The lanthanide tetrad effect and its correlation with K/Rb,Eu/Eu1, Sr/Eu,Y/Ho,and Zr/Hf of evolving peraluminous granite suites     

《Geochimica et cosmochimica acta》1999,63(3-4):489-508

Lanthanide tetrad effects are often observed in REE patterns of more highly evolved Variscan peraluminous granites of mid-eastern Germany (Central Erzgebirge, Western Erzgebirge, Fichtelgebirge, and Northern Oberpfalz). The degree of the tetrad effect (TE_1,3) is estimated and plotted vs. K/Rb, Sr/Eu, Eu/Eu1, Y/Ho, and Zr/Hf. The diagrams reveal that the tetrad effect develops parallel to granite evolution, and significant tetrad effects are strictly confined to highly differentiated samples. Mineral fractionation as a cause for the tetrad effect is not supported by a calculated Rayleigh fractionation, which also could not explain the fractionation trends of Sr/Eu and Eu/Eu1. The strong decrease of Eu concentrations in highly evolved rocks suggests that Eu fractionates between the residual melt and a coexisting aqueous high-temperature fluid. Mineral fractionation as a reason for the tetrad effect is even more unlikely as REE patterns of accessory minerals display similar tetrad effects as the respective host rocks. The accessory minerals inherit the REE signature of the melt and do not contribute to the bulk-rock tetrad effect via mineral fractionation. These results point in summary to significant changes of element fractionation behavior in highly evolved granitic melts: ionic radius and charge, which commonly control the element distribution between mineral and melt, are no longer the exclusive control. The tetrad effect and the highly fractionated trace element ratios of Y/Ho and Zr/Hf indicate a trace element behavior that is similar to that in aqueous systems in which chemical complexation is of significant influence. This distinct trace element behavior and the common features of magmatic-hydrothermal alteration suggest the increasing importance of an aqueous-like fluid system during the final stages of granite crystallization. The positive correlation of TE_1,3 with bulk-rock fluorine contents hints at the importance of REE fluorine complexation in generating the tetrad effect. As the evolution of a REE pattern with tetrad effect (M-type) implies the removal of a respective mirroring REE pattern (W-type), the tetrad effect identifies open system conditions during granite crystallization.  相似文献   

A Cretaceous dike swarm provides evidence of a spreading axis in the back-arc basin of the Kohistan paleo-island arc,northwestern Himalaya,Pakistan     

《Journal of Asian Earth Sciences》2007,29(2-3):350-360

A 100–4000 m wide and 15 km long dike swarm, consisting of basalt and dolerite, occurs at the base of the Thelichi Formation in the Kohistan paleo-island arc terrane, north Pakistan. The dikes contain hornblende (altered from diopsidic-augite), diopsidic-augite (relics; ophitic to subophitic texture), chlorite, epidote, sphene, apatite, zircon, ilmenite, titanomagnetite and magnetite. The geochemistry reveals two groups of dikes: (1) Higher TiO₂ (2.74–3.50 wt%), Na₂O, Fe₂O₃ and lower Al₂O₃ (12.65–14.16 wt%) and MgO (3.73–5.04 wt%); (2) Lower TiO₂ (1.24–2.05 wt%), Na₂O, Fe₂O₃ and higher Al₂O₃ (14.02–16.52 wt%) and MgO (3.98–7.52 wt%). The MgO contents (3.73–7.52-wt%) show a variation in the dikes from relatively primitive to more evolved compositions. The dikes contain high amounts of both LILE and HFSE. The major, trace and rare-earth elements data confirm the MORB affinity and the back-arc basin origin of the dike swarm. The NW–SE orientation of the dike swarm and its 134 ± 3 Ma K–Ar age suggest the spreading axis of the back-arc basin in the Early Cretaceous.  相似文献   

青藏高原凯蒙蛇绿混杂岩中碱性火山岩的发现及意义     

潘政  史仁灯  黄启帅  陈生生  龚小晗  吴钪  杨可 《岩石矿物学杂志》2020,39(1):18-34

班公湖-怒江洋的关闭时间直接制约青藏高原早期构造演化的认识。最近,在班公湖-怒江缝合带南侧凯蒙蛇绿混杂岩中发现一碱性火山岩,岩性主要是橄榄粗安岩,具粗面结构,斑晶主要是更长石和少量普通辉石,基质主要由更长石、普通辉石和少量填隙的碱性长石组成,有的具辉绿结构。岩石化学成分较一致,Si O2含量介于51.34%~53.91%之间,Ti O2含量为1.02%~1.55%,具有高Al2O3(17.06%~18.46%)和Na2O(4.90%~6.36%)、低K2O(0.05%~0.88%)含量特点,大多数Mg#大于60,最高68.62,里特曼指数(σ)介于3.65~4.47之间,为碱性系列火山岩;富集Sr、Rb、Ba等大离子亲石元素,亏损Nb、Y、Yb等高场强元素,相对富集Zr、Ti,Nb/U、Zr/Nb、La/Yb等比值稳定,分别为7.45~8.51、15.92~17.26和7.26~8.06;(87Sr/86Sr)i值变化范围较小,介于0.706~0.707之间,(143Nd/144Nd)t值在0.512 368~0.512 548之间,说明源区较为一致,结合Ce/Pb-Si O2图解判断结果,认为凯蒙碱性火山岩具有原始地幔、陆壳和深海沉积物源区混合特征。锆石U-Pb同位素定年结果表明该火山岩年龄为101.8±1.1 Ma,可能形成于洋壳俯冲阶段末期,由大陆边缘陆壳与俯冲洋壳板片断离导致软流圈地幔上涌诱发部分熔融所致,推测班公湖-怒江洋大约在早白垩世晚期关闭。  相似文献   

Revisiting the tectonic setting of the Carboniferous volcanic rocks in the Chinese Tianshan and its neighboring areas     

《Gondwana Research》2020

The Carboniferous–Early Permian rift-related volcanic successions, covering large areas in the Chinese Tianshan and its adjacent areas, make up an important phanerozoic large igneous province in the word, which can be further divided into two sub-provinces: Tianshan and Tarim. The Early Permian volcanic rocks have been considered to be the products of an intraplate volcanism by most researchers. However, there is still strong controversy about the nature and geological setting of the Carboniferous volcanic rocks. The regional angular unconformity of Lower Carboniferous upon basement or pre-Carboniferous rocks, the ages (360–351 Ma) of the youngest ophiolite and the peak of subduction metamorphism of high pressure-low temperature metamorphic belt and the occurrence of Ni-Cu-bearing mafic-ultramafic intrusion with age of ~352 Ma and A-type granite with age of ~358 Ma reveal that the final closure of the Paleo-Asian Ocean might take place in the Early Mississippian. Our studies reveal that although contamination by continental crust or lithosphere can impart subduction-like signature (e.g., low Nb, low Ta and low Ti) and lead to misidentification of contaminated Carboniferous basaltic lavas from the Chinese Tianshan and its neighboring areas as arc related, there are still some essential differences between the Carboniferous basaltic lavas and arc related ones; such as: uncontaminated Carboniferous basaltic lavas have higher Nb concentrations (9–22 ppm), Nb/La > 1, “hump-shaped” OIB-like trace element patterns and moderate positive ɛ_Nd values that distinguish them from the arc related ones; whereas, the contaminated Carboniferous basaltic lavas are characterized by pronounced negative Nb, Ta and Ti anomalies, but, their concentrations of incompatible trace elements are conspicuously higher than those of subduction-zone basalts that also distinguishes them from the arc related ones. Our summation suggests that the Carboniferous volcanic successions did indeed erupt in an intracontinental rift setting and their generation is likely confined to mantle plume.  相似文献   

Lithium isotopic evidence for subduction of the Indian lower crust beneath southern Tibet     

《Gondwana Research》2020

Post-collisional K-rich volcanic rocks (KVRs) can provide an opportunity to constrain the architecture of the lithosphere and the mechanisms of plateau uplift. However, their petrogenesis and geodynamic setting remain in dispute. Lithium concentrations and isotopic compositions of 87 potassic, ultrapotassic and Mg-rich potassic volcanic rocks (PVRs, UPVs, and MPRs, respectively) in SW Tibet, along with new Pb–Sr–Nd isotope data and whole-rock analyses, are used to constrain their mantle source and genesis. These rocks are characterized by very similar δ⁷Li values: PVRs vary from −4.9‰ to +3.2‰, UPVs from −3.9‰ to +1.7‰, and MPRs from −1.2‰ to +3.5‰. They can be classified into two groups: Group I (19 out of 87 samples) with heavier δ⁷Li values (+1.0‰ to +3.5‰) similar to those reported for mid-ocean-ridge and ocean-island basalts (MORBs and OIBs, respectively), and Group II (68 out of 87 samples) with lighter values (−4.9‰ to +1.0‰) similar to those of Indian lower crust. These variable isotopic compositions may record the isotopic signature of the early-middle Miocene subcontinental lithospheric mantle (SCLM). This paper demonstrates the existence of isotopically light mantle domains beneath the Lhasa terrane, which were ascribed to the interaction with fluids/melts derived from the subducted Indian lower crust. The modeling curves of Indian lower crust with a metasomatized mantle composition fully account for compositional variations in the PVRs, UPVs, and MPRs. They were generated by the partial melting of SCLM, which was metasomatized by fluids/melts derived from the subducted Indian lower crust (ca. 4–14%, ca. 4–10%, and ca. 6–10% for the PVRs, UPVs, and MPRs, respectively). The Li isotopic data indicate that the Indian lower crust was subducted beneath the central Lhasa subterrane, and this sheds new light on the formation of the Tibet Plateau.  相似文献   

基于GPS应变、地震应变率与震源应力场对帕米尔高原现今构造变形特征的分析          下载免费PDF全文

潘正洋  邵志刚  周云  王洵  解孟雨  艾萨·伊斯马伊力 《地球物理学报》2020,63(3):1143-1154

研究帕米尔高原的构造变形特征对于理解印度板块向北推挤过程中的应变分配方式以及应力转换模式具有重要的意义.本文利用区域GPS应变场、地震应变场与震源应力场分析帕米尔高原的构造形变特征.主要结论为:(1)该区域变形主要以NNW-SSE或近N-S向的挤压为主,在高原内部伴有明显的近ENE-WSW或E-W向拉张,应力方向在帕米尔高原与塔吉克盆地区域呈现逆时针旋转的趋势,而在塔里木盆地则显示几乎与帕米尔高原的一致的应力状态,这可能与两侧盆地块体的强度差异有关.(2)安德森断层参数A∅显示帕米尔高原北缘与西侧区域为逆断层应力状态,在高原内部为正断层应力状态,这与GPS应变的结果显示的应变主要集中在主帕米尔断裂与阿莱谷地附近而在高原内部应变较低是一致的,另外应力在喀喇昆仑断裂北段的方向基本平行于断层走向,以及断层北端较低的滑动速率,这说明了地壳挤压缩短可能是帕米尔高原主要的的构造变形特征,并不支持由于边界走滑断裂导致的应变分异或者块体挤出的模式.(3)综合考虑地震应变方向与SHmax从帕米尔北部NNW-SSE方向到天山北部的近N-S方向的转换,GPS应变方向在帕米尔高原两侧盆地都存在不同程度的旋转,应力场安德森参数A∅显示的应力状态以及SKS的结果显示的近ENE-WSW方向,我们认为印度板块向北推挤与天山造山带碰撞导致帕米尔高原不对称的径向逆冲是帕米尔高原现今构造变形的主要成因与构造模式.  相似文献   

Spatiotemporal changes of epidemics and their relationship with human living environments in China over the past 2200 years     

Gong  Shengsheng  Xie  Haichao  Chen  Fahu 《中国科学:地球科学(英文版)》2020,63(8):1223-1226

正Epidemics are biological disasters resulting from the widespread occurrence of acute and severe infectious diseases that are normally caused by viruses, bacteria and parasites.They are amongst the most destructive of all natural disasters suffered by humans (Gong, 2019). The pathogens that cause epidemics have always existed in nature, understanding the spatiotemporal distribution of past epidemics is important for preventing and controlling future epidemics.  相似文献   

西藏玛旁雍错和拉昂错水深、水质特征及现代沉积速率   总被引：4，自引：2，他引：2  

王君波  彭萍  马庆峰  朱立平 《湖泊科学》2013,25(4):609-616

基于2009年和2010年分别在玛旁雍错和拉昂错开展的2次野外湖泊调查,本文简要报道这2个藏南内流水系湖泊的水深分布、湖水理化特征及湖泊现代沉积速率.测深结果显示玛旁雍错湖盆形状规则,深水区坡度平缓,最大水深为72.6 m;拉昂错北部为较浅的河流冲积扇,通过狭长的水道与开阔的南部湖区相连,南部湖区中心平坦,实测最深处49.03 m;根据水深数据计算的玛旁雍错和拉昂错水量分别为1.462×10¹⁰m³和5.711×10⁹m³.玛旁雍错湖水剖面水质在垂直方向上呈现明显的分层结构,温跃层介于25~35 m之间,温度梯度为0.17℃/m,水体pH、电导率和溶解氧在温跃层具有同步变化特征;拉昂错湖水温跃层与玛旁雍错相比不明显,5~15 m间温度梯度为0.16℃/m,湖水pH与溶解氧呈反相变化,这可能与水生植物呼吸作用有关.2个湖泊湖水的主要离子组成特征除Ca²⁺外基本相同,拉昂错主要离子浓度约为玛旁雍错的3倍,而Ca²⁺则约为玛旁雍错的1/2;利用²¹⁰Pb和¹³⁷Cs方法对玛旁雍错和拉昂错的短岩芯进行了测试,结果表明2个湖泊近代沉积速率分别约为0.31 mm/a和0.65 mm/a.  相似文献   

湖泊流域生态系统演化对人类世研究的重要意义     

王荣  张科  刘建宝  董旭辉  羊向东 《湖泊科学》2024,36(2):333-338

人类世可能成为一个全新的地质时期,以描述人类活动对地球环境造成极为深远的影响,目前已被广泛讨论。湖泊及流域生态系统作为与人类社会最密切的地球单元之一,受到人类活动显著影响,相关研究成果能为理解人类世做出贡献。本文从湖泊流域生态系统和人类世本身特征为切入点,讨论了湖泊及流域生态系统演化对人类世研究的重要意义。我们认为,湖泊具有相对独立的整体,清晰的内部作用关系、完备的理论支持和时空数据支撑,能够为人类世地球各圈层交互作用提供研究框架。湖泊流域生态系统演化的稳态转换与地球环境进入新的地质时期具有诸多相似之处,相关研究成果能够更好地界定人类世开始时间、总体特征以及演变过程和机制。本文指出人类世湖泊及流域生态系统演化研究依然面临诸多挑战,并提出了对未来相关研究的展望。  相似文献   

The youngest eclogite in central Himalaya: P–T path,U–Pb zircon age and its tectonic implication     

《Gondwana Research》2017

Relict omphacite inclusions have been discovered in mafic granulite at Dinggye of China, confirming the existence of eclogite in central Himalayan orogenic belt. Detailed petrological studies show that relict omphacite occur as inclusions in both garnets and zircons, and the peak mineral assemblage of eclogite-facies should be garnet, omphacite, rutile, muscovite and quartz which was strongly overprinted by granulite-facies minerals during the exhumation. Phase equilibria modeling and associated geothermometer predict that the minimum P–T conditions for peak eclogite-facies stage are 720–760 °C and 20–21 kbar, and those of overprinted granulite-facies are 750 °C and 7–9 kbar in water-undersaturated condition. Thus, a near isothermal decompression P–T path for central Himalayan eclogite has been obtained. Zircon SHRIMP U–Pb dating of two studied eclogite samples at Dinggye yields the peak metamorphic ages of 13.9 ± 1.2 Ma and 14.9 ± 0.7 Ma, respectively, which indicates that the Dinggye eclogite should be the youngest eclogite in Himalayan orogenic belt. Geochemical characteristics and zircon analyses show that the protoliths of eclogite in Dinggye are predicted to be continental rift-related basaltic rocks. The eclogite at Dinggye in central Himalaya should be formed by the crustal thickening during the long-lasting continental overthrusting by Indian plate beneath Euro-Asian continent, and its exhumation process may be related with channel flow and orogen-parallel extension. In the middle Miocene (~ 14 Ma), Indian continental crust had reached at least ~ 65 km depth in southern Tibet.  相似文献