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The Shilu deposit is a world-class Fe–Co–Cu orebody located in the Changjiang area of the western part of Hainan Island, South China. The distribution of Fe, Co, and Cu orebodies is controlled by strata of the No. 6 Formation in the Shilu Group and the Beiyi synclinorium. Based on a petrological study of the host rocks and their alteration assemblages, and textural and structural features of the ores, four mineralization stages have been identified: (1) the sedimentary ore-forming period; (2) the metamorphic ore-forming period; (3) the hydrothermal mineralization comprising the skarn and quartz–sulfide stage; and (4) the supergene period. The fluid inclusions in sedimentary quartz and/or chert indicate low temperatures (ca. 160 °C) and low salinities from 0.7 to 3.1 wt.% NaCleq, which corresponds to densities of 0.77 to 0.93 g/cm3. CO2-bearing or carbonic inclusions have been interpreted to result from regional metamorphism. Homogenization temperatures of fluid inclusions for the skarn stage have a wide range from 148 °C to 497 °C and the salinities of the fluid inclusions range from 1.2 to 22.3 wt.% NaCleq, which corresponds to densities from 0.56 to 0.94 g/cm3. Fluid inclusions of the quartz–sulfide stage yield homogenization temperatures of 151–356 °C and salinities from 0.9 to 8.1 wt.% NaCleq, which equates to fluid densities from 0.63 to 0.96 g/cm3.Sulfur isotopic compositions indicate that sulfur of the sedimentary anhydrite and Co-bearing pyrite, and the quartz–sulfide stage, was derived from seawater sulfate and thermochemical sulfate reduction of dissolved anhydrite at temperatures of 200 °C and 300 °C, respectively. H and O isotopic compositions of the skarn and quartz–sulfide stage demonstrate that the ore-forming fluids were largely derived from magmatic water, with minor inputs from metamorphic or meteoric water. The Shilu iron ore deposit has an exhalative sedimentary origin, but has been overprinted by regional deformation and metamorphism. The Shilu Co–Cu deposit has a hydrothermal origin and is temporally and genetically associated with Indosinian granitoid rocks. 相似文献
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石碌铁矿床外围的印支期花岗岩属于昌江岩体的一部分。这些花岗岩岩性为二长花岗岩,为准铝质-弱过铝质,属于高钾钙碱性系列和钾玄岩系列。岩石稀土元素总量较低,变化不大,∑REE介于134.96×10-6～241.05×10-6;轻重稀土分异明显,LREE/HREE变化于4.44～9.67,(La/Yb)N变化于3.95～10.69;具有中等负Eu异常(δEu=0.28～0.57),Ba、Nb(-Ta)、Ce、Sr、P、Ti具明显负异常。Ba、Sr、Eu的明显负异常表明源区有斜长石的大量残留或岩石经历了斜长石的结晶分异作用。花岗岩87Sr/86Sr初始比(ISr)主要变化于0.710 852～0.715 492(1个样品ISr值为0.706 364)。εNd(t)=–7.3～-9.1,TDM2模式年龄变化于1.5～1.9 Ga。总体来说,ISr值、εNd(t)值和TDM2值比较均匀,表明源区是均匀的,由中元古代抱板群部分熔融作用所形成。花岗岩形成于后碰撞环境。笔者在探讨海南岛与俯冲有关的弧岩浆活动、同碰撞岩浆活动和与后碰撞有关的岩浆活动基础上,认为海南岛海西—印支期花岗岩可与北越南海西—印支期花岗岩进行对比。 相似文献
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海南石碌钴-铜矿体赋存于石碌群第六层的下段,即介于铁矿体与石碌群第五层片岩之间的含钴-铜层位中,容矿岩石主要为白云岩、透辉石透闪石化白云岩。钴-铜矿床的形成经历了海底喷溢沉积期、石英-硫化物期(热液期)和表生期。海底喷溢沉积期石英包裹体均一温度变化于112~205℃,多集中在130~205℃;盐度w(NaCleq)为1.74%~6.59%;密度变化于0.88~0.95 g/cm3。温度范围与很多古代沉积喷流矿床及正在活动的海底热液成矿作用的温度相似,盐度低于曾报道的多数沉积喷流矿床的流体包裹体盐度值, 但与那些同为低密度成矿流体的喷流沉积矿床极为相近。海底喷溢沉积期形成的硬石膏δ34S值为+21.4‰~+21.8‰,平均值为+21.6‰,强烈富集重硫,硬石膏δ34S值代表着新元古代石碌群沉积时海水的δ34S值。石英-硫化物期石英、白云石和方解石均一温度多集中在170~270℃;盐度w(NaCleq)为1%~7%;密度变化于0.88~0.95 g/cm3。成矿流体属于中温低盐度流体。石英-硫化物期成矿流体δD值为-63‰~-83‰,成矿流体δ18O水值变化于1.3‰~6.8‰之间,指示成矿流体来源于岩浆,成矿后期有大气降水的加入。石英-硫化物期硫化物δ34S值为+8.1‰~+21.2‰,硫源来源于石碌群中蒸发岩的溶解作用。石碌钴-铜矿床属中温热液充填交代矿床,与矿床周围花岗质岩浆活动有关。 相似文献
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