Origin of K-rich diamond-forming immiscible melts and CO2 fluid via partial melting of carbonated pelites at a depth of 180–200 km     

《Gondwana Research》2019

Melt inclusions in kimberlitic and metamorphic diamonds worldwide range in composition from potassic aluminosilicate to alkali-rich carbonatitic and their low-temperature derivative, a saline high-density fluid (HDF). The discovery of CO₂ inclusions in diamonds containing eclogitic minerals are also essential. These melts and HDFs may be responsible for diamond formation and metasomatic alteration of mantle rocks since the late Archean to Phanerozoic. Although a genetic link between these melts and fluids was suggested, their origin is still highly uncertain. Here we present experimental results on melting phase relations in a carbonated pelite at 6 GPa and 900–1500 °C. We found that just below solidus K₂O enters potassium feldspar or K₂TiSi₃O₉ wadeite coexisting with clinopyroxene, garnet, kyanite, coesite, and dolomite. The potassium phases react with dolomite to produce garnet, kyanite, coesite, and potassic dolomitic melt, 40(K_0.90Na_0.10)₂CO₃·60Ca_0.55Mg_0.24Fe_0.21CO₃ + 1.9 mol% SiO₂ + 0.7 mol% TiO₂ + 1.4 mol% Al₂O₃ at the solidus established near 1000 °C. Molecular CO₂ liberates at 1100 °C. Potassic aluminosilicate melt appears in addition to carbonatite melt at 1200 °C. This melt contains (mol/wt%): SiO₂ = 57.0/52.4, TiO₂ = 1.8/2.3, Al₂O₃ = 8.5/13.0, FeO = 1.4/1.6, MgO = 1.9/1.2, CaO = 3.8/3.2, Na₂O = 3.2/3.0, K₂O = 10.5/15.2, CO₂ = 12.0/8.0, while carbonatite melt can be approximated as 24(K_0.81Na_0.19)₂CO₃·76Ca_0.59Mg_0.21Fe_0.20CO₃ + 3.0 mol% SiO₂ + 1.6 mol% TiO₂ + 1.4 mol% Al₂O₃. Both melts remain stable to at least 1500 °C coexisting with CO₂ fluid and residual eclogite assemblage consisting of K-rich omphacite (0.4–1.5 wt% K₂O), almandine-pyrope-grossular garnet, kyanite, and coesite. The obtained immiscible alkali‑carbonatitic and potassic aluminosilicate melts resemble compositions of melt inclusions in diamonds worldwide. Thus, these melts entrapped by diamonds could be derived by partial melting of the carbonated material of the continental crust subducted down to 180–200 km depths. Given the high solubility of chlorides and water in both carbonate and aluminosilicate melts inferred in previous experiments, the saline end-member, brine, could evolve from potassic carbonatitic and/or silicic melts by fractionation of Ca-Mg carbonates/eclogitic minerals and accumulation of alkalis, chlorine and water in the residual low-temperature supercritical fluid. Direct extraction from the hydrated marine sediments under conditions of cold subduction would be another possibility for the brine formation.  相似文献   

Benthic foraminiferal fauna and sediment provenance of Eocene syn-rift sequences in Taiwan: implication for onset of Asian epi-continental marginal seas off China coast     

Huang  Chi-Yue  Shao  Lei  Wang  Ming-Huei  Xue  Wei-Guang  Qiao  Pei-Jun  Cui  Yu-Chi  Hou  Yuan-Li 《Marine Geophysical Researches》2019,40(2):111-127

Marine Geophysical Research - Early Cenozoic rift basins developed commonly on the Mesozoic basement along the SE Asia Continent. However, Eocene–Oligocene sequences were only exposed widely...  相似文献   

Preface to Special Issue ‘Insights on the vertebrate paleontology of the Neuquén Group,Argentina’     

《Cretaceous Research》2018

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Two generations of Variscan garnet: Implications from a petrochronological study of a high-grade Avalonia-derived paragneiss from the Drosendorf unit,Bohemian Massif     

《Gondwana Research》2020

Garnets in metapelitic paragneisses from the southern Drosendorf unit in the Austrian part of the Bohemian Massif exhibit two episodes of growth during the Variscan orogeny, which can be distinguished on textural and chemical grounds. The first garnet (grt1) records evidence of high-grade metamorphism in the Late Devonian (Frasnian–Famennian), while the second garnet (grt2) formed by a second high-grade event in the Early Carboniferous (Visean). Both garnet generations contain abundant inclusions, of which monazite, rutile and crystallised melt droplets are particularly useful for reconstructing P–T–t conditions. The Late Devonian age (373 ± 9 Ma) for the first episode of garnet growth was obtained from chemical dating of monazite inclusions in grt1. Metamorphic conditions during the first episode of garnet growth are estimated to have been between 0.7 and 0.8 GPa at 680–700 °C and 0.95–1.10 GPa at 745–785 °C. There followed a phase of cooling and exhumation, after which the second garnet (grt2) were formed beginning under amphibolite facies conditions and continuing prograde to peak conditions of 0.95–1.10 GPa and 745–785 °C, which are similar to those of the first garnet forming event. Subsequently, the rocks experienced near isothermal decompression to 0.5–0.8 GPa. Chemical dating of both monazite inclusions in grt2 and the matrix provide a Visean age (343 ± 3 Ma).A study of detrital zircons in these paragneisses revealed zircon forming events at around 1.2, 1.5 and 1.8 Ga, suggesting an Avalonian provenance. The lack of zircons younger than 1 Ga and the presence of Cadomian metamorphic monazite relics (652 ± 15 Ma) indicates an Early Neoproterozoic deposition age for the sedimentary protolith likely. Our documentation of a Late Devonian high-grade metamorphic event in rocks derived from Avalonian corroborates tectonic models which assume that frontal parts of the Armorican terrane had already docked with Avalonia by this time.  相似文献   

Internal and forced climate variability during the last millennium: a model-data comparison using ensemble simulations     

《Quaternary Science Reviews》2005,24(12-13):1345-1360

A three-dimensional climate model was used to perform 25 simulations over the last millennium, which are driven by the main natural and anthropogenic forcing. The results are compared to available reconstructions in order to evaluate the relative contribution of internal and forced variability during this period. At hemispheric and nearly hemispheric scale, the impact of the forcing is clear in all the simulations and knowing the forced response provides already a large amount of information about the behaviour of the climate system. Besides, at regional and local scales, the forcing has only a weak contribution to the simulated variability compared to internal variability. This result could be used to refine our conception of Medieval Warm Period and Little Ice Age (MWP and LIA). They were hemispheric-scale phenomena, since the temperature averaged over the Northern Hemisphere was, respectively generally higher/lower during those periods because of a stronger/weaker external forcing at that time. Nevertheless, at local-scale, the sign of the internal temperature variations determines to what extent the forced response will be actually visible or even masked by internal noise. Because of this role of internal variability, synchronous peak temperatures during the MWP or LIA between different locations are unlikely.  相似文献   

Cenozoic sedimentary basins of southern Turkey: an introduction     

《Sedimentary Geology》2005,173(1-4):1-13

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IAGC Membership Form     

《Applied Geochemistry》2005,20(11):II

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Going underground: in search of Carboniferous coal forests     

Howard J. Falcon-Lang  William A. DiMichele  Scott Elrick  & W. John Nelson 《Geology Today》2009,25(5):181-184

The development of coal forests during the Carboniferous is one of the best-known episodes in the history of life. Although often reconstructed as steamy tropical rainforests, these ancient ecosystems were a far cry from anything we might encounter in the Amazon today. Bizarre giant club-mosses, horsetails and tree ferns were the dominant plants, not flowering trees as in modern rainforests. At their height, coal forests stretched all the way from Kansas to Kazakhstan, spanning the entire breadth of tropical Pangaea. Most of what we know of their biodiversity and ecology has been quite literally mined out of the ground through two centuries of hard labour. Without coal mining, our knowledge would be greatly impoverished. Over the past few years, we've been exploring underground coal mines in the United States, where entire forested landscapes have been preserved intact over huge areas. Never before have geologists had the opportunity to walk out through mile upon mile of fossilized forest. In this feature article, we describe some of our recent explorations and attempt to shed new light on these old fossils.  相似文献   

Zircon U–Pb age, trace element and Hf isotope composition of Kongling terrane in the Yangtze Craton: refining the timing of Palaeoproterozoic high-grade metamorphism     

Y.-B. WU  S. GAO  H.-J. GONG  H. XIANG  W.-F. JIAO  S.-H. YANG  Y.-S. LIU  H.-L. YUAN 《Journal of Metamorphic Geology》2009,27(6):461-477

U–Pb age, trace element and Hf isotope compositions of zircon were analysed for a metasedimentary rock and two amphibolites from the Kongling terrane in the northern part of the Yangtze Craton. The zircon shows distinct morphological and chemical characteristics. Most zircon in an amphibolite shows oscillatory zoning, high Th/U and ¹⁷⁶Lu/¹⁷⁷Hf ratios, high formation temperature, high trace element contents, clear negative Eu anomaly, as well as HREE-enriched patterns, suggesting that it is igneous. The zircon yields a weighted mean ²⁰⁷Pb/²⁰⁶Pb age of 2857 ± 8 Ma, representing the age of the magmatic protolith. The zircon in the other two samples is metamorphic. It has low Th/U ratios, low trace element concentrations, variable HREE contents (33.8 ≥ Lu_N≥2213; 14.7 ≤ Lu_N/Sm_N ≤ 354) and ¹⁷⁶Lu/¹⁷⁷Hf ratios (0.000030–0.001168). The data indicate that the zircon formed in the presence of garnet and under upper amphibolite facies conditions. The metamorphic zircon yields a weighted mean ²⁰⁷Pb/²⁰⁶Pb age of 2010 ± 13 Ma. These results combined with previously obtained Palaeoproterozoic metamorphic ages suggest a c. 2.0 Ga Palaeoproterozoic collisional event in the Yangtze Craton, which may result from the assembly of the supercontinent Columbia. The zircon in two samples yields weighted mean two-stage Hf model ( T _DM2) ages of 3217 ± 110 and 2943 ± 50 Ma, respectively, indicating that their protoliths were mainly derived from Archean crust.  相似文献   

Age and early metamorphic history of the Sanbagawa belt: Lu–Hf and P–T constraints from the Western Iratsu eclogite     

S. ENDO  S.WALLIS  T. HIRATA  R. ANCZKIEWICZ  J. PLATT  M. THIRLWALL  Y. ASAHARA 《Journal of Metamorphic Geology》2009,27(5):371-384

Two distinct age estimates for eclogite-facies metamorphism in the Sanbagawa belt have been proposed: (i) c.  120–110 Ma based on a zircon SHRIMP age for the Western Iratsu unit and (ii) c.  88–89 Ma based on a garnet–omphacite Lu–Hf isochron age from the Seba and Kotsu eclogite units. Despite the contrasting estimates of formation ages, petrological studies suggest the formation conditions of the Western Iratsu unit are indistinguishable from those of the other two units—all ∼20 kbar and 600–650 °C. Studies of the associated geological structures suggest the Seba and Western Iratsu units are parts of a larger semi-continuous eclogite unit. A combination of geochronological and petrological studies for the Western Iratsu eclogite offers a resolution to this discrepancy in age estimates. New Lu–Hf dating for the Western Iratsu eclogite yields an age of 115.9 ± 0.5 Ma that is compatible with the zircon SHRIMP age. However, petrological studies show that there was significant garnet growth in the Western Iratsu eclogite before eclogite facies metamorphism, and the early core growth is associated with a strong concentration of Lu. Pre-eclogite facies garnet (Grt1) includes epidote–amphibolite facies parageneses equilibrated at 550–650 °C and ∼10 kbar, and this is overgrown by prograde eclogite facies garnet (Grt2). The Lu–Hf age of c.  116 Ma is strongly skewed to the isotopic composition of Grt1 and is interpreted to reflect the age of the pre-eclogite phase. The considerable time gap ( c.  27 Myr) between the two Lu–Hf ages suggests they may be related to separate tectonic events or distinct phases in the evolution of the Sanbagawa subduction zone.  相似文献