抑制型离子色谱法同时测定水中锂和锶   总被引：2，自引：0，他引：2  

桂建业  张永涛张莉 《岩矿测试》2006,25(1):87-88

对离子色谱法测定水中的锂、锶含量及其影响因素进行了研究。以甲烷磺酸为流动相，用IonPacCS12A阳离子色谱柱分离后，电导检测器同时测定矿泉水中锂和锶，其检出限分别为0．003mg／L和0．006mg／L。对Li^＋和Sr^2＋的离子色谱条件进行了优化，并对流动相的选择及干扰离子的影响进行了讨论。  相似文献   

地下水人工调蓄研究进展与问题   总被引：7，自引：0，他引：7  

费宇红  崔广柏 《水文》2006,26(4):10-14

通过对国内外地下水调蓄有关资料分析,阐明了地下水库、地下调蓄和人工回灌补给理念之间差异及其关系；阐述了国外地下水人工调蓄研究状况及其发展趋势,回顾了国内地下水人工调蓄发展过程及存在的问题,给出了了地下水调蓄基本原理及其条件；结合我国北方地区水资源面临的危机,提出了急需研究的科学问题。  相似文献   

ArcGIS空间分析技术在地下水评价中的应用   总被引：1，自引：0，他引：1  

陈浩  胡燕  王贵玲  张薇  蔺文静  范琦  侯新伟 《水文地质工程地质》2007,34(4):112-115

ArcGIS是目前世界具有代表性的地理信息系统，其强大的空间分析技术，在各行业中得到广泛应用。本文就空间分析技术在地下水评价中的应用进行了探讨，并在实际工作中成功地进行了研究区域的地下水评价，其高效特点使工作强度大大减小，是值得进一步推广的地下水评价方法。  相似文献   

同忻井田采空区积水贮存分布特征及突水预测   总被引：1，自引：0，他引：1  

狄效斌 《水文地质工程地质》2007,34(3):24-27

本文依据井田范围内采空积水调查资料,探讨了采空积水的贮存分布规律,并采用冒落带及导水裂隙带最大高度的计算方法,预测了未来开采下伏可采煤层造成的漏水灾害区。  相似文献   

The application of isotope and chemical analyses in managing transboundary groundwater resources     

《Applied Geochemistry》2013

Managing transboundary groundwater resources requires accurate and detailed knowledge of aquifers and groundwater bodies. The Pannonian Basin is the largest intracontinental basin in Europe with a continuous succession of more than 7 km of Miocene to Quaternary sediments and with an average geothermal gradient of about 5 °C/100 m. Geographically the Pannonian basin overlaps eight countries (Hungary, Romania, Serbia, Croatia, Slovenia, Austria, Slovakia and Ukraine), so the issue of transboundary cold and thermal water resources is regionally very important. The T-JAM bilateral Hungarian–Slovenian (HU–SLO) project is the first to apply modern isotopic and chemical analyses in the characterization and correlation of a number of shared groundwater resources in the Mura-Zala Sub-basin of the Pannonian. The aims of this work were the identification of groundwater flow paths, the delineation of transboundary aquifers based on thermal and cold groundwater geochemical and isotope properties in the Mura-Zala Basin, and providing input to calibrate a hydraulic numerical model. Following a common groundwater sampling campaign, 24 cold and thermal groundwater samples from seven aquifers were collected for chemical, isotope, gas and noble gas analyses. Chemical analyses, and D, O and C isotopes were used to correlate cross border aquifers. A regional groundwater flow is hydrogeologically possible in some aquifers in the Mura-Zala Basin, and has been confirmed by hydrogeochemistry. The Újfalu (HU) and Mura (SLO) Formations are a part of the active regional thermal groundwater flow system, probably hydraulically separated from the shallower flow system of the Ptuj-Grad (SLO), Zagyva and Somló-Tihany (HU) Formations. The thermal water is of meteoric origin, reductive and alkaline. The predominant water type in the Quaternary and Pliocene aquifers is Ca–Mg–HCO₃, changing to Na–HCO₃ in the main Pannonian geothermal aquifer, and Na–Cl brine in deeper and older Miocene aquifers. Total dissolved solids and Na content generally increase with depth. Deuterium is in the range −87‰ to −75‰, ¹⁸O from −11.9‰ to −10.4‰, while ¹⁴C values are less than 6.1 pmC in the samples of the active regional thermal groundwater flow system. These and results of noble gas analyses indicate recharge during the Pleistocene interglacial period with temperatures around 6–7 °C. Regional thermal water resources are limited and environmental isotopes can be used as an early warning in the management of thermal water.  相似文献   

Litho-stratigraphic effect on Variscan fluid flow within the Prague synform,Barrandian: Evidence based on C,O, Sr isotopes and fluid inclusions     

《Marine and Petroleum Geology》2012,36(1):128-138

The Palaeozoic sedimentary sequence of the Prague synform (Ordovician–Devonian) in the centre of the Bohemian massif underwent Variscan deformation and thermal overprint events. Variscan veins widespread throughout the sedimentary strata have precipitated from syntectonic aqueous and hydrocarbon-rich fluids. Homogenization temperatures of aqueous inclusions increased from 70 up to 226 °C in the Cambrian rocks underlying the Prague synform. Seawater, modified due to intensive water–rock interaction, was the main fluid component. Fluid flow was limited and restricted to the lithostratigraphic compartments forming a rock-buffered system. Stable isotopic modelling (C, O) and final interpretations of the confined hydrostratigraphic fluid migration was supported by the ⁸⁷Sr/⁸⁶Sr ratio in veins and wall rocks. Siliciclastic Cambrian and Ordovician rocks and the associated intersecting veins yielded similar isotopic signatures, and consequently the fluid migration is restricted to layer- and formation-scales. Gradually downwards increasing fluid temperature and compositional changes reflect burial at oil-window conditions. An open fluid system could be expected in proximity of major faults of the Prague syncline and at the top of the sedimentary sequence.  相似文献   

Hydrogeochemical models locating sulfate-methane transition zone in marine sediments overlying black shales: A new tool to locate biogenic methane?     

《Marine and Petroleum Geology》2015

Precise hydrogeochemical modeling of early diagenesis is a key in the reconstruction of sedimentary basin models. This determines the mineralogical evolution of the sediment and consequently the porosity of the rock. During early diagenesis also part of the initial organic matter is converted into biogenic gas: CH₄ CO₂, and H₂S. These processes are part of complex reaction chains during sedimentation, and biogeochemical reactions leave different signals that can be observed today. In this work, we reproduce the early diagenetic processes as integrated signals over geological times in sediments of the Demerara Rise by applying chemical thermodynamics using the PHREEQC (version 2) computer code. The investigated sediments are characterized by the presence of black shales in 410–490 mbsf and by a diagenetic barite layer above in 300–350 mbsf at depth of sulfate-methane transition (SMT). We determine the parameters that influence the location of diagenetic barite peaks in sediments overlying black shales by means of a novel modeling approach. Crucial parameters are the amount of bacterial organic matter mineralization, sedimentation rates and bottom water sulfate concentrations. All parameters are intertwining and influence the sulfate-methane cycle. They affect the location of the SMT visualized by diagenetic barite peaks. However, our model approach opens a wide field in exploring early diagenetic reactions, processes and products (such as biogenic methane) over geological times mirrored by diagenetic minerals and pore water concentration profiles that can be detected in present-day sediments.  相似文献   

深层水漏斗区开采量组成变化特征与机制   总被引：1，自引：0，他引：1       下载免费PDF全文

张光辉  费宇红  杨丽芝  刘中培  连英立 《水科学进展》2010,21(3):370-376

为阐明强烈开采条件下华北平原深层水的开采水量来源及组成问题,以德州地区深层水漏斗分布区为重点研究区,通过基于大量钻孔资料对含水层组及其粘性土夹层或透镜体的分析和野外地下水采样、动态监测及地面沉降测量资料等分析,采用分层、分区计算方法对漏斗中心至外围的各分区弹性释水量、粘性土压密释水量、侧向流入和越流补给量进行均衡计算。结果表明:在强烈开采条件下,深层水开采量中弹性释水量和压密释水量所占比率不是常量,随着深层水位下降的幅度和深度增大、超采释压持续时间愈长、开采层中粘性土夹层或透镜体愈多,则区内弹性释水和压密释水的强度及累积地面沉降量愈大;愈靠近漏斗中心,弹性和压密释水强度愈大,相同降深下平均单位降深的地面沉降量愈小。在深层水开采量中粘性土压密释水占35.5%~61.9%,与地面沉降密切相关。  相似文献   

浅层地下水补给对人类活动影响的响应特征研究   总被引：3，自引：1，他引：2  

王金哲  张光辉  母海东  严明疆  聂振龙  王莹 《地球学报》2010,31(4):557-562

本文通过数据整理分析, 查明滹沱河流域平原区1976-2005年以开采量、灌区引水量和河道过水量为代表的人类活动逐渐增强, 分析了浅层地下水补给在大气降水减少和人类活动逐渐增强背景下大幅减少的响应特征: 综合补给量所占比率由1976-1980年的21.6%下降到2000-2005年的11.3%。随后, 从开采量、河道过水量和灌区引水量三个方面分析了浅层地下水补给响应人类活动的变化特征: 地下水补给量与开采量呈y=65.412x-0.2576模式随降水量增减而负相关变化; 河道渗漏补给量和渠水入渗量在地下水位不同埋深条件下表现出随来水量、引水量增加而增大的态势, 但在不同埋深条件下, 河道渗漏补给量与来水量之间、渠水入渗量和引水量之间关系不同。  相似文献   

液闪法测量水中氚放射性活度的淬灭效应   总被引：3，自引：2，他引：1  

张向阳  刘福亮  张琳  郭华良 《岩矿测试》2010,29(4):469-471

采用液体闪烁计数法进行放射性同位素测量时存在淬灭效应,而且几乎每个样品的淬灭程度都不同,并影响测量精度。采用液体闪烁计数法测量水中氚的放射性活度,淬灭是难以避免的,因此要进行淬灭校正,才能使不同淬灭程度的样品的测量结果具有可比性。淬灭校正的方法有很多,外标准校正法是一种比较可靠的方法。文章采用氚外标准校正法进行实验,得出淬灭校正曲线即探测效率E与淬灭参数SQP(E)的关系式为E=0.001 3SQP(E)-0.707 6,经过样品验证,该曲线是可靠的。采用外标准校正法适合于大批样品的测量。  相似文献