essentially reflect the ages revealed by the Paleocene and Plio-Pleistocene intrusions. Xenocrystic zircons in the Plio-Pleistocene granitoids imply that the crust underlying the metabasaltic carapace of the SDMCC consists chiefly of Australian-continent derived sedimentary rocks.  相似文献   

A smoothed particle hydrodynamics modelling of soil–water mixing and resulting changes in average strength     

Wangcheng Zhang  Mark F. Randolph 《国际地质力学数值与分析法杂志》2020,44(11):1548-1569

Soil–water interaction is a pivotal process in many underwater geohazards such as underwater landslides where soil sediments gradually evolve into turbidity currents after interactions with ambient water. Due to the large deformations, multiphase interactions and phase changes this involves, investigations from numerical modelling of the transition process have been limited so far. This study explores a simple numerical replication of such soil–water mixing with respect to changes in average strength using smoothed particle hydrodynamics (SPH). A uniform viscoplastic model is used for both the solid-like and fluid-like SPH particles. The proposed numerical solution scheme is verified by single-phase dam break tests and multiphase simple shear tests. SPH combinations of solid-like and fluid-like particles can replicate the clay–water mixture as long as the liquidity index of the solid-like particles is larger than unity. The proposed numerical scheme is shown to capture key features of an underwater landslide such as hydroplaning, water entrainment and wave generation and thus shows promise as a tool to simulate the whole process of subaquatic geohazards involving solid–fluid transition during mass transport.  相似文献