Water productivity and integrated water resources management     

《Physics and Chemistry of the Earth》2016

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Contamination,bioaccessibility and human health risk of heavy metals in exposed-lawn soils from 28 urban parks in southern China's largest city,Guangzhou     

《Applied Geochemistry》2016

The total concentrations and oral bioaccessibility of heavy metals in surface-exposed lawn soils from 28 urban parks in Guangzhou were investigated, and the health risks posed to humans were evaluated. The descending order of total heavy metal concentrations was Fe > Mn > Pb > Zn > Cu > Cr > Ni > Cd, but Cd showed the highest percentage bioaccessibility (75.96%). Principal component analysis showed that Grouped Cd, Pb, Cr, Ni, Cu and Zn, and grouped Cr and Mn could be controlled two different types of human sources. Whereas, Ni and Fe were controlled by both anthropogenic and natural sources. The carcinogenic risk probabilities for Pb and Cr to children and adults were under the acceptable level (<1 × 10⁻⁴). Hazard Quotient value for each metal and Hazard Index values for all metals studied indicated no significant risk of non-carcinogenic effects to children and adults in Guangzhou urban park soils.  相似文献   

Mapping the hydraulic connection between a coalbed and adjacent aquifer: example of the coal-seam gas resource area,north Galilee Basin,Australia     

Zhenjiao Jiang  Gregoire Mariethoz  Christoph Schrank  Malcolm Cox  Wendy Timms 《Hydrogeology Journal》2016,24(8):2143-2155

Coal-seam gas production requires groundwater extraction from coal-bearing formations to reduce the hydraulic pressure and improve gas recovery. In layered sedimentary basins, the coalbeds are often separated from freshwater aquifers by low-permeability aquitards. However, hydraulic connection between the coalbed and aquifers is possible due to the heterogeneity in the aquitard such as the existence of conductive faults or sandy channel deposits. For coal-seam gas extraction operations, it is desirable to identify areas in a basin where the probability of hydraulic connection between the coalbed and aquifers is low in order to avoid unnecessary loss of groundwater from aquifers and gas production problems. A connection indicator, the groundwater age indictor (GAI), is proposed, to quantify the degree of hydraulic connection. The spatial distribution of GAI can indicate the optimum positions for gas/water extraction in the coalbed. Depressurizing the coalbed at locations with a low GAI would result in little or no interaction with the aquifer when compared to the other positions. The concept of GAI is validated on synthetic cases and is then applied to the north Galilee Basin, Australia, to assess the degree of hydraulic connection between the Aramac Coal Measure and the water-bearing formations in the Great Artesian Basin, which are separated by an aquitard, the Betts Creek Beds. It is found that the GAI is higher in the western part of the basin, indicating a higher risk to depressurization of the coalbed in this region due to the strong hydraulic connection between the coalbed and the overlying aquifer.  相似文献   

Arsenic contamination caused by roxarsone transformation with spatiotemporal variation of microbial community structure in a column experiment          下载免费PDF全文

Liu Ya-ci  Zhang Zhao-ji  Zhao Xin-yi  Wen Meng-tuo  Cao Sheng-wei  Li Ya-song 《地下水科学与工程》2021,9(4):304-316

Arsenic contamination from roxarsone in livestock manure is common, and livestock manure continuously accumulates in the open environment. Evaluations of the environmental processes of As mobilization and transformation are critical for predicting the fate of As compounds after roxarsone degradation. In this study, spatiotemporal variations in As species and microbial community structure were characterized using laboratory column experiments with background soil collected from Yanggu County (northern Shandong Plain, China), a region of intense poultry production. Organic and inorganic arsenic were detected by high-performance liquid chromatography (HPLC) and HPLC with hydride generation atomic fluorescence spectrometry (HPLC-HG-AFS), respectively. High-throughput sequencing technology was used to describe microbial diversity. Results showed that roxarsone was transformed completely within 7 days, and As(Ⅲ) and As(Ⅴ) were the major degradation products. The concentration of As(Ⅲ) was much lower than that of As(Ⅴ). The As(Ⅲ) concentration increased significantly after Day 14, whereas the As(Ⅴ) concentration increased significantly after Day 84, indicating that As(Ⅲ) was initially produced. The microbial community structure changed significantly as roxarsone transformed into various As compounds. A critical and dominant bacterial strain, norank_f__Family_XVⅢ, was found to be related to the degradation of roxarsone into As(Ⅲ). This study improves our understanding of the fate of As species released from poultry litter to soil and groundwater, which is a threat to human health and environment.  相似文献   

Sensitivity assessment of strontium isotope as indicator of polluted groundwater for hydraulic fracturing flowback fluids produced in the Dameigou Shale of Qaidam Basin          下载免费PDF全文

Zheng Zhao-xian  Cui Xiao-shun  Zhu Pu-cheng  Guo Si-jia 《地下水科学与工程》2021,9(2):93-101

Hydrogeochemical processes that would occur in polluted groundwater and aquifer system, may reduce the sensitivity of Sr isotope being the indicator of hydraulic fracturing flowback fluids(HFFF) in groundwater. In this paper, the Dameigou shale gas field in the northern Qaidam Basin was taken as the study area, where the hydrogeochemical processes affecting Sr isotope was analysed. Then, the model for Sr isotope in HFFF-polluted groundwater was constructed to assess the sensitivity of Sr isotope as HFFF indicator. The results show that the dissolution can release little Sr to polluted groundwater and cannot affect the εSr(the deviation of the 87 Sr/86 Sr ratio) of polluted groundwater. In the meantime, cation exchange can considerably affect Sr composition in the polluted groundwater. The Sr with low εSr is constantly released to groundwater from the solid phase of aquifer media by cation exchange with pollution of Quaternary groundwater by the HFFF and it accounts for 4.6% and 11.0% of Sr in polluted groundwater when the HFFF flux reaches 10% and 30% of the polluted groundwater, respectively. However, the Sr from cation exchange has limited impact on Sr isotope in polluted groundwater. Addition of Sr from cation exchange would only cause a 0.2% and 1.2% decrease in εSr of the polluted groundwater when the HFFF flux reaches 10% and 30% of the polluted groundwater, respectively. These results demonstrate that hydrogeochemical processes have little effect on the sensitivity of Sr isotope being the HFFF indicator in groundwater of the study area. For the scenario of groundwater pollution by HFFF, when the HFFF accounts for 5%(in volume percentage) of the polluted groundwater, the HFFF can result in detectable shifts of εSr(ΔεSr=0.86) in natural groundwater. Therefore, after consideration of hydrogeochemical processes occurred in aquifer with input of the HFFF, Sr isotope is still a sensitive indicator of the Quaternary groundwater pollution by the HFFF produced in the Dameigou shale of Qaidam Basin.  相似文献   

Comment on a paper by Sibuet et al. (2016) entitled “Thinned continental crust intruded by volcanics beneath the northern Bay of Bengal”     

《Marine and Petroleum Geology》2017

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Response to the comment by M. Lustrino on “High-pressure melting experiments on garnet clinopyroxenite and the alkalic–tholeiitic transition in ocean-island basalts” by Keshav et al. [Earth Planet. Sci. Lett. 223, 365–379 (2004)]     

《Earth and Planetary Science Letters》2006,241(3-4):997-999

We welcome the comments made by Lustrino [M. Lustrino, Pyroxenites everywhere, Earth Planet. Sci. Lett., this issue.] on the high-pressure experimental melting phase relations of anhydrous garnet pyroxenite reported by Keshav et al. [S. Keshav, G.H. Gudfinnsson, G. Sen, Y. Fei, High-pressure melting experiments on garnet clinopyroxenite and the alkalic-to-tholeiitic transition in ocean-island basalts, Earth Planet. Sci. Lett. 223 (2004) 365–379.]. Such healthy debates, in our view, are needed to promote our understanding on the origin of oceanic-island basalts (OIB).  相似文献   

The development of a multi-surface soil speciation model for Cd (II) and Pb (II): Comparison of two approaches for metal adsorption to clay fractions     

《Applied Geochemistry》2014

The mobility of toxic metals in soils or sediments is of great concern to scientists and environmentalists since it directly affects the bioavailability of metals and their movement to surface and ground waters. In this study, a multi-surface soil speciation model for Cd (II) and Pb (II) was developed to predict the partition of metals on various soil solid components (e.g. soil organic matter (SOM), oxide mineral, and clay mineral). In previous study, the sorption of metal cations on SOM and oxide minerals has been evaluated by thermodynamically based surface complexation model. However, metal binding to soil clay fractions was normally treated in a simplistic manner: only cation exchange reactions were considered and exchange coefficient was assumed unity. In this study, the binding of metals onto clays was described by a two-site surface sorption model (a basal surface site and an edge site). The model was checked by predicting the adsorption behavior of Cd (II) and Pb (II) onto three selected Chinese soils as a function of pH and ionic strengths. Results showed that the proposed model more accurately predicted the metal adsorption on soils under studied condition, especially in low ionic strength condition, suggesting that adsorption of metals to soil clay fractions need to be considered more carefully when modeling the partition of trace elements in soils. The developed soil speciation model will be useful when evaluating the movement and bioavailability of toxic metals in soil environment.  相似文献   

Response of runoff to climate change in the area of runoff yield in upstream Shiyang River Basin,Northwest China: A case study of the Xiying River          下载免费PDF全文

Shu-hong Song  Zhen-long Nie  Xin-xin Geng  Xue Shen  Zhe Wang  Pu-cheng Zhu 《地下水科学与工程》2023,11(1):89-96

The objective of this study was to analyze the response of runoff in the area of runoff yield of the upstream Shiyang River basin to climate change and to promote sustainable development of regional water resources and ecological environment. As the biggest tributary of the Shiyang River, Xiying River is the only hydrological station (Jiutiaoling) that has provincial natural river and can achieve long time series monitoring data in the basin. The data obtained from this station is representative of natural conditions because it has little human activites. This study built a regression model through identifying the characteristics of runoff and climate change by using Mann-Kendall nonparametric statistical test, cumulative anomaly, and correlation analysis. The results show that the average annual runoff is 320.6 million m³/a with the coefficient of variation of 0.18 and shows slightly decrease during 1956–2020. It has a significant positive correlation the average annual precipitation (P<0.01). Runoff is sensitive to climate change, and the climate has becoming warm and wet and annual runoff has entering wet period from 2003. Compared to the earlier period (1955–2000), the increases of average annual temperature, precipitation and runoff in recent two decades were 15%, 9.3%, and 7.8%, respectively. Runoff in the Shiyang River is affected by temperature and precipitation among climate factors, and the simulation results of the runoff-climate response model (R = 0.0052P ? 0.1589T + 2.373) indicate that higher temperature leads to a weakening of the ecological regulation of surface runoff in the flow-producing area.  相似文献   

A Numerical Simulation Study of Temperature and Pressure Effects on the Breakthrough Pressure of CO2 in Unsaturated Low-permeability Rock Core     

HU Zhikai  LI Yi  LI Qi  DIAO Yujie  MA Xin  LIU Hejuan  FENG Guanhong  WANG Fugang  YU Qingchun 《《地质学报》英文版》2023,97(3):911-924

Gas breakthrough pressure is a key parameter to evaluate the sealing capacity of caprock, and it also plays important roles in safety and capacity of CO2 geological storage. Based on the published experimental results, we present numerical simulations on CO2 breakthrough pressure in unsaturated low-permeability rock under 9 multiple P-T conditions (which can keep CO2 in gaseous, liquid and supercritical states) and thus, a numerical method which can be used to accurately predict CO2 breakthrough pressure on rock-core scale is proposed. The simulation results show that CO2 breakthrough pressure and breakthrough time are exponential correlated with P-T conditions. Meanwhile, pressure has stronger effects on experimental results than that of temperature. Moreover, we performed sensitivity studies on the pore distribution index λ (0.6, 0.7, 0.8, and 0.9) in van Genuchten-Muale model. Results show that with the increase of λ, CO2 breakthrough pressure and breakthrough time both show decreasing trends. In other words, the larger the value of λ is, the better the permeability of the caprock is, and the worse the CO2 sealing capacity is. The numerical method established in this study can provide an important reference for the prediction of gas breakthrough pressure on rock-core scale and for related numerical studies.  相似文献