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101.
102.
Condensed water particles are known to exist in the high latitude upper mesosphere during the summer months. However, the mechanism or mechanisms through which they nucleate remains uncertain. It is postulated here that particles of amorphous solid water (ASW, condensed water with a non-crystalline structure) may nucleate homogeneously in the summer mesosphere. Using classical nucleation theory and a one-dimensional model, it is shown that more than 105 cm?3 amorphous solid water particles can nucleate homogeneously under mesopause conditions. Furthermore, it is shown that homogeneous nucleation competes with heterogeneous nucleation on meteoric smoke particles when the cooling rate is >0.5 K/h. The homogeneous nucleation of amorphous solid water could provide an explanation for the high density of ice particles (many thousands per cm3) thought to be required for electron depletions in the upper mesosphere. A parameterisation for homogeneous nucleation is presented which can be used in other mesospheric cloud models.  相似文献   
103.
This paper presents a semi-analytical method for studying the two-dimensional problem of elastic wave scattering by surface irregularities in a half-space. The new method makes use of the member of a c-completeness family of wave functions to construct the scattering fields, and then applies equal but opposite tractions to those of the foregoing constructed scattering fields on the horizontal surface of the half-space to produce additional scattering fields. These additional scattering fields are a series of Lamb's solutions. Thus the whole scattering field constructed in the series automatically satisfies the Navier equations, the condition of zero traction on the half-space surface, and the radiation boundary conditions at infinity. Using the traction-free conditions along the canyon surface, the coefficients of the series solutions are determined via a least-squares method. For incident P, SV, and Rayleigh waves, the numerical results are presented for the scattering displacements in the vicinity of a semi-circular canyon in the half-space.  相似文献   
104.
锡(Sn)被认为是具有环境负效应的元素。近年来,不同地区的沉积物样品显示近几十年来地壳中的Sn明显快速上升,并认为煤炭的燃烧可能是导致环境中Sn含量增加的重要途径。锡在中国煤中的平均含量约为3.38 μg/g,略高于世界煤中Sn的均值,与上地壳的含量基本持平。由于煤中Sn的含量在10-6量级,因此,在测试过程中可以考虑选择利用ICP MS和高精度AAS结合微波消解技术对Sn进行测定。因为该元素本身在煤中含量微少,几乎不以独立的矿物相存在,因此鲜少有文献报道。但在本文中,还是提出了几种Sn在煤中的可能存在方式:锡石态、硫化物态、钽铌矿物中的类质同象、有机结合态、硅酸盐矿物中的类质同象,以及非紧密结合的可交换离子态。并以中国典型的高Sn煤层为例,分析了高Sn煤出现的可能原因。此外,当煤中Sn的赋存状态为可交换离子态与有机质结合态时,部分Sn可以在煤的开采和燃烧中迁移并进入环境,应当予以关注。  相似文献   
105.
A newly identified northwest–southeast oriented, deeply-rooted, steep to vertical, large-scale structural system within the Proterozoic Curnamona Province, Australia, which we term the “Benagerie Shear Zone”, is imaged in regional magnetic and gravity datasets. In this study, we use a combination of field analysis and quantitative geophysical methods, to establish a 1100 Myr history of activity along the Benagerie Shear Zone during which the location of younger geological structures are influenced by the pre-existing shear zone. This deformational system is interpreted to have 1) aided ascent and emplacement of the ca. 1600 Ma Ninnerie (magmatic) Supersuite; 2) controlled the loci of nucleation of normal faults during rifting and continental breakup at ca. 800 Ma; and 3) influenced the development of fold structures as well as acting as a plane co-linear to the rotation axis of pre-existing normal faults such that they were steepened and reactivated as strike slip structures during the ca. 500 Ma Delamerian Orogeny. We interpret that the Benagerie Shear Zone has not undergone uni-directional propagation during its evolution but rather through reactivation was a primary influence on controlling the nucleation of Neoproterozoic rift faults, thereby playing a major role in accommodating strain over a significant period of the evolution of the Curnamona Province. This study demonstrates that crustal-scale shear zones can evolve over hundreds of millions of years, have strike-lengths of hundreds to thousands of kilometers, and have vastly different surface expressions along strike.  相似文献   
106.
Digital Elevation Model (DEM) is a quantitative representation of terrain and is important for Earth science and hydrological applications. DEM can be generated using photogrammetry, interferometry, ground and laser surveying and other techniques. Some of the DEMs such as ASTER, SRTM, and GTOPO 30 are freely available open source products. Each DEM contains intrinsic errors due to primary data acquisition technology and processing methodology in relation with a particular terrain and land cover type. The accuracy of these datasets is often unknown and is non-uniform within each dataset. In this study we evaluate open source DEMs (ASTER and SRTM) and their derived attributes using high postings Cartosat DEM and Survey of India (SOI) height information. It was found that representation of terrain characteristics is affected in the coarse postings DEM. The overall vertical accuracy shows RMS error of 12.62 m and 17.76 m for ASTER and SRTM DEM respectively, when compared with Cartosat DEM. The slope and drainage network delineation are also violated. The terrain morphology strongly influences the DEM accuracy. These results can be highly useful for researchers using such products in various modeling exercises.  相似文献   
107.
Cambodia is one of the most vulnerable countries to climate change impacts such as floods and droughts. Study of future climate change and drought conditions in the upper Siem Reap River catchment is vital because this river plays a crucial role in maintaining the Angkor Temple Complex and livelihood of the local population since 12th century. The resolution of climate data from Global Circulation Models (GCM) is too coarse to employ effectively at the watershed scale, and therefore downscaling of the dataset is required. Artificial neural network (ANN) and Statistical Downscaling Model (SDSM) models were applied in this study to downscale precipitation and temperatures from three Representative Concentration Pathways (RCP 2.6, RCP 4.5 and RCP 8.5 scenarios) from Global Climate Model data of the Canadian Earth System Model (CanESM2) on a daily and monthly basis. The Standardized Precipitation Index (SPI) and Standardized Precipitation Evapotranspiration Index (SPEI) were adopted to develop criteria for dry and wet conditions in the catchment. Trend detection of climate parameters and drought indices were assessed using the Mann-Kendall test. It was observed that the ANN and SDSM models performed well in downscaling monthly precipitation and temperature, as well as daily temperature, but not daily precipitation. Every scenario indicated that there would be significant warming and decreasing precipitation which contribute to mild drought. The results of this study provide valuable information for decision makers since climate change may potentially impact future water supply of the Angkor Temple Complex (a World Heritage Site).  相似文献   
108.
The effects of eutrophication on short term changes in the microbial community were investigated using high resolution lipid biomarker and trace metal data for sediments from the eutrophic Lake Rotsee (Switzerland). The lake has been strongly influenced by sewage input since the 1850s and is an ideal site for studying an anthropogenically altered ecosystem. Historical remediation measures have had direct implications for productivity and microbial biota, leading to community composition changes and abundance shifts. The higher sewage and nutrient input resulted in a productivity increase, which led predominantly to a radiation in diatoms, primary producers and methanogens between about 1918 and 1921, but also affected all microorganism groups and macrophytes between about 1958 and 1972. Bacterial biomass increased in 1933, which may have been related to the construction of a mechanical sewage treatment plant. Biomarkers also allowed tracing of fossil organic matter/biodegraded oil contamination in the lake. Stephanodiscus parvus, Cyclotella radiosa and Asterionella formosa were the dominant sources of specific diatom biomarkers. Since the 1850s, the cell density of methanogenic Archaea (Methanosaeta spp.) ranged within ca. 0.5–1.8 × 109 cells g−1 dry sediment and the average lipid content of Rotsee Archaea was ca. 2.2 fg iGDGTs cell−1. An altered BIT index (BITCH), indicating changes in terrestrial organic matter supply to the lake, is proposed.  相似文献   
109.
Diffusion coefficients of dense gases in liquids can be measured by considering two-phase binary nonequilibrium fluid mixing in a closed cell with a fixed volume. This process is based on convection and diffusion in each phase. Numerical simulation of the mixing often requires accurate algorithms. In this paper, we design two efficient numerical methods for simulating the mixing of two-phase binary fluids in one-dimensional, highly permeable media. Mathematical model for isothermal compositional two-phase flow in porous media is established based on Darcy’s law, material balance, local thermodynamic equilibrium for the phases, and diffusion across the phases. The time-lag and operator-splitting techniques are used to decompose each convection–diffusion equation into two steps: diffusion step and convection step. The Mixed finite element (MFE) method is used for diffusion equation because it can achieve a high-order and stable approximation of both the scalar variable and the diffusive fluxes across grid–cell interfaces. We employ the characteristic finite element method with moving mesh to track the liquid–gas interface. Based on the above schemes, we propose two methods: single-domain and two-domain methods. The main difference between two methods is that the two-domain method utilizes the assumption of sharp interface between two fluid phases, while the single-domain method allows fractional saturation level. Two-domain method treats the gas domain and the liquid domain separately. Because liquid–gas interface moves with time, the two-domain method needs work with a moving mesh. On the other hand, the single-domain method allows the use of a fixed mesh. We derive the formulas to compute the diffusive flux for MFE in both methods. The single-domain method is extended to multiple dimensions. Numerical results indicate that both methods can accurately describe the evolution of the pressure and liquid level.  相似文献   
110.
We address the geoeffectiveness of three interplanetary structures in the interplanetary space: magnetic clouds (MCs), interplanetary shocks (IPSs), and corotating interaction regions (CIRs). The geoeffectiveness is evaluated using the geomagnetic indices Kp, AE, and Dst. We find that MCs are more geoeffective than IPSs, or CIRs. The average values of magnetic indices are significantly enhanced during disturbed periods associated with MCs, IPSs and CIRs, compared to the whole interval. The highest effect is noted for MC disturbed periods.Results obtained for the three data sets are used to derive a theoretical (continuous) probability distribution function (PDF) by fitting the histograms representing the percentage of events against the intervals of magnetic index. PDFs allow estimation of the probability of a given level of geomagnetic activity to be reached after the detection, by in situ solar wind observations, of a given interplanetary structure approaching the Earth.  相似文献   
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