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981.
In this paper, the authors present the results of both macroscopic and microscopic investigations on structure development created by repeated ice lensing in various loamy experiments. Experimental data are compared with observations performed on active forms in High Arctic and Alpine Mountain environments. Those observations are also compared with phenomena observed in fossil periglacial formations of Western Europe. Platy and short prismatic structure formation is bonded to the hydraulic and thermal conditions during ice segregation. When a long series of alternating freezing and thawing affects platy structures, the fabric evolves, also being influenced by slope and drainage conditions: cryoturbations, frostcreep, and gelifluction can appear. They are characterized by specific microfabrics which are better developed with an increasing number of cycles: this is clear in experiments where hydraulic and thermal parameters are better controlled. Vesicles are also a prominent characteristic of the surface horizon in experiments and arctic soils. The genesis of vesicles is discussed on the basis of new observations and is related to the mechanical collapse of frost-created aggregates under the mechanical work of soil air escape during soil saturation by water at thaw. 相似文献
982.
983.
Allen M. Solomon 《地球表面变化过程与地形》1986,11(6):681-685
Taxon calibrations based on eastern North America or on the southeastern United States alone suggest a different forest composition from that based on Wisconsin/Michigan, which is argued as preferable. Questions are raised about how well comparison with modern analogues distinguishes forest characteristics. The simulation model used by Delcourt and Delcourt is thought to be inappropriate, partly because it is constrained by faulty climatic data. Models are seen as complementary to other techniques rather than as an alternative methodology. 相似文献
984.
Stratigraphic and chemical data from the ice core of an ‘anthropogenic palsa’ at Toolik Lake, Alaska, indicate that the mound formed as a consequence of hydrostatic pressure developed in an isolated hydrologic system within the active layer. Survey data for five palsas over a three-year period suggest that growth was essentially complete at the time of the initial survey; a net decrease of summit elevation is apparent in all five mounds, but complete degradation of the palsas would require several decades at observed rates. Because accurate field measurements of thermal and hydrologic evolution in such features are extremely difficult, simulation of the environmental conditions and events involved in palsa growth is an important supplement to field observation. Both analytic and finite-element models yield results that are in substantial agreement with inferences drawn from observational data. 相似文献
985.
Immature Torbanite and the resistant biopolymer (PRB A) isolated from extant B. braunii were previously compared using bulk spectroscopic methods. In the present work, analysis of 400°C pyrolysis products and pyrolysis residues provided further information on their structure and possible relationships. It appears that such polymers are based upon unbranched, saturated, cross-linked hydrocarbon chains up to C31. In addition to these bridging structures, a substantial part of the alkyl chains is singly bound, as esters of unbranched, saturated or cis unsaturated, even fatty acids. These esters are sterically protected, against chemical degradations, by the network of the bioand geopolymer.Quantitative and qualitative observations derived from 400°C pyrolysis confirm that the chemical structure of PRB A and immature Torbanite are closely related. The pyrolysis residues show a similar evolution and numerous common features are noted, with respect to the nature and the distribution of the major constituents of the pyrolysates (hydrocarbons and fatty acids). Accordingly, Botryococcus provides what seems to be the first example of a close structural relationship between a biopolymer produced in large amounts by an extant alga and the geopolymer of an immature kerogen. The essential role of PRB A in Torbanite formation is ascertained. Moreover, it is found that the resistant biopolymer does not undergo important structural changes during the first stages of diagenesis. Thus, owing to steric protection, the esters of immature Torbanite show a distribution quite close to the one of PRB A esters, with exclusively even constituents and a large contribution of unsaturated acids.Recent observations pointed to the possible genesis of some algal kerogens principally by selective preservation of resistant macromolecules. Such a type of formation is clearly predominant in Torbanite, where the bulk of the fossil organic matter corresponds to a selectively preserved and weakly altered, resistant biopolymer, while incorporation of lipids into the kerogen structure during diagenesis seems to play a minor role. 相似文献
986.
Peng Wang Lei Liu Xichuan Liu Shuai Hu Shijun Zhao Wenming Ji Taichang Gao 《地球科学进展》1986,35(7):704-714
The accurate observation of the microphysical structure of cloud and precipitation plays an important role in understanding the formation of clouds and precipitation. In-situ measurement using measuring instruments carried by meteorological balloons is an effective way to obtain the microphysical properties of cloud and precipitation particles, which is a supplementary means for aircraft to observe cloud and precipitation particles. This observation method plays a more and more important role in in-situ measurement. According to the difference of the working principle of the existing balloon-borne cloud and precipitation particles probes, the detectors can be divided into particle impact-sampling sensors, particle imaging sensors, light-scattering sensors, light intensity attenuation sensors and charge measurement sensors. The working principles, key technologies and main advantages and disadvantages of typical instruments were summarized, and their applications to detailed cloud structure acquisition, cloud remote sensing method establishment, cloud and precipitation physical process research and parameterization, and scientific observation of thunderstorm clouds were briefly introduced. Finally, the development trend of balloon-borne cloud precipitation particle detectors was prospected, which will provide reference for related technical research and equipment development. 相似文献
987.
988.
The sensitive and selective determination of polyalcohols without chromophores or fluorophores in the lower ppb-level is still an analytical task of high interest, especially in the field of environmental investigations. This paper describes a cation-exchange HPLC procedure for the separation and fluorescence detection of two quaternary ammonium compounds with polyalcoholic groups (degradation products of fabric softener) after derivatization with 9-fluorenylmethyl chloroformate (FMOC). Detailed experiments were carried out to determine optimum reaction conditions (pH, reaction time, temperature), linear range, detection limits, and kinetics of the reaction. The HPLC separation on a cation-exchange column includes a gradient program which provides complete separation from neutral compounds also reacting with FMOC and its hydrolysis products formed during the reaction in alkaline medium. High specificity for both investigated ammonium compounds with detection limits in the range of 1 ppb could be achieved. 相似文献
989.
Products and mechanisms for the gas-phase reactions of NO3 radicals with CH2=CHCl, CH2=CCl2, CHCl=CCl2,cis-CHCl=CHCl andtrans-CHCl=CHCl in air have been studied. The experiments were carried out at 295±2 K and 740±5 Torr in a 480-L Teflon-coated reaction chamber and at 295±2 K and 760±5 Torr in a 250-L stainless steel reactor. NO3 was generated by the thermal dissociation of N2O5. Experiments with15NO3 and CD2CDCl have also been performed. The initially formed nitrate peroxynitrates decay into carbonyl compounds, nitrates, HCl and ClNO2. In adidtion, there are indications of nitrooxy acid chlorides being produced. The reactions with CH2=CCl2 and CHCl=CCl2 are more complex due to release of chlorine atoms which eventually lead to formation of chloroacid chlorides.A general reaction mechanism is proposed and the observed concentration-time profiles of reactants and products are simulated for each compound. The rate constants for the initial step of NO3 addition to the chloroethenes are determined as: (2.6±0.5, 9.4±0.9, 2.0±0.4 and 1.4±0.4) × 10–16 cm3 molecule–1 s–1 for CH2=CHCl, CH2=CCl2, CHCl=CCl2 andcis-CHCl=CHCl, respectively. 相似文献
990.
The use of cloud tracking techniques and storm identification procedures is proposed in this paper with the aim of predicting the evolution of cloud entities associated with the highest rainfall probability within a given meteorological scenario. Suitable algorithms for this kind of analysis are based on the processing of digital images in the thermal infrared (IR) band from geostationary satellites: a selection of such algorithms is described in some detail together with a few real case applications. Three heavy rainfall events have been selected for this purpose with reference to the extreme meteorological situation observed during Fall 1992 and 1993 over the Mediterranean area. A window from 30 to 60 °N and from 20 °W to 30 °E has been identified for the analysis of data from the radiometer on board the ESA Meteosat platform. In conclusion, the suitability of cloud tracking techniques for predicting the probability of heavy rainfall events is discussed provided that the former are associated with proper modeling of small scale rainfall distribution. 相似文献