Mawsoniid remains (Sarcopterygii: Actinistia) from the lacustrine Missão Velha Formation (Lower Cretaceous) of the Araripe Basin,North-East Brazil     

《Cretaceous Research》2016

Mawsoniids are a lineage of extinct fresh/brackish water coelacanth fishes, common in Cretaceous Godwanan deposits of South America, North and West Africa and Madagascar. Here we formally describe mawsoniid remains from the fluvio-lacustrine Missão Velha Formation (Lower Cretaceous) of the Araripe Basin, North-East Brazil. The examples from the Missão Velha Formation are here described as Mawsonia cf. gigas, based mainly on elements of the lower jaw and opercular series. The occurrence of M. cf. gigas in the Missão Velha Formation expands the stratigraphic and geographical ranges of the type species.  相似文献   

Reactivity of micas and cap-rock in wet supercritical CO2 with SO2 and O2 at CO2 storage conditions     

《Applied Geochemistry》2016

Seal or cap-rock integrity is a safety issue during geological carbon dioxide capture and storage (CCS). Industrial impurities such as SO₂, O₂, and NOx, may be present in CO₂ streams from coal combustion sources. SO₂ and O₂ have been shown recently to influence rock reactivity when dissolved in formation water. Buoyant water-saturated supercritical CO₂ fluid may also come into contact with the base of cap-rock after CO₂ injection. Supercritical fluid-rock reactions have the potential to result in corrosion of reactive minerals in rock, with impurity gases additionally present there is the potential for enhanced reactivity but also favourable mineral precipitation.The first observation of mineral dissolution and precipitation on phyllosilicates and CO₂ storage cap-rock (siliciclastic reservoir) core during water-saturated supercritical CO₂ reactions with industrial impurities SO₂ and O₂ at simulated reservoir conditions is presented. Phyllosilicates (biotite, phlogopite and muscovite) were reacted in contact with a water-saturated supercritical CO₂ containing SO₂, or SO₂ and O₂, and were also immersed in the gas-saturated bulk water. Secondary precipitated sulfate minerals were formed on mineral surfaces concentrated at sheet edges. SO₂ dissolution and oxidation resulted in solution pH decreasing to 0.74 through sulfuric acid formation. Phyllosilicate dissolution released elements to solution with ∼50% Fe mobilized. Geochemical modelling was in good agreement with experimental water chemistry. New minerals nontronite (smectite), hematite, jarosite and goethite were saturated in models. A cap-rock core siltstone sample from the Surat Basin, Australia, was also reacted in water-saturated supercritical CO₂ containing SO₂ or in pure supercritical CO₂. In the presence of SO₂, siderite and ankerite were corroded, and Fe-chlorite altered by the leaching of mainly Fe and Al. Corrosion of micas in the cap-rock was however not observed as the pH was buffered by carbonate dissolution. Ca-sulfate, and Fe-bearing precipitates were observed post SO₂-CO₂ reaction, mainly centered on surface cracks and an illite rich illite-smectite precipitate quantified. Water saturated impure supercritical CO₂ was observed to have reactivity to rock-forming biotite, muscovite and phlogopite mineral separates. In the cap-rock core however carbonates and chlorite were the main reacting minerals showing the importance of assessing actual whole core.  相似文献   

Sulfur speciation with high performance liquid chromatography as a tool for El Chichón volcano,crater lake monitoring     

《Journal of South American Earth Sciences》2016

The monitoring of sulfur species in crater lakes has proven to be useful for forecasting episodes of volcanic unrest in certain active volcanoes, including Poás, Costa Rica; Kusatsu-Shirane, Japan; and Mt. Ruapehu, New Zealand. In this study, we have improved the current geochemical monitoring of El Chichón volcano through the setting of optimal high-performance liquid chromatography conditions (HPLC) for the analysis of S²⁻, SO₃²⁻, S₂O₃²⁻, S₄O₆²⁻ and SO₄²⁻ using a common chromatographic system. The procedure was applied to the analysis of lake samples taken in March, July and October of 2014 and April of 2015. The results were promising, since nearly all species were detected (with the exception of S₂O₃²⁻) in measurable amounts, including S²⁻ (<0.85–5.05 mg/L), SO₃²⁻ (<2.77–26.1 mg/L), S₄O₆²⁻ (108.27–303.82 mg/L) and SO₄²⁻ (489.58–676.26 mg/L). The spatial distribution of these species along the lakeshore showed zones of increased concentrations to the east and southeast of the lake, which provides information on the distribution of faults or cracks that feed hydrothermal fluids to the lake. This method thus provides additional information linked to the volcanic and hydrothermal activity of the volcano.  相似文献   

Role of heterogeneities in jointing (fracturing) of geological media: Numerical analysis of fracture mechanisms     

《Comptes Rendus Geoscience》2018,350(8):452-463

Fracture process is investigated using finite-difference simulations with a new constitutive model. It is shown that both geometry and fracture mechanism itself depend on the preexisting heterogeneities that are stress concentrators. In the brittle regime (low pressure, P), Mode-I fractures propagate normal to the least stress σ₃ from the imposed weak zones. At high P, shear deformation bands are formed oblique to σ₃. At intermediate values of P, the fracture process involves both shear banding and tensile cracking and results in the initiation and propagation of pure dilation bands. The propagating band tip undulates, reacting on the failure mechanism changes, but its global orientation is normal to σ₃. The σ₃-normal fractures are joints. There are thus two types of joints resulting from Mode-I cracking and dilation banding, respectively. The obtained numerical results are in good agreement with and explain the results from previous similar experimental study.  相似文献   

Convective and conductive heat transfer in sedimentary basins   总被引：1，自引：0，他引：1  

G. Vasseur  L. Demongodin 《Basin Research》1995,7(1):67-79

In the Earth's crust the temperature is largely controlled by heat conduction. However, under some circumstances, the thermal state is disturbed by advection of heat associated with groundwater flow. The corresponding thermal disturbance depends on the water flow velocity (modulus and direction) and therefore thermal data may be used to constrain the pattern of natural fluid flow. In this paper, some models of thermal disturbance induced by convective heat transfer are presented. They are based on the assumption that the water flow is concentrated in thin permeable structures such as aquifer or fault zones. The steady-state and transient thermal effects associated with such scenarios are computed using a somewhat idealized model which depends on a small number of parameters: flow rate, time, aquifer geometry and thermal parameters of surrounding rocks. In order to extract the conductive and convective components of heat transfer from temperature data and to estimate the corresponding fluid flow rate, it is first necessary to estimate the thermal conductivity field. The problem of the estimation of thermal conductivity in clay-rich rocks, based on laboratory and in-situ measurements, is emphasized. Then a method is proposed for the inversion of temperature data in terms of fluid flow. Vertical and lateral variations of thermal conductivity are taken into account and the fluid flow is assumed to be concentrated on a specified surface (2-D quasi-horizontal pattern). Thermal effects of the flow are simulated by a distribution of surface heat production which can be calculated and then inverted in terms of horizontal fluid flow pattern.  相似文献   

Experimental modelling of forearc basin development during accretionary wedge growth   总被引：1，自引：0，他引：1  

CHRISTOPHE Larroque  SYLVAIN Calassou†  JACQUES Malavieille†  FRANK Chanier‡ 《Basin Research》1995,7(3):255-268

We present results of three sand-box experiments that model the association between tectonic accretion and sedimentation in a forearc basin. Experimental sedimentation occurs step by step in the forearc basin during shortening of the sand wedge. In each experiment, the development of the accretionary wedge leads to the formation of a major backthrust zone. This major deformation zone accounts for the thickening in the rear part of the wedge. In natural settings this tectonic bulge dams sediments that are transported toward the trench from mountainous terrain behind the forearc. We test the variation of friction along the déollement and note the following: (1) shortening of a low-friction wedge involves a mechanical balance between forethrusts and backthrust propagation and this balance is recorded by the sedimentary sequence trapped in the forearc basin. Indeed, if most of the movement occurs along the backthrust, the deepening of the basin will be larger and consequently the thickness of the sedimentary sequence will be greater. (2) Such balance does not exist in the case of a high-friction wedge. (3) Variation of friction along the décollement during shortening of the sand wedge leads to modification in the forearc basin filling. Thus, for similar increments of convergence, the sequence deposited in the forearc basin shows relatively larger thickness when the wedge is shortened above a high-friction décollement. We suggest that contraction and thickening in the rear part of the wedge is an efficient mechanism to, initiate and develop a forearc basin. Thus, this kind of basin occurs in convergent settings, without collapse related to local extension or tectonic erosion. They represent a sedimentary trap on a passive basement, bounded by a tectonic bulge. The Quaternary Hikurangi forearc basin, southeast of the North Island of New Zealand, is bounded by two actively uplifting ridges. Thus, this basin is considered to be a possible example of the basins modelled in our experiments, and we suggest that the limit between the basin and the wedge could be a complex backthrust zone.  相似文献   

Paleo-stress orientations from calcite twins in the North Pyrenean foreland, determined by the Etchecopar inverse method   总被引：1，自引：0，他引：1  

C. Tourneret  P. Laurent 《Tectonophysics》1990,180(2-4):287-302

During the last decade, it has been shown that accurate analyses of calcite twinning in thin section may allow computation of the paleo-deviatoric stress tensor associated with this deformation. Following from the work of Larroque and Laurent (1988), and Lacombe et al. (1989), this is a new application of the Etchecopar inverse method. Weakly deformed limestones from about 150 to 200 km north of the Pyrenean chain (South France) were studied. The Etchecopar inverse method, which can be used on a microcomputer, is comparable to the method of analysis of striated fault planes proposed by Etchecopar et al. in 1981, as it determines the principal stress orientations and the stress ellipsoid shape ratio φ = (σ₂ − σ₃)/(σ₁ − σ₃). The Etchecopar method using calcite twins has been selected for this study because it is suitable for the determination of polyphase deformation in coarse-grained limestones (Lacombe et al. 1989).

Ten samples of oolitic limestones, cemented with sparry calcite, from the Bajocian (170 Ma) and the Oligocene (30 Ma) were studied. For each of them, only one or two stress tensors were determined: the first is characterized by a principal compressive stress axis σ₁ which is horizontal and approximately N-S. Local departures from this orientation have been observed and are interpreted as local stress perturbations. For the second, which was defined in the Oligocene, but occurred only locally in the Jurassic limestones, the position of σ₁ is nearly vertical; the direction of extension σ₃ is either NE-SW or undefined into the horizontal plane (σ₂ = σ₃); this radial extension is interpreted as the result of two or more superposed extensive deformation phases with vertical σ₁. The N-S compression was never found in the Oligocene limestones, and from its orientation, it is assumed to correspond to the Pyrenean deformation. These results are compared to the more complex deformation pattern obtained from classical microtectonical studies (Arthaud and Choukroune, 1972; Bonijoly and Blès, 1983; Granier and Blès, 1988; Blès et al., 1989). Only the major tectonic events are recorded by calcite twinning. Finally, the suitability of calcite twin analyses for the determination of complex polyphase deformation is discussed.  相似文献   

Comportement piezometrique des nappes d''alterites en zone intertropicale humide d''altitude (hauts plateaux de Madagascar)     

J.C Grillot  M Raunet  L Ferry 《Journal of Hydrology》1990,120(1-4):271-282

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The African rain forest vegetation and palaeoenvironments during late quaternary   总被引：4，自引：0，他引：4  

Jean Maley 《Climatic change》1991,19(1-2):79-98

This review paper presents first the main pollen results on the vegetation history of the rain forest during the late Quaternary.- The Lake Bosumtwi record (Ghana) shows the disappearance of rain forest from the base of the core (ca. 28 000 yr BP) to ca. 9000 yr BP. During this time interval the vegetation was of montane type with sparse clumps of trees. There is synchronism between montane vegetation disappearance and rain forest reappearance. This phenomenon occurred abruptly around 9000 yr BP.- The Lake Barombi Mbo record (West Cameroon) shows clearly that from ca. 24 000 yr BP until the present time, rain forest persisted with limited variations, and thus, this area represents a refuge area.From these data and other, one concludes that Afromontane vegetation extended to lowland during cool and humid phases.Other palaeoenvironmental data were obtained by diverse geological analyses of the lacustrine sediments. For Bosumtwi, the relatively precise reconstruction of lake-level fluctuations permitted several palaeoclimatic interpretations for the main Holocene phases.For Barombi Mbo, the evolution of total organic carbon (TOC) and total nitrogen (TON) seems to be related mainly to temperature evolution. By comparison with present-day mountain environments, TOC and TON increase in cool environments, but decrease when warmth and humidity increase, as during Holocene time, because the recycling processes speed up in the topsoil. For the same period the alteration of the soils in the catchment produced a strong increase of kaolinite. All these change intervened ca. 9500 yr BP, which is a key date in tropical Africa.In conclusion, climatic correlations between equatorial and dry north tropical Africa illustrate how changes in the forest block must have important effects on adjacent climatic zones.  相似文献   

Chromite crystallization in a multicellular magma flow: Evidence from a chromitite dike in the Oman ophiolite     

Marc Leblanc  Georges Ceuleneer 《Lithos》1991,27(4):231-257

The investigated chromitite dike is located at the top of an upwelling mantle structure of the Oman ophiolite (Maqsad diapir), in undeformed dunites displaying evidence for magma impregnation and circulation, just below the paleo-ridge axis. The chromitite dike is undeformed, its shape is that of an upward widening tube. It exhibits an internal layering which is roughly perpendicular to the cavity axis and comprises a vertical succession of four main layers showing a graded-bedding. Chromitite magmatic structures are beautifully preserved and result from a progressive crystallization from small euhedral crystals to wide octahedron-shaped nodules; dissolution textures provide evidence for late magmatic desequilibrium; sedimentation structures include flattening of the largest nodules. The silicate matrix comprises poikilitic forsterite and a locally abundant association of primary pargasite and plagioclase and alteration minerals (vesuvianite-chlorite-dolomite); pargasite inclusions are very abundant in the chromite. Chromite composition changes from one layer to the other and from core to rim in the chromite nodules (chromium decreases and titanium increases); Ti contents are generally high (0.4 to 0.8 wt.% TiO₂) with respect to podiform chromites. Platinum-group elements are not abundant but they show a strong fractionation at the scale of the orebody and of the main graded-bedded layers (Pd/Ir ratio varies from 0.5 to 11.5). REE patterns of chromitite parallel to those of gabbros and furthermore display a sea water related hydrothermal alteration (Ce negative anomaly).

The chromitite dike of Maqsad provides evidence for the crystallization of chromitite bodies in subvertical magma conduits below oceanic ridges; it corroborates the model of Cassard et al. (1981) and Lago et al. (1982) concerning the formation of chromitite pods in ophiolites which were later deformed and transposed into the horizontal plane due to the plastic flow prevailing away from the paleo-axial zone. Layering and chromite compositional variations are ascribed to a multicellular convective system segregating various stocks of chromite particles either in the upwelling flow of fresh magma or in the convective cells of fractionated residual magma in the confined part of the cavity. The estimated life-time for the magma influx is very short (<2 months). The parent-magma was probably of MORB-type and already fractionated (Ti-rich and PGE-poor), which is consistent with the strong evidence of magma-peridotite interactions in the core of the Maqsad diapir. Hydrous fluids were present during chromite crystallization (pargasite inclusions) suggesting that fluid-rich melts occur in the upper mantle.  相似文献