A caveat regarding diatom-inferred nitrogen concentrations in oligotrophic lakes     

Heather A. Arnett  Jasmine E. Saros  M. Alisa Mast 《Journal of Paleolimnology》2012,47(2):277-291

Atmospheric deposition of reactive nitrogen (Nr) has enriched oligotrophic lakes with nitrogen (N) in many regions of the world and elicited dramatic changes in diatom community structure. The lakewater concentrations of nitrate that cause these community changes remain unclear, raising interest in the development of diatom-based transfer functions to infer nitrate. We developed a diatom calibration set using surface sediment samples from 46 high-elevation lakes across the Rocky Mountains of the western US, a region spanning an N deposition gradient from very low to moderate levels (<1 to 3.2 kg Nr ha⁻¹ year⁻¹ in wet deposition). Out of the fourteen measured environmental variables for these 46 lakes, ordination analysis identified that nitrate, specific conductance, total phosphorus, and hypolimnetic water temperature were related to diatom distributions. A transfer function was developed for nitrate and applied to a sedimentary diatom profile from Heart Lake in the central Rockies. The model coefficient of determination (bootstrapping validation) of 0.61 suggested potential for diatom-inferred reconstructions of lakewater nitrate concentrations over time, but a comparison of observed versus diatom-inferred nitrate values revealed the poor performance of this model at low nitrate concentrations. Resource physiology experiments revealed that nitrogen requirements of two key taxa were opposite to nitrate optima defined in the transfer function. Our data set reveals two underlying ecological constraints that impede the development of nitrate transfer functions in oligotrophic lakes: (1) even in lakes with nitrate concentrations below quantification (<1 μg L⁻¹), diatom assemblages were already dominated by species indicative of moderate N enrichment; (2) N-limited oligotrophic lakes switch to P limitation after receiving only modest inputs of reactive N, shifting the controls on diatom species changes along the length of the nitrate gradient. These constraints suggest that quantitative inferences of nitrate from diatom assemblages will likely require experimental approaches.  相似文献   

Mercury in the Southern North Sea and Scheldt estuary     

《Marine Chemistry》2001,75(3):229-248

Dissolved and particulate mercury and methylmercury concentrations were determined in the Southern Bight of the North Sea and the Scheldt estuary in the period 1991–1999. Mercury and methylmercury concentrations are higher before 1995 than after 1995, especially in the fluvial part.The North Sea: In the offshore stations, dissolved Hg concentrations are generally higher in winter than in summer while the reverse is true for particulate Hg K_D values (K_D=the concentration of particulate Hg (Hg_P in pmol kg⁻¹) divided by the concentration of dissolved Hg (Hg_D in pmol l⁻¹)) range from 100,000 to 1000,000 l kg⁻¹. Dissolved methylmercury concentrations vary from 0.05 to 0.25 pmol l⁻¹ in summer and from d.l. to 0.23 pmol l⁻¹ in winter and particulate methylmercury concentrations from 1.8 to 36 pmol g⁻¹ in summer and from 0.9 to 21 pmol g⁻¹ in winter. The K_D ranges from 9,000 to 219,000 l kg⁻¹.The Scheldt estuary: In winter, dissolved Hg concentrations are elevated in the upper estuary, decrease exponentially in the low salinity range followed by a very slow decrease towards the mouth. In summer, they are low in the fluvial part, increase in the low salinity range or in the mid-estuary and sometimes show an increase in the lower estuary. Particulate Hg concentrations do not show any seasonal trend.Dissolved MMHg concentrations are much lower in winter, when maximum concentrations are found in the upper estuary, than in summer. In summer, the MMHg concentrations are low at low salinity, they show a first increase in the salinity range from 3 to 12, a decrease in the mid-estuary and a second increase in the lower estuary.The highest particulate MMHg concentrations are found in the upper estuary, while in the lower estuary generally lower and more constant values are observed. The ratio of dissolved MMHg to dissolved Hg (cruise averages between 1.3% and 20%), is higher than the ratio of particulate MMHg to particulate Hg (cruise averages of 0.27–0.90%). The K_D values for MMHg are lower in the summer (30,000–65,000) than in autumn and winter (77,000–114,000).The Scheldt river: In the fluvial part of the Scheldt, dissolved increases in the most upstream stations, while particulate Hg shows no particular pattern. Dissolved MMHg ranges from 0.1 to 0.39 pmol l⁻¹ and particulate MMHg from 3.1 to 43.5 pmol g⁻¹. The MMHg concentrations are comparable to those found in the estuary and no seasonal variations could be observed.  相似文献   

区域渔业管理组织中的鲨鱼养护管理问题研究     

褚晓琳  唐议  陈勇 《海洋通报》2019,38(2):132-140

目前鲨鱼养护管理问题已引起国际社会的广泛关注,《鲨鱼养护管理国际行动计划》和《濒危野生动植物种国际贸易公约》等国际文件从生态系统保护和贸易管控角度对鲨鱼问题做出规定。为了顺应国际社会加强鲨鱼养护管理的趋势,RFMOs出台了一系列决议和措施。对此,作为远洋渔业大国的我国应针对目前履行RFMOs管理规定中存在的问题,尽早做好各项准备,以彰显我国渔业大国的负责任态度,更好地维护我国远洋渔业合法权益。第一,对外加大宣传,树立我国远洋渔业的正面形象;第二,加强远洋渔业从业人员培训,强化远洋渔船监管;第三,加强国际渔业法律科学人才队伍建设,提升在国际渔业管理中的话语权和主导权;第四,转变我国渔业法规指导理念,确立以养护为主的渔业管理基本方针。  相似文献   

Monitoring qualitative spatiotemporal change for geosensor networks     

Mike Worboys  Matt Duckham 《International journal of geographical information science》2013,27(10):1087-1108

Recent technological advances in geosensor networks demand new models of distributed computation with dynamic spatial information. This paper presents a computational model of spatial change in dynamic regions (such as may be derived from discretizations of continuous fields) founded on embeddings of graphs in orientable surfaces. Continuous change, connectedness and regularity of dynamic regions are defined and local transition rules are used to constrain region evolution and enable more efficient inference of a region's state. The model provides a framework for the detection of global high‐level events based on local low‐level ‘snapshot’ spatiotemporal data. The approach has particular relevance to environmental monitoring with geosensor networks, where technological constraints make the detection of global behaviour from local conditions highly advantageous.  相似文献   

Advancements and best practices for analysis and correlation of tephra and cryptotephra in ice     

《Quaternary Geochronology》2017

Geochemical analysis of fine grained (<20 μm) tephra found in ice cores is inherently difficult, due to the typically low number and small size of available particles. Ice core tephra samples require specialized sample preparation techniques to maximize the amount of information that can be gained from these logistically limited samples that may provide important chronology to an ice record, as well as linking glacial, marine and terrestrial sediments. We have developed a flexible workflow for preparation of tephra and cryptotephra samples to allow accurate and robust geochemical fingerprinting, which is fundamental to tephrochronology. The samples can be prepared so that secondary electron imagery can be obtained for morphological characterization of the samples to ensure that the sample is tephra-bearing and then the sample can be further prepared for quantitative electron microprobe analysis using wavelength dispersive techniques (EMP-WDS), scanning electron microscopy with energy dispersive spectrometry (SEM-EDS), laser ablation inductively coupled mass spectrometry (LA-ICP-MS) or secondary ion mass spectrometry (SIMS). Some samples may be too small for typical instrumentation conditions to be used (i.e. 20 μm beam on the EMP) to analyze for geochemistry and we present other techniques that can be employed to obtain accurate, although less precise, geochemistry. Methods include analyzing unpolished tephra shards less than 5 μm in diameter with a 1 μm beam on an SEM; using the “broad beam overlap” EMP method on irregular particles less than 20 μm in diameter, and analyzing microlitic shards as well as aphyric shards using EMP to increase the number of analyzed shards in low abundance tephra layers. The methods presented are flexible enough to be employed in other geological environments (terrestrial, marine and glacial) which will help maximize and integrate multiple environments into the overall tephra framework.  相似文献   

Socio-economic vulnerability due to climate change: Deriving indicators for fishing communities in Mumbai     

《Marine Policy》2017

This paper assessed the socio-economic implications of climate change and vulnerability of fishing communities known as “Koli” living in Mumbai, India. The vulnerability indicators are derived from sustainable livelihood literature and use of multi-criteria analyses and are validated with expert opinions. A survey of two hundred fishermen from five fishing villages in Mumbai was conducted to collect data. The results demonstrate that vulnerability perpetuates due to physical and financial resource constraints among the fishing community. Fishermen from Madh and Worli villages are observed to be more vulnerable and less adaptive due to their inability to use efficient mechanized boats and advanced fishing implements, such as fish finders and GPS (Global Positioning System). The divergence in the vulnerability scores among fishing villages is attributed to the coping strategies, resource availability, knowledge and the benefit derived from the local government. Fishermen have been observing the negative impacts of climate change on their fishing livelihoods. Adaptation strategies to maximize fish catch are observed in such practices as targeting different species and fishing intensively for several days. However, these practices are leading to an imbalance in the common resource pool and biased resource sharing among different groups of fishermen.  相似文献   

Modeling the long-term variability of phytoplankton functional groups and primary productivity in the South China Sea     

Wentao Ma  Fei Chai  Peng Xiu  Huijie Xue  Jun Tian 《Journal of Oceanography》2013,69(5):527-544

Primary productivity (PP) and phytoplankton structure play an important role in regulating oceanic carbon cycle. The unique seasonal circulation and upwelling pattern of the South China Sea (SCS) provide an ideal natural laboratory to study the response of nutrients and phytoplankton dynamics to climate variation. In this study, we used a three-dimensional (3D) physical–biogeochemical coupled model to simulate nutrients, phytoplankton biomass, PP, and functional groups in the SCS from 1958 to 2009. The modeled results showed that the annual mean carbon composition of small phytoplankton, diatoms, and coccolithophores was 33.7, 52.7, and 13.6 %, respectively. Diatoms showed a higher seasonal variability than small phytoplankton and coccolithophores. Diatoms were abundant during winter in most areas of the SCS except for the offshore of southeastern Vietnam, where diatom blooms occurred in both summer and winter. Higher values of small phytoplankton and coccolithophores occurred mostly in summer. Our modeled results indicated that the seasonal variability of PP was driven by the East Asian Monsoon. The northeast winter monsoon results in more nutrients in the offshore area of the northwestern Luzon Island and the Sunda Shelf, while the southwest summer monsoon drives coastal upwelling to bring sufficient nutrients to the offshore area of southeastern Vietnam. The modeled PP was correlated with El Niño/Southern Oscillation (ENSO) at the interannual scale. The positive phase of ENSO (El Niño conditions) corresponded to lower PP and the negative phase of ENSO (La Niña conditions) corresponded to higher PP.  相似文献   

Incorporating uncertainty into the estimation of biological reference points for a spiny lobster (Panulirus penicillatus) fishery     

Yi‐Jay Chang  Chi‐Lu Sun  Yong Chen  Su‐Zan Yeh  Wei‐Chuan Chiang 《新西兰海洋与淡水研究杂志》2013,47(1):429-442

The status of a fishery is often defined as the probability of fishing mortality rate exceeding a perilous level for long‐term sustainability. Lobster stock assessments are often subject to large uncertainty in input data and high levels of natural variability in lobster life history processes, which calls for incorporating uncertainty associated with both indicator and management reference points in an evaluation of biological risk of overfishing. Using a Monte Carlo simulation approach, we evaluated the impacts of uncertainty in modelling on the determination of the status of the Taitung spiny lobster (Panulirus penicillatus) fishery (Taiwan), which has not been quantitatively determined despite its commercial importance. The commonly used biological reference points derived from the per recruit model (F _0.1 the fishing mortality rate where the slope of the curve of yield‐per‐recruit model is 10% of the maximum slope and F _4Q%, the fishing mortality rate that reduces the expected egg production for a cohort of female lobsters to 40% of that produced in the absence of a fishery of the egg‐per‐recruit model) were influenced by uncertainties associated with lobster life history and fishery parameters. A large uncertainty in the current fishing mortality rate (F _cnr) and estimates of biological reference points (F _BRPs) increased the uncertainty in determining the risk of overexploitation throughout the confidence levels of the stochastic decision‐making framework. This simulation study suggests that the target reference point of F _40% is less sensitive to the input parameters’ uncertainty than F _0.1 We suggest a further evaluation of other F‐based references points and development of biomass‐based reference points before final selection and implementation for the management of the Taitung lobster fishery.  相似文献   

The most extensive Holocene advance in the Stauning Alper, East Greenland, occurred in the Little Ice Age   总被引：1，自引：0，他引：1  

Brenda L. Hall  Carlo Baroni  & George H. Denton 《Polar research》2008,27(2):128-134

We present glacial geologic and chronologic data concerning the Holocene ice extent in the Stauning Alper of East Greenland. The retreat of ice from the late-glacial position back into the mountains was accomplished by at least 11 000 cal years B.P. The only recorded advance after this time occurred during the past few centuries (the Little Ice Age). Therefore, we postulate that the Little Ice Age event represents the maximum Holocene ice extent in this part of East Greenland.  相似文献   

An inter-laboratory comparison of cosmogenic 3He and radiogenic 4He in the CRONUS-P pyroxene standard     

《Quaternary Geochronology》2015

This study reports an inter-laboratory comparison of the ³He and ⁴He concentrations measured in the pyroxene material CRONUS-P. This forms part of the CRONUS-Earth and CRONUS-EU programs, which also produced a series of natural reference materials for in situ produced ²⁶Al, ¹⁰Be, ¹⁴C, ²¹Ne and ³⁶Cl.Six laboratories (GFZ Potsdam, Caltech Pasadena, CRPG Nancy, SUERC Glasgow, BGC Berkeley, Lamont New York) participated in this intercomparison experiment, analyzing between 5 and 22 aliquots each. Intra-laboratory results yield ³He concentrations that are consistent with the reported analytical uncertainties, which suggests that ³He is homogeneous within CRONUS-P. The inter-laboratory dataset (66 determinations from the 6 different labs) is characterized by a global weighted mean of (5.02 ± 0.12) × 10⁹ at g⁻¹ with an overdispersion of 5.6% (2σ). ⁴He is characterized by a larger variability than ³He, and by an inter-lab global weighted mean of (3.60 ± 0.18) × 10¹³ at g⁻¹ (2σ) with an overdispersion of 10.4% (2σ).There are, however, some systematic differences between the six laboratories. More precisely, 2 laboratories obtained mean ³He concentrations that are about 6% higher than the clustered other 4 laboratories. This systematic bias is larger than the analytical uncertainty and not related to the CRONUS-P material (see Schaefer et al., 2015). Reasons for these inter-laboratory offsets are difficult to identify but are discussed below. To improve the precision of cosmogenic ³He dating, we suggest that future studies presenting cosmogenic ³He results also report the ³He concentration measured in the CRONUS-P material in the lab(s) used in a given study.  相似文献