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1.
北京市有机氯农药填图与风险评价 总被引：2，自引：0，他引：2
采用1个样/km2的密度、1个分析组合样/16km2的方法,对北京市784km2范围内的土壤、大气干湿沉降物、大气颗粒物中HCH、DDT的含量和空间分布特征进行有机氯农药填图.查明2000年北京市地表土壤HCH和DDT的平均含量分别为8.80±11.83ng/g、108.99±301.90ng/g.2006年大气干湿沉降物中HCH和DDT平均含量分别为10.09±9.60ng/g、12.99±13.51ng/g,HCH和DDT的年沉降通量分别为996.57±939.96g/a·km2、1291.53±1342.28g/a·km2.2006年大气颗粒物PM10和PM2.5中的HCH含量分别为0.294±0.205ng/m3和0.217±0.137ng/m3,DDT的平均含量分别为1.037±1.301ng/m3和0.522±0.773ng/m3,显著高于2002-2003年度大气颗粒物中HCH(PM100.01786ng/m3,PM250.01731ng/m3)和DDT(PM100.01672ng/m3,PM2.50.02353ng/m3)的含量,表明北京市或周边地区仍在使用含HCH和DDT化学成分的农药.以2000年北京地表土壤和2006年大气干湿沉降物中HCH和DDT的含量为基础,对2020年土壤中HCH和DDT的时空演变的预测显示,即使干湿沉降物中HCH和DDT的沉降通量每年以5%的速率递减,到2020年土壤中HCH和DDT的环境质量仍不能显著改善,而控制和削减北京及周边地区含HCH和DDT成分农药的使用将是改善北京地表土壤环境质量的关键措施. 相似文献
3.
Guided by the theory of groundwater system, based on the groundwater level data from the northern basin of Laiyuan Spring area, the authors took into account factors such as the lithology, geological structure and topography to study the relationship between groundwater recharge, runoff and drainage in this area. It was concluded that the infiltration of atmospheric precipitation is the main source of groundwater supply in this area; the upper layer of the Spring area is distributed with the Cambrian-Lower Ordovician karst water, and the lower layer is filled with the Jixian system karst water. The upper layer of karst water supplies to the lower layer of karst water or the pore water in loose strata through the fault while the lower layer of karst water runs to the three strong runoff belts from the east and west sides of the watershed, southwards into the basin, partially replenishing the pore water in loose strata, or forming fault Springs (e.g. Nanguan Spring, Beihai Spring) when dolomite movement encounters faults. Replenished by atmospheric precipitation and the upper and lower layers of karst waters, the pore water in loose strata joins the groundwater in the southern basin and then flows eastwards, in the end it flows out of the system in Shangfanpu. Through the analyses of groundwater level data and hydrogeological drilling data, based on groundwater D and 18O isotope test results, the karst groundwater circulation system in the northern basin of Laiyuan Spring area is further verified, which provides hydrogeological basis for water resources development and utilization as well as protection in this area. 相似文献
4.
陕西凤太矿集区多金属成矿作用的构造控制 总被引：3，自引：0，他引：3
陕西凤县-太白(简称凤太)矿集区铅、锌、金、银、铜多金属资源丰富,已发现二十余个大中小型矿床。在大地构造位置上,凤太矿集区位于南秦岭造山带北缘,紧邻商丹缝合带。以往的工作缺乏对矿集区整体的构造研究,本次工作通过比较系统的构造测量和解析,提出在南秦岭晚三叠世碰撞造山过程中,凤太矿集区南北两条边界断裂带的左行走滑运动导致在区内衍生了NNE向主压应力场,从而形成了NWW向复式褶皱、脆韧性剪切带、断裂和节理(纵向破裂)、B型线理,以及NNE向断裂和节理(横向破裂)、劈理、张裂隙等一系列构造组合,所有构造形迹都是在统一构造应力场下随着构造层次不断抬升,脆韧性和脆性递进变形叠加的产物,共同构成了一个大型压扭性走滑双重构造变形系统。在构造几何学上,凤太矿集区整体上表现为一个隔档式复式褶皱,由一组NWW向紧闭复背斜和一组相对宽缓复向斜组成。区内的多金属成矿作用、岩浆活动、动力变质变形作用的同位素年龄数据集中于230~190Ma。综合地质演化和成矿作用的研究成果,提出在南秦岭碰撞造山过程中引发的动力变质变形作用和岩浆活动提供了成矿元素和成矿流体,在温压梯度以及浮力效应的驱动下向上运移至走滑双重构造变形系统中的有利扩容空间中发生充填型和交代型矿化,即凤太矿集区多金属矿床是区域大规模变形变质-岩浆活动-流体作用的产物,是在构造作用这一主导因素控制下形成的一个多金属后生热液成矿系统。 相似文献
5.
麻棚和赤瓦屋岩体都位于太行山中段热液金属矿成矿区内,在其周围已发现石湖石英脉大型金矿等60余处热液型矿床(点),其深部和外围可能存在找矿前景。本文通过探讨太行山中段城南庄一带遥感环形构造和重力负场特征与金属矿床和岩体的耦合关系,从城南庄卫星式-多层蘑菇群式遥感环形构造群、重力负场、中酸性岩脉侵入和温泉五种证据,推测城南庄深部存在比麻棚和赤瓦屋岩体大近六倍、面积约700 km~2的中酸性隐伏岩体—城南庄隐伏岩体。城南庄隐伏岩体边界基本与布格重力负异常边界吻合,呈长轴北东向宽缓带状展布,向南西方向倾伏,北侧埋深较浅、南侧埋深较深。城南庄隐伏岩体边部(特别是产状缓外倾,具有良好成矿空间的区域)和顶部与围岩的接触带位置、环形构造形成的晚期"小岩体"内部及附近位置和中酸性岩脉附近位置是寻找热液型矿床的有利部位。 相似文献
6.
《Chemie der Erde / Geochemistry》2021,81(2):125748
Although antimony (Sb) and arsenic (As) exhibit similar geochemical behavior and toxicity in the environment, growing evidence suggests that their water–rock interaction behavior in contaminated rivers is quite different. Twenty-nine river water samples were collected between September and November 2018 from contaminated rivers around an antimony mine in Hunan Province, China. The concentrations of As and Sb were inversely proportional to the water flow distance. The rates and magnitudes of Sb decrease were more prominent than those of As. Silicate mineral dissolution from rocks such as silicified limestone increased the As and Sb concentration of in-mine-district (IMD) water. Dissolution of carbonate minerals, ion exchange, and competitive adsorption were the major water–rock interactions, resulting in rapidly decreasing As and Sb concentration in IMD direct impacted water and IMD indirect impacted water. The behaviors of As and Sb during water–rock interaction were dissimilar for areas dominated by carbonate and silicate minerals. 相似文献
7.
大湾斑岩-矽卡岩型锌钼矿床地处太行山北段成矿带中,是该段重要的金属矿床之一.五台群板峪口组和长城系高于庄组为主要赋矿围岩,锌钼矿体主要赋存在流纹斑岩体内及斑岩与围岩接触部位.文章对大湾矿床内2件赋矿流纹斑岩进行LA-ICP-MS锆石U-Pb年代测定,获得206Pb/238U年龄加权平均值分别为(137.1±0.9)Ma(MSWD=0.56,n=24)和(136.8±1.2)Ma(MSWD=0.40,n=22);对矿区4件辉钼矿样品进行Re-Os定年,得到加权平均年龄为(136.5±1.0)Ma,等时线年龄为(136.1±2.3)Ma,在误差范围内成岩成矿时代一致,显示大湾锌钼矿床形成于早白垩世.大湾矿床中辉钼矿的w(Re)为5.816～16.484μg/g,反映了矿床成矿物质来源具有壳幔混合特征.区内流纹斑岩和蚀变体系为进一步找矿勘查的有利标志. 相似文献
8.
In this paper we present a review of sedimentological, geomorphological, lithological, geochronological and geophysical data from major, minor and satellite basins of the Baikal Rift Zone (BRZ) and discuss various aspects of its evolution. Previously, the most detailed sedimentological data have been obtained from the basins of the central BRZ, e.g., Baikal, Tunka and Barguzin, and have been used by many scientists worldwide. We add new information about the peripheral part and make an attempt to provide a more comprehensive view on BRZ sedimentation stages and environments and their relations to local and regional tectonic events. A huge body of sedimentological data was obtained many years ago by Soviet geologists and therefore is hardly accessible for an international reader. We pay tribute to their efforts to the extent as the format of a journal paper permits. We discuss structural and facial features of BRZ sedimentary sequences for the better understanding of their sedimentation environments. In addition, we review tectono-sedimentation stages, neotectonic features and volcanism of the region. Finally, we consider the key questions of the BRZ evolution from the sedimentological point of view, in particular, correlation of Mesozoic and Cenozoic basins, bilateral growth of the Baikal rift, Miocene sedimentation environment and events at the Miocene/Pliocene boundary, Pliocene and Pleistocene tectonic deformations and sedimentation rates. The data from deep boreholes and surface occurrences of pre-Quaternary sediments, the distribution of the Pleistocene sediments, and the data from the Baikal and Hovsgol lakes sediments showed that 1) BRZ basins do not fit the Mesozoic extensional structures and therefore hardly inherited them; 2) the Miocene stage of sedimentation was characterized by low topography and weak tectonic processes; 3) the rifting mode shifted from slow to fast at ca. 7–5 Ma; 4) the late Pleistocene high sedimentation rates reflect the fast subsidence of basin bottoms. 相似文献
9.
Three bitumen fractions were obtained and systematically analysed for the terpane and sterane composition from 30 Paleozoic source rocks and 64 bitumen-containing reservoir rocks within the Upper Sinian, Lower Cambrian, Lower Silurian, Middle Carboniferous, Upper Permian and Lower Triassic strata in the Sichuan Basin and neighbouring areas, China. These bitumen fractions include extractable oils (bitumen I), oil-bearing fluid inclusions and/or closely associated components with the kerogen or pyrobitumen/mineral matrix, released during kerogen or pyrobitumen isolation and demineralization (bitumen II), and bound compounds within the kerogen or pyrobitumen released by confined pyrolysis (bitumen III). In addition, atomic H/C and O/C ratios and carbon isotopic compositions of kerogen and pyrobitumen from some of the samples were measured. Geochemical results and geological information suggest that: (1) in the Central Sichuan Basin, hydrocarbon gases in reservoirs within the fourth section of the Upper Sinian Dengying Formation were derived from both the Lower Cambrian and Upper Sinian source rocks; and (2) in the Eastern Sichuan Basin, hydrocarbon gases in Middle Carboniferous Huanglong Formation reservoirs were mainly derived from Lower Silurian source rocks, while those in Upper Permian and Lower Triassic reservoirs were mainly derived from both Upper Permian and Lower Silurian marine source rocks. For both the source and reservoir rocks, bitumen III fractions generally show relatively lower maturity near the peak oil generation stage, while the other two bitumen fractions show very high maturities based on terpane and sterane distributions. Tricyclic terpanes evolved from the distribution pattern C20 < C21 < C23, through C20 < C21 > C23, finally to C20 > C21 > C23 during severe thermal stress. The concentration of C30 diahopane in bitumen III (the bound components released from confined pyrolysis) is substantially lower than in the other two bitumen fractions for four terrigenous Upper Permian source rocks, demonstrating that this compound originated from free hopanoid precursors, rather than hopanoids bound to the kerogen. 相似文献
10.
以代表性暗棕壤垂直剖面土壤地球化学数据为依据,研究了长白山区特定的森林景观条件下成土过程中元素的分异与富集特征。研究结果表明,在岩石风化过程中主要以CaO、Na2O、Sr淋溶为主,有机酸淋溶过程中SiO2、Al2O3、K2O部分被淋溶,部分游离铁下渗到土体中下部氧化成铁锰胶膜;微量元素在风化过程中被次生黏土矿物吸附,不同程度地富集,在腐殖质积累过程中Cd、Zn、Pb、Mo、Hg、Co、Mn、Cr等亲生物元素进一步富集于表层土壤,Ce、Ni、Sb、Ti、V、Y、Zr在表生环境中地球化学性质稳定,残留富集于土壤表层。母质层继承和保留了基岩元素地球化学分布的基本特征。 相似文献