Source identification of PM_2.5 particles measured in Gwangju, Korea   总被引：1，自引：0，他引：1  

Hanlim Lee  Seung S. Park  Kyung W. Kim  Young J. Kim   《Atmospheric Research》2008,88(3-4):199-211

The UNMIX and Chemical Mass Balance (CMB) receptor models were used to investigate sources of PM_2.5 aerosols measured between March 2001 and February 2002 in Gwangju, Korea. Measurements of PM_2.5 particles were used for the analysis of carbonaceous species (organic (OC) and elemental carbon (EC)) using the thermal manganese dioxide oxidation (TMO) method, the investigation of seven ionic species using ion chromatography (IC), and the analysis of twenty-four metal species using Inductively Coupled Plasma (ICP)-Atomic Emission Spectrometry (AES)/ICP-Mass Spectrometry (MS). According to annual average PM_2.5 source apportionment results obtained from CMB calculations, diesel vehicle exhaust was the major contributor, accounting for 33.4% of the measured PM_2.5 mass (21.5 μg m^− 3), followed by secondary sulfate (14.6%), meat cooking (11.7%), secondary organic carbon (8.9%), secondary nitrate (7.6%), urban dust (5.5%), Asian dust (4.4%), biomass burning (2.8%), sea salt (2.7%), residual oil combustion (2.6%), gasoline vehicle exhaust (1.9%), automobile lead (0.5%), and components of unknown sources (3.4%). Seven PM_2.5 sources including diesel vehicles (29.6%), secondary sulfate (17.4%), biomass burning (14.7%), secondary nitrate (12.6%), gasoline vehicles (12.4%), secondary organic carbon (5.8%) and Asian dust (1.9%) were identified from the UNMIX analysis. The annual average source apportionment results from the two models are compared and the reasons for differences are qualitatively discussed for better understanding of PM_2.5 sources.Additionally, the impact of air mass pathways on the PM_2.5 mass was evaluated using air mass trajectories calculated with the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) backward trajectory model. Source contributions to PM_2.5 collected during the four air mass patterns and two event periods were calculated with the CMB model and analyzed. Results of source apportionment revealed that the contribution of diesel traffic exhaust (47.0%) in stagnant conditions (S) was much higher than the average contribution of diesel vehicle exhaust (33.4%) during the sampling period. During Asian dust (AD) periods when the air mass passed over the Korean peninsula, Asian dust and secondary organic carbon accounted for 25.2 and 23.0% of the PM_2.5 mass, respectively, whereas Asian dust contributed only 10.8% to the PM_2.5 mass during the AD event when the air mass passed over the Yellow Sea. The contribution of biomass burning to the PM_2.5 mass during the biomass burning (BB) event equaled 63.8%.  相似文献   

Satellite and ground observations for large-scale air pollution transport in the Yellow Sea region     

Hak-Sung Kim  Yong-Seung Chung 《Journal of Atmospheric Chemistry》2008,60(2):103-116

Large-scale air pollution transport (LSAPT) in the Yellow Sea region and their inflow onto the Korean Peninsula were observed through satellite images and ground measurements. LSAPT includes regional continental air-masses saturated with pollutants originating from China and subsequently landing on or passing through the Korean Peninsula. It is also possible to identify the distribution and transport patterns of LSAPT over the Yellow Sea. The ground concentrations for PM10, PM2.5 and CO measured at Cheongwon, located in the centre of south Korea, were compared with NOAA satellite images. Notably, the episodes observed of the LSAPT show a PM2.5 to PM10 ratio of 74% of the daily maximum concentrations. However, cases of duststorms were clearly distinguished by much higher PM10 concentrations and a ratio of 30% of PM2.5 to PM10 for daily maximum concentrations. For the episode on January 27, 2006, the inflow of a regionally polluted continental air-mass into the central and southwestern regions of the Korean Peninsula was observed sequentially at various ground observatories as well as by satellite. The north airflow dissipated the clouds over Mt. Halla on Jeju Island and further downwind, reducing air pollution and creating a von Kármán vortex.  相似文献   

北京城区夏季污染建立、维持、消退的天气过程     

赵文灿  胡开明  黄刚  陈元昭 《气候与环境研究》2016,21(4):479-489

利用北京城区污染观测站2006~2013年夏季可吸入颗粒物PM10逐日浓度检测资料,挑选所有PM10浓度大于150μg/m~3的个例,合成分析华北及北京地区风场变化情况,发现风速在污染当天变化不明显,南风与PM10的相关性普遍为正,污染当天各区南风增加较大,太行山一带甚至增长了5倍。南风异常可能会使河北、山东等地污染物向北京输送,造成北京大气污染。同时我们分析北京夏季空气污染时大气环流特征。在500 h Pa与200 h Pa,北京和内蒙古上空有显著的高压异常。在850 h Pa,环流场表现为东正西负的高度场异常,其中北京在正负异常分界线上。低层气压梯度异常会造成北京和以南地区南风异常。同时,我们发现北京污染天气伴随的高空环流异常具有准定常特征。在污染前4天,蒙古上空存在一个显著的高层高压异常。该高压异常增强并向南延伸,在污染当天控制北京和内蒙古。在污染消退期,该异常也逐渐消退。但在消退后第四天,北京和内蒙古上空依然受高压异常控制。这表明北京夏季污染和高空准定常环流异常有关。  相似文献   

京津冀地区霾成因机制研究进展与展望   总被引：9，自引：3，他引：6  

缪育聪  郑亦佳  王姝  刘树华 《气候与环境研究》2015,20(3):356-368

为满足当前对京津冀地区霾研究和控制的迫切要求,本文梳理了近年来京津冀地区霾的长期变化特征、天气学特征、污染物来源等相关研究成果,发现:从2000年以后,京津冀地区的霾日数呈现出了下降趋势;北京细颗粒物(PM2.5)质量浓度也在总体上呈现下降的趋势,但2013年年均质量浓度仍高达89.5μg m–3,约为我国空气质量标准的3倍(35μg m–3),京津冀空气污染的形势依然严峻;近年来京津冀地区的霾污染事件频发可以归因为不利天气条件与大量污染物人为排放的共同作用;大量的研究表明,区域输送对京津冀地区霾事件的形成和维持有不可忽视的影响;京津冀地区的大气污染不再局限于一时一地,针对重污染天气的预警以及应急控制应该以区域预报为基础实现区域联动;京津冀地区独特的地理环境条件加上城市群的快速发展,形成的局地大气环流也会对局地的污染过程产生重大的影响;大气边界层内气象要素的变化对重污染发生具有显著贡献。京津冀地区的污染控制需要城市群的联动应对治理。  相似文献   

沈阳冬夏季可吸入颗粒物浓度及尺度谱分布特征   总被引：15，自引：0，他引：15       下载免费PDF全文

严文莲  周德平  王扬峰  杨军  李子华 《应用气象学报》2008,19(4):435-443

利用沈阳大气成分监测站颗粒物监测仪 (Grimm 180) 连续测得的夏季 (2006年8月)、冬季 (2006年12月和2007年1月) 可吸入颗粒物的数浓度和质量浓度数据, 分析了沈阳市可吸入颗粒物浓度日变化、谱分布及污染特征, 在此基础上结合沈阳市常规气象资料, 分析了气象要素和颗粒物污染之间的关系。结果表明:沈阳市冬、夏季部分时段可吸入颗粒物浓度存在明显的日变化和日际变化; 谱分布较好地符合Junge分布; 沈阳冬季PM₁₀超标日数占冬季观测总天数的77%, PM_2.5超标日数 (按美国EPA日均标准) 占冬季观测总天数的87%, PM₁₀平均数浓度为6668.7个/cm3, 平均质量浓度达252.8μg/m3, 分别是夏季的3.0和2.4倍; 冬、夏季PM_2.5/PM₁₀平均质量分数分别为0.647和0.603, PM_2.5占可吸入颗粒物总数量的99%以上; 浓度变化在很大程度上受到各种气象要素的影响, 与温度、风速负相关, 与湿度正相关, 降雨、降雪过程使得颗粒物浓度明显降低, 近地层逆温和雾是颗粒物增多的一个重要因素。颗粒物污染对城市能见度影响较大。  相似文献   

An Observational Study of Black Carbon Aerosol in Northwest China in the Spring of 2006     

GAO Run-xiang  NIU Sheng-jie  ZHANG Hua  XIN Jin-yuan  GUO Jun  XU Mei 《南京气象学院学报》2008,31(5)

  相似文献   

南京市PM2.5物理化学特性及来源解析   总被引：7，自引：0，他引：7  

黄辉军  刘红年  蒋维楣  黄世鸿  张予燕 《气候与环境研究》2006,11(6):713-722

在夏、冬两季,分别在南京市4个站点进行为期7天的气溶胶PM2.5采样,同步采集并分离主要排放源的PM2.5样品,用X射线荧光光谱仪(XRF)分析得到气样及源样中PM2.5的化学成分,对南京市PM2.5的物理化学特性、富集因子进行了分析,并应用化学质量平衡法(CMB)计算各类源对气溶胶PM2.5的贡献。结果表明,南京市PM2.5的夏、冬平均值分别为69.1、139.5μg.m-3,PM2.5/PM10的全年平均值为63.9%;富集成分中,S、As、Zn、Pb等主要来源于人为污染源,Na则主要来源于海洋。来源解析的结果表明,各类污染源对南京市气溶胶PM2.5的贡献率分别为:扬尘37.28%、煤烟尘30.34%、硫酸盐9.87%、建筑尘7.95%、汽车尘2.98%、冶炼尘2.57%、其他源9.01%。作者还对扬尘中的PM2.5进行了来源解析。  相似文献   

MERSI和MODIS卫星监测京津冀及周边地区PM_2.5浓度   总被引：1，自引：0，他引：1  

陈辉  厉青  王中挺  孙云  毛慧琴  程斌 《遥感学报》2018,22(5):822-832

京津冀及周边地区是中国PM_(2.5)污染最重的区域之一,利用卫星遥感技术监测大范围的PM_(2.5)时空分布变化是一种先进的重要手段。本研究首先基于暗像元算法利用FY-3B/MERSI与AQUA/MODIS对京津冀及周边区域进行了遥感AOT反演和验证分析;然后,引入气象资料和地面观测资料利用GWR模型反演了区域PM_(2.5)浓度,并对遥感反演结果进行了交叉验证评估,综合对比分析了MERSI和MODIS的气溶胶及PM_(2.5)遥感监测能力;最后,利用MERSI数据对2017年第一季度京津冀及周边区域的PM_(2.5)月均浓度时空分布变化情况进行了初步探索分析。结果表明:FY-3B/MERSI在气溶胶及PM_(2.5)遥感监测能力方面略优于AQUA/MODIS,MERSI反演的1 km分辨率AOT和PM_(2.5)与地面站点实测结果的决定系数R2分别为0.76μg/m~3和0.79μg/m~3,均方根误差分别为0.26μg/m~3和28μg/m~3,平均绝对误差分别为0.16μg/m~3和15μg/m~3,能基本满足对京津冀及周边区域PM_(2.5)的精细化监测需要。2017年第一季度京津冀及周边区域PM_(2.5)月均浓度遥感监测结果表明该区域的PM_(2.5)空间分布格局与地形地貌关系密切,高值区整体上沿太行山脉成带成片;从时间变化来看,1—3月呈逐月下降的趋势,其中3月份PM_(2.5)区域浓度较1月和2月有大幅下降。这说明FY-3\MERSI遥感反演产品能为环境质量监测和环境管理工作效果评估提供有效参考,本研究对国产卫星在大气环境遥感业务中的大力发展应用有重要参考意义。  相似文献   

The cumulative characteristics of PAEs in PM2.5 in Changji,Northwest China     

Yuyan Liu  Caiye Ji  Bo Fu  Yongxin Yu  Haofeng Liu  Yaxing Shen 《自然地理学》2020,41(4):332-342

ABSTRACT

This paper discusses characteristics of the seasonal variation in phthalate acid esters (PAEs) in the PM_2.5 in the city of Changji, which is located an arid area of Xinjiang Province, northwest China. Samples were collected using a Laoying 2030 median discharge intelligent total suspended particulate (TSP) sampler and analyzed by a Shimadzu GC-2010 gas chromatograph. The results showed that PAEs in PM_2.5 were mainly composed of phthalic acid dibutyl phthalate (DBP) and phthalic acid (2-)ethyl hexyl ester (DEHP). DBP and DEHP are the most commonly used plasticizers, accounting for the majority of plasticizers used, and have large environmental emissions. Compared with the proportions of TSPs, proportions of DBP and DEHP in the PM_2.5 were lower, while the proportions of DMP and DEP were higher. A correlation exists between the distribution of PAEs and the particle size and concentration of atmospheric particulates. Seasonal variations in DBP and DEHP were the same, with lowest concentrations in the summer. Although seasonal variation in DMP was not the same as those of DBP and DEHP, the general trend was similar. Seasonal variation in DEP was different from those of other PAEs. This pattern is related to PAE characteristics and seasonal variations in their sources.  相似文献   

中国高耗能产品生产与区域PM2.5浓度的动态关联效应——基于省级尺度的分析     

金凤君  林美含  张晓平  李润奎 《地理研究》2021,40(8):2141-2155

面向经济高质量发展及实现“双碳”战略目标,中国传统能源密集型产业发展的资源环境效应备受学界关注。基于2000—2017年中国31个省（直辖市、自治区）的面板数据,通过构建面板向量自回归模型（PVAR）,结合脉冲响应分析和方差分解及动态系统GMM模型,探究中国火电、水泥、钢铁、焦炭等典型高耗能产品的生产规模与区域PM_2.5污染的动态关联效应。结果表明：① 短期内,省域PM_2.5浓度具有明显的时间惯性,火电、水泥、钢铁、焦炭产业规模的短期波动对其冲击影响有限;② 动态影响显示,区域钢铁生产规模对PM_2.5浓度的影响程度最大,火电、焦炭行业次之;③ 长期影响结果显示,钢铁、焦炭产业的扩张加剧了PM_2.5污染,而火电、水泥产品生产规模未与PM_2.5污染表现出同步特征;④ 区域PM_2.5污染成因具有复合性,研究期内控制变量如地区经济规模、工业化程度、城镇化率的提高加剧了PM_2.5污染,地方政府环境污染治理力度越弱则PM_2.5污染程度越重。中国在高耗能产品生产规模逐年增加的情况下,有效地控制了区域PM_2.5污染的加剧。未来应进一步提高行业标准,通过技术创新和产业结构升级控制污染物排放强度;增强地方政府对环境污染的治理力度;研究能源原材料产业的适度产能规模,在满足中国新型基础设施、新型城镇化等重大工程建设对基础原材料产业需求的同时,实现环境质量的优化。  相似文献