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1.
Confronted by observations, the difficulties to explain the formation of the iron lines in active galactic nuclei (AGNs) in the context of the current “reflection disk-photoelectric absorption-fluorescence line” model are discussed in detail, and it is further pointed out that a newly recognized line emission mechanism — the Cerenkov line-like radiation could be the dominant mechanism to produce the AGN iron line. The negative effect of the hydrogen plasma on the refractive index is proved to be negligible. The Cerenkov iron line emission is calculated for the optically thin case and compared with the observations. The reasonableness of this new mechanism is verified, thus providing a new scenario for the physical situation around a black hole.  相似文献   
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This study investigated proton adsorption to an extracellular polymeric substance (EPS) producing bacterial strain, Bacillus licheniformis S-86, in order to characterise and quantify the contribution made by EPS to cell surface reactivity. Potentiometric titrations were conducted using both untreated cells and cells from which the EPS layer had been extracted. Surface-complexation modelling indicated the presence of four different functional groups in both untreated and EPS-free cells. These sites are assigned to phosphodiester, (pKa 3.3–3.4), carboxylic (pKa 5.3–5.4), phosphoryl/ (pKa 7.4–7.5) and hydroxyl/amine (pKa 9.9–10.1) type groups. The pKa values for the four groups were very similar for untreated and EPS-free cells, indicating no qualitative difference in composition, but site concentrations in the untreated cells were statistically found to be significantly higher than those in the EPS-free cells for the pKa 3.3–3.4 and pKa 9.9–10.1 sites. Infrared analysis provided supporting evidence that site 2 is carboxylic in nature but did not reveal any difference in IR absorption between the native and EPS-free cells. Dissolved organic carbon (DOC) analysis conducted during this study indicated that DOC release by cells is significant, and that the EPS layer is the major contributor.  相似文献   
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A steady-state reaction-transport model is applied to sediments retrieved by gravity core from two stations (S10 and S13) in the Skagerrak to determine the main kinetic and thermodynamic controls on anaerobic oxidation of methane (AOM). The model considers an extended biomass-implicit reaction network for organic carbon degradation, which includes extracellular hydrolysis of macromolecular organic matter, fermentation, sulfate reduction, methanogenesis, AOM, acetogenesis and acetotrophy. Catabolic reaction rates are determined using a modified Monod rate expression that explicitly accounts for limitation by the in situ catabolic energy yields. The fraction of total sulfate reduction due to AOM in the sulfate-methane transition zone (SMTZ) at each site is calculated. The model provides an explanation for the methane tailing phenomenon which is observed here and in other marine sediments, whereby methane diffuses up from the SMTZ to the top of the core without being consumed. The tailing is due to bioenergetic limitation of AOM in the sulfate reduction zone, because the methane concentration is too low to engender favorable thermodynamic drive. AOM is also bioenergetically inhibited below the SMTZ at both sites because of high hydrogen concentrations (∼3-6 nM). The model results imply there is no straightforward relationship between pore water concentrations and the minimum catabolic energy needed to support life because of the highly coupled nature of the reaction network. Best model fits are obtained with a minimum energy for AOM of ∼11 kJ mol−1, which is within the range reported in the literature for anaerobic processes.  相似文献   
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Sewage water rich in P poses a threat to natural water systems. In households that are not connected to a sewer network, an easily maintained purification technique is needed to remove P from domestic waste waters. In the present study, the P retention properties of phlogopite-rich mine tailings were studied to determine whether the untapped tailings can be utilised in wastewater treatment for this purpose. On the basis of its chemical and mineralogical properties, this material, produced in the enrichment process of apatite ore in Siilinjärvi, Finland, can be assumed to act as a P sorbent. The P retention capacity and the P sorption mechanisms of phlogopite-rich tailings were studied with desorption–sorption isotherms and various chemical extractions. The impact of the artificial weathering of the material as well as the reaction time and particle size on P retention were also investigated. The fluctuating shape of the isotherm determined for the untreated material suggests the operation of several sorption mechanisms. The results imply that phlogopite-rich tailings retain P efficiently through specific sorption by amorphous Al and Fe oxides and possibly also by calcite present as an accessory mineral. Acidification of the material, extended reaction time and decrease in particle-size markedly increased the P retention.  相似文献   
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Crude petroleum was emulsified or degraded by marine microorganisms and physically altered by an artificial weathering process. Only the water-soluble fraction from emulsified crude petroleum inhibited glutamate uptake by marine microorganisms from South Carolina and Georgia coastal waters. Chloroform extraction recovered almost equal amounts of total hydrocarbon from each water-soluble fraction. Chromatographic data indicated that the composition of microbially emulsified petroleum was similar to that of microbially degraded petroleum. Emulsification of crude petroleum was only observed in summer water samples and did not consistently occur at a given location. Results of this study indicate that the process by which crude petroleum is altered will influence its toxicity to microbial heterotrophic activity.  相似文献   
7.
A survey of the aerobic heterotrophic bacteria present in sediments at Sawyers Bay, New Zealand, receiving tannery effluent high in Cr, and a control site, indicates that the populations present are different and show seasonal variation. The bacterial population present at the polluted site appears more able to tolerate CrIII at concentrations less than 0·2 μmol ml?1.  相似文献   
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This in situ study reports on the relevance of intact phospholipids as new biomarkers and highlights the limits of the classical fatty acid analysis after the hydrolysis of the polar lipid fraction. The analysis of polar lipid fractions revealed significant contributions of marine macrophytes with either non-phospholipid compounds (sulfoquinovosyl diacylglycerol) or with both non-bacterial phospholipid classes (phosphatidylcholine) and non-bacterial phospholipid molecular species (some molecular species of phosphatidylglycerol). The analysis of intact phospholipids showed also the predominance of gram-negative bacteria in sediments whereas the analysis of fatty acids alone cannot confirm such information. Lastly, as regard to the effects of petroleum hydrocarbons on the sedimentary bacterial communities, we observed a higher degree of saturation of the fatty acyl chains of the phospholipids extracted from sediment exposed to a massive and chronic crude oil contamination. Such a result was interpreted as an adaptive response resulting in higher membrane rigidity of the bacterial communities.  相似文献   
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A study of the microbial uptake and respiration (mineralization) of radioactive glutamic acid was made in 141 surface water samples in the Cook Inlet, Alaska during three sampling periods (October, 1976; April, 1977; and November, 1977). The rate at which the test substrate was incorporated into cell material plus that respired as CO2 was used to calculate the relative microbial activity. A northern water mass with salinities less than 31 showed high rates of relative microbial activity but low mineralization rates as indicated by respiration of14CO2. The reverse pattern was seen in the water mass (salinity higher than 31) to the south which was more typical of coastal water. These data suggest that the organic nutrients in these two water masses are quite different either qualitatively or quantitatively. This study illustrates how the observed measurement of relative microbial activity might be helpful in defining specific water masses.(The publication of this article was unintentionally delayed owing to a fault in secretarial routine.)Published as Technical Paper No. 6009, Oregon Agricultural Experiment Station.  相似文献   
10.
Microbially produced lipopeptide have been isolated and studied for microbial enhanced oil recovery. About 60 gram positive bacteria isolated from soil contaminated with crude oil, near the crude oil storage tank in Tehran Refinery, Tehran, Iran. However, most of these studies have produced lipopeptide by one of the pure-culture microbes isolated in a laboratory. Among the isolates, heamolytic tests revealed two biosurfactant producers. The isolated strains were designated as C2, E1. By using morphological, biochemical and molecular biology tests (16 SrRNA), the strains identified as Bacillus licheniformis and Bacillus subtitlis, respectively. Emulsification activity and measurement of surface tension indicated that, the isolates were high producers of biosurfactant. The product of C2 and E1 is mainly lipopeptide. This product reduce surface tension from 65 to 30 mN/m. Emulsified activity of crude oil was 92% for C2 and 90 % in case of E1. This is the first report of indigenous Bacillus licheniformis and Bacillus subtilis from a soil contaminated with oil in an Iranian refinery with ability to produce biosurfactant.  相似文献   
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