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101.
The Kenting Mélange on the Hengchun Peninsula, Taiwan, formed through tectonic shearing of subduction complex lithologies, probably within the plate boundary subduction channel between the Eurasian and Philippine Sea plates, with further deformation and exhumation in the Pliocene–Pleistocene during arc–continent collision. Field relations reveal a structural gradation from normal stratified turbidite sequence (Mutan Formation) through broken formation to highly sheared Kenting Mélange containing allochthonous polygenic blocks. This gradation is consistent with an increase of average vitrinite reflection values from ~ 0.72% in the Mutan Formation through ~ 0.93% in the broken formation to ~ 0.99% in the mélange, suggesting temperatures of at least 140 °C during formation of the Kenting Mélange. Zircons from gabbro in the Kenting Mélange are dated as 25.46 ± 0.18 Ma, which together with geochemical data constrains the source to South China Sea oceanic lithosphere. In combination with the field relationships, vitrinite reflectance values, microfossil stratigraphy, and offshore geophysical data from S and SE Taiwan, we propose that the Kenting Mélange initially formed at the subduction plate boundary from off-scraped trench deposits. Minor Plio–Pleistocene microfossils (< 5%) occur within the mélange in proximity to slope basin of equivalent age and were likely sheared into the mélange during out-of-sequence thrusting associated with active arc–continent collision, which in the Hengchun Peninsula commenced after 6.5 Ma.  相似文献   
102.
The late Paleozoic Bailingshan intrusions and volcanic rocks are located in the Aqishan–Yamansu arc belt in the southern part of the eastern Tianshan and are associated with an important group of iron skarn deposits. The exposed intrusive rocks are mainly granodiorite, monzonitic granite, and granite. Zircon U–Pb dating of the Tugutublak Formation tuffaceous dacitic lava yields an age of 324 Ma, whereas dates of the Bailingshan granodiorite, monzonitic granite, and granite yields ages of 317 Ma, 313 Ma, and 307 Ma, respectively. The results indicate that the Bailingshan granitoids were emplaced soon after the eruption of the Tugutublak dacite. All these rocks studied show calc-alkaline to high-K calc-alkaline and metaluminous affinities, with A/CNK values ranging 0.83–1.10. They are enriched in Rb, K, and Pb, depleted in Nb, Ta, Ti, and P, and contain low Sr/Y (4.16–23.7) and Sr (109.0–347.0 ppm) values, displaying typical arc geochemical affinities. The tuffaceous dacitic lava has low Nb/Ta (10.3–14.1) values, a wide range of Mg# (6–64), positive zircon εHf(t) (3.2–7.5) values, and elevated whole-rock εNd(t) (2.03–4.41), but low ISr values (0.70427–0.70530), indicating that the source magma may have been derived from the juvenile lower crust with minor mantle input. The Bailingshan I-type intrusions also exhibit a mixed source signal, as constrained by Nb/Ta ratios, Mg#, and isotopes characteristics. Because the granodiorite, monzonitic granite, and granite intrusions have higher zircon εHf(t) (3.3–7.5, 11.8–13.5, and 10.2–14.4, respectively) and εNd(t) (3.90, 5.78, and 5.94, respectively) values than those of the tuffaceous dacitic lava, it is suggested that mantle-derived materials may have played a more prominent role with their petrogenetic evolution. Integrating our new geological, age, geochemical and isotopic data we propose that the Aqishan–Yamansu iron skarn belt may have formed in a back-arc position or within an intra-arc basin generated by the southward subduction of the Kanggur oceanic plate beneath the Yili–Central Tianshan block during the late Paleozoic, with felsic-intermediate magmatism occurring during the basin inversion.  相似文献   
103.
The NW–SE trending Longshoushan is in the southwestern margin of the Alxa Block, which was traditionally considered the westernmost part of the North China Craton (NCC). Precambrian crystalline basement exposed in the Longshoushan area was termed the “Longshoushan Complex”. This complex's formation and metamorphism are significant to understand the geotectonics and early Precambrian crustal evolution of the western NCC. In this study, field geology, petrology, and zircon U–Pb and Lu–Hf isotopes of representative orthogneisses and paragneisses in the Longshoushan Complex were investigated. U–Pb datings reveal three Paleoproterozoic magmatic episodes (ca. 2.33, ca. 2.17 and ca. 2.04 Ga) and two subsequent regional metamorphic events (ca. 1.95–1.90 Ga and ca. 1.85 Ga) for metamorphic granitic rocks in the Longshoushan Complex. U–Pb dating of the detrital magmatic zircons from two paragneisses yields concordant 207Pb/206Pb ages between 2.2 Ga and 2.0 Ga, and a small number of metamorphic zircon rims provide a ca. 1.95 Ga metamorphic age, suggesting that the depositional time of the protolith was between 2.0 and 1.95 Ga and that the sedimentary detritus was most likely derived from the granitic rocks in the Longshoushan Complex itself. Zircon Lu–Hf isotopic analyses indicate that nearly all magmatic zircons from ca. 2.0 Ga to ca. 2.17 Ga orthogneisses have positive εHf(t) values with two-stage Hf model ages (TDMC) ranging from 2.45 to 2.65 Ga (peak at ca. 2.5 Ga), indicating that these Paleoproterozoic granitic rocks were derived from the reworking of the latest Neoarchean–early Paleoproterozoic juvenile crust. Detrital magmatic zircons from two paragneisses yield scattered 176Hf/177Hf ratios, εHf(t) and TDMC values, further indicating that the sedimentary detritus was not only derived from these plutonic rocks but also from other unreported or denuded Paleoproterozoic igneous rocks. The ca. 2.15 Ga detrital magmatic zircons from one paragneiss have negative εHf(t) values with TDMC ranging from 2.76 to 3.04 Ga, indicating another important crustal growth period in the Longshoushan region. These data indicate that the Longshoushan Complex experienced Neoarchean–Early Paleoproterozoic crustal growth, approximately ca. 2.3–2.0 Ga experienced multiphase magmatic events, and approximately ca. 1.95–1.90 Ga and ca. 1.85 Ga experienced high-grade metamorphic events. The sequence of tectonothermal events is notably similar to that of the main NCC. Together with the datasets from an adjacent area, we suggest that the western Alxa Block was most likely an integrated component of the NCC from the Neoarchean to the Paleoproterozoic.  相似文献   
104.
The Atkan Formation in the Ayan-Yuryakh anticlinorium, Magadan province, northeastern Russia, is of great interest because of the occurrence of deposits of apparent “dropstones” and “ice rafted debris” that have been previously interpreted as glacial. Two high-precision U–Pb zircon ages, one for an intercalated volcanic tuff (262.5 ± 0.2 Ma) and the other for a boulder clast (269.8 ± 0.1 Ma) within a diamictite of the Atkan Formation, constrain the age of the Atkan Formation as Guadalupian (middle Permian). Sedimentologic study of the Atkan Formation casts doubt on the glacial nature of the diamictites. Deposition of rocks of the Atkan Formation temporally correlates with the Capitanian interglacial event in the southern hemisphere that recently was calibrated with high precision CA-TIMS. The previously proposed climate proxy record based upon warm-water foraminifera, which corresponds closely to global climate fluctuations, is compared with the glacial record of eastern Australia and indicates that the Capitanian was a time of globally warm climate. The sedimentology of Atkan Formation, the record of diversification of both fusulinids and rugosa corals, global sea-water temperature, and sea-level fluctuations agree well with high latitude paleoclimate records in northeastern Russia and eastern Australia. Major components of the Atkan Formation, the volcanic rocks, are syngenetic with the sedimentation process. The volcanic activity in the nearby regions during middle–late Permian was quite extensive.  相似文献   
105.
The Indochina–Simao and Yangtze blocks were separated by a branch of the Paleo-Tethys Ocean, commonly referred as the Ailaoshan Ocean in the Paleozoic. Remnants of this Ailaoshan Ocean have been variably suggested to locate along (from east to west) the Ailaoshan fault, Jiujia–Anding fault and Amojiang–Lixianjiang fault. In order to test these models, we have carried out comprehensive detrital zircon U–Pb dating and Hf isotope analyses on the Cambrian to Devonian sedimentary units in the Ailaoshan Belt and its adjacent western margin of the Yangtze Block. Our results indicate marked detrital zircon provenance variation on different sides of the Ailaoshan–Tengtiaohe fault: detrital zircons from east of the fault display a diagnostic age peak at 730–900 Ma, which is characterized by both positive and negative εHf(t) values with a Hf model age (TDMC) peak at ~ 1.8 Ga, whereas detrital zircons from west of the fault display two major age populations of 400–500 and 900–1000 Ma, both characterized by mainly negative εHf(t) values with a Hf model age (TDMC) peak at ~ 2.1 Ga. Our new data indicate that detritus from east and west of the Ailaoshan–Tengtiaohe fault may have been mainly derived from, respectively, the Yangtze Block and Indochina–Simao blocks, thus suggesting the fault may represent the actual suture between the two blocks. Our study also reveals that the Ailaoshan Ocean may have started its early continental rift in the Early Silurian.  相似文献   
106.
The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.  相似文献   
107.
There is a dearth of information about the distribution of trace elements in kerogen from shale rocks despite several reports on trace element composition in many shale samples. In this study, trace elements in shale rocks and their residual kerogens were determined by inductively coupled plasma–mass spectrometry. The results from this study show redox-sensitive elements relatively concentrated in the kerogens as compared to the shales. This may be primarily due to the adsorption and complexation ability of kerogen, which enables enrichment in Ni, Co, Cu, and Zn. For the rare earth elements (REEs), distinct distribution characteristics were observed for shales dominated by terrigenous minerals and their kerogen counterparts. However, shales with less input of terrigenous minerals showed similar REE distribution patterns to their residual kerogen. It is speculated that the distribution patterns of the REEs in shales and kerogens may be source-related.  相似文献   
108.
109.
The ~?2-km-thick Panzhihua gabbroic-layered intrusion in SW China is unusual because it hosts a giant Fe–Ti oxide deposit in its lower zone. The deposit consists of laterally extensive net-textured and massive Fe–Ti oxide ore layers, the thickest of which is ~?60 m. To examine the magmatic processes that resulted in the Fe enrichment of parental high-Ti basaltic magma and the formation of thick, Fe–Ti oxide ore layers, we carried out a detailed study of melt inclusions in apatite from a ~?500-m-thick profile of apatite-bearing leucogabbro in the middle zone of the intrusion. The apatite-hosted melt inclusions are light to dark brown in color and appear as polygonal, rounded, oval and negative crystal shapes, which range from ~?5 to ~?50 µm in width and from ~?5 to ~?100 µm in length. They have highly variable compositions and show a large and continuous range of SiO2 and FeOt with contrasting end-members; one end-member being Fe-rich and Si-poor (40.2 wt% FeOt and 17.7 wt% SiO2) and the other being Si-rich and Fe-poor (74.0 wt% SiO2 and 1.20 wt% FeOt). This range in composition may be attributed to entrapment of the melt inclusions over a range of temperature and may reflect the presence of µm-scale and immiscible Fe-rich and Si-rich components in different proportions. Simulating results for the motion of Si-rich droplets within a crystal mush indicate that Si-rich droplets would be separated from Fe-rich melt and migrate upward due to density differences in the interstitial liquid when the magma unmixed. Migration of the Si-rich, immiscible liquid component from the interstitial liquid caused the remaining Fe-rich melt in the lower part to react with plagioclase primocrysts (An59–60), as evidenced by fine-grained lamellar intergrowth of An-rich plagioclase (An79–84)?+?clinopyroxene in the oxide gabbro of the lower zone. Therefore, magma unmixing within a crystal mush, combined with gravitationally driven loss of the Si-rich component, resulted in the formation of Fe-rich, melagabbro and major Fe–Ti oxide ores in the lower part and Si-rich, leucogabbro in the upper part of the intrusion.  相似文献   
110.
针对近年来长白山火山下方地幔转换带中是否存在低波速异常指示的太平洋板块"空缺"而引起的不同科学认识的热烈辩论,本文主要回顾了我国东北地区地幔转换带的体波成像结果。使用相对走时残差的远震体波成像结果显示,长白山火山以西地幔转换带中存在低波速异常指示的太平洋板块"空缺";而使用绝对走时残差的区域成像和全球成像结果,尽管展示出长白山火山以西比以东略低的波速异常,但长白山火山以东至我国东北重力梯度带区域下方的地幔转换带均展示出明显的连续的高波速异常。在接收函数分析时,如果以全球平均值660km而非我国东北地区平均值670km作为基准,来分析660km间断面是抬升还是下沉;以全球平均值250km而非我国东北地区平均值260km作为基准,来分析地幔转换带是增厚还是减薄的话,则可以得到长白山火山以东至我国东北重力梯度带区域660km间断面下沉与地幔转换带增厚的认识。这种与绝对走时残差成像结果展示的地幔转换带为连续的高波速异常结果相一致的结果,说明太平洋板块俯冲前缘已由日本海沟抵达我国东北松辽盆地与大兴安岭交界处。结合高温高压实验、数值模拟与岩石地球化学研究结果,本文并不支持长白山火山以西的地幔转换带存在低波速异常指示的板块"空缺"和地幔转换带"减薄"的认识。长白山火山的深部起源与太平洋板块深俯冲至我国东北松辽盆地与大兴安岭交界处形成的"大地幔楔"结构动力学相关。  相似文献   
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