A comparative study of the hopanoid hydrocarbons in sediments of two lakes (Fuxian and Changdang) with contrasting environments     

《Limnologica》2019

Biologically configured ββ-hopanes, geologically configured αβ-hopanes and the biogenic hopenes were determined in dated sediment cores from Lake Fuxian in SW China and Lake Changdang in Eastern China in order to investigate anthropogenic influences on the abundance, composition and provenance of hopanoid hydrocarbons in lake sediments. Based on the results, hopenes were prevalent, with maximum values reaching 148.9 μg g⁻¹ TOC in sediments of Lake Fuxian, an oligotrophic deep lake (average depth 89.6 m), where the long water column provided ample potential for the growth of hopene-producing bacteria especially the cyanobacteria. Sediment hopenes have diminished in abundance to values of 13.4–78.5 μg g⁻¹ TOC in Lake Changdang, a eutrophic shallow (average 0.8–1.2 m) body, reflecting comparatively reduced importance of nutrient level on hopene production. Historical trends in hopenes input to the sediments of each lake are strongly dependent on nutrient status. During the last few decades, human-induced eutrophication has greatly boosted bacterial production, enhancing the accumulation of hopenes in sediments. Inputs of petroleum-derived αβ-hopanes were exceptionally high (average 71.2 μg g⁻¹ TOC) in post-1968 sediments from Lake Changdang, their increase coinciding with the advent and acceleration of petroleum product use around the lake, in particular by fishing boats. Lake Fuxian on the other hand, has undergone slower economic development and the appearance of petroleum-derived αβ-hopanes in sediments was delayed to 1990 since when the average value has been 27.1 μg g⁻¹ TOC. The abundance of αβ-hopanes in Lake Changdang has created a marked decrease in the relative contribution of hopenes to total hopanoids since 1968. Conversely, the amounts of αβ-hopanes introduced to Lake Fuxian since 1990 has yet to yield a clear change in the overall proportion of hopenes, but the abundance of ββ-hopanes has declined relative to total hopanoid levels for the period.  相似文献   

Formulation of risk-targeted seismic action for the force-based seismic design of structures     

Jure Žižmond  Matjaž Dolšek 《地震工程与结构动力学》2019,48(12):1406-1428

A risk-targeted design spectral acceleration and the corresponding seismic design action for the force-based design of structures is introduced by means of two formulations. The first one called direct formulation utilizes the seismic hazard function at the site of the structure. Because the seismic action defined in the codes is often associated with a designated return period, an indirect formulation is also introduced. It incorporates a risk-targeted safety factor that can be used to define a risk-targeted reduction factor. It is shown that the proposed formulations give analogical results and provide an insight into the concept of the reduction of seismic forces for the force-based seismic design of structures if the objective is defined by a target collapse risk. The introduced closed-form solution for the risk-targeted reduction factor can be used to investigate how the target collapse risk, the seismic hazard parameters, the randomness of the seismic action, and the conventional parameters (ie, the overstrength factor and the deformation and energy dissipation capacity) affect the seismic design forces in the case of force-based design. However, collaborative research is needed in order to develop appropriate models of these parameters. In the second part of the paper, the proposed formulations are demonstrated by estimating the risk-targeted seismic design action for a six-storey reinforced concrete building. By verifying the collapse risk of the designed structure, it is demonstrated that the risk-targeted seismic action, in conjunction with a conventional force-based design, provided structure with acceptable performance when measured in terms of collapse risk.  相似文献   

近场地震下竖向刚度不同的混合结构动力性能分析   总被引：1，自引：0，他引：1       下载免费PDF全文

马肖彤  包超  张立新  徐芳泽  陆华 《地震工程学报》2019,41(4):860-865

近场地震的动力特性明显不同于远场地震,因此有必要对结构在近场地震作用下的动力性能展开研究。以上部钢结构-下部混凝土结构这类竖向刚度不同的加层混合结构为研究对象,对其在近场脉冲型地震、近场无脉冲型地震及远场地震作用下的动力响应进行研究。结果表明:在多遇、设防、罕遇地震作用下,近场脉冲型地震会使结构的层间位移角、层间剪力、加速度等动力响应均放大并出现超限的情况,而且都比罕遇地震作用下结构的响应增大更明显;在进行近场区加层混合框架结构的设计和建设时,近场脉冲效应会使结构存在不满足规范的情况,有必要对竖向刚度不同的加层混合结构在近场区的适用性进行深入研究。  相似文献   

考虑支座滑移及挡块破坏的中小跨径梁桥地震易损性研究     

宋帅  王帅  吴刚 《震灾防御技术》2019,14(4):781-789

从板式橡胶支座及混凝土挡块抗震设计角度,以一座典型的3跨预应力混凝土连续梁桥为例,结合概率地震需求分析及桥墩、支座等抗震关键构件极限破坏状态,建立不同支座及挡块分析模型的中小跨径梁桥地震易损性曲线,研究考虑支座滑移效应及挡块破坏的中小跨径梁桥的易损性特征。研究结果表明:不考虑橡胶支座的滑移效应及混凝土挡块破坏,桥墩地震破坏概率明显增大,且会低估支座破坏概率;桥梁系统易损性受支座破坏状态的影响显著,需设置合理的限位装置;在中小跨径梁桥地震易损性分析中,考虑支座的滑移效应及混凝土挡块的破坏十分必要。  相似文献   

Equilibrium thallium isotope fractionation and its constraint on Earth’s late veneer     

Tong Fang  Yun Liu 《Acta Geochimica》2019,(4):459-471

Equilibrium isotope fractionation of thallium(Tl) includes the traditional mass-dependent isotope fractionation effect and the nuclear volume effect(NVE). The NVE dominates the overall isotope fractionation, especially at high temperatures. Heavy Tl isotopes tend to be enriched in oxidized Tl^3+-bearing species. Our NVE fractionation results of oxidizing Tl^+ to Tl^3+ can explain the positive enrichments observed in ferromanganese sediments. Experimental results indicate that there could be0.2–0.3 e-unit fractionation between sulfides and silicates at 1650 ℃. It is consistent with our calculation results,which are in the range of 0.17–0.38 e-unit. Importantly,Tl’s concentration in the bulk silicate Earth(BSE) can be used to constrain the amount of materials delivered to Earth during the late veneer accretion stage. Because the Tl concentration in BSE is very low and its Tl isotope composition is similar with that of chondrites, suggesting either no Tl isotope fractionation occurred during numerous evaporation events, or the Tl in current BSE was totally delivered by late veneer. If it is the latter, the Tl-contentbased estimation could challenge the magnitude of late veneer which had been constrained by the amount of highly siderophile elements in BSE. Our results show that the lateaccreted mass is at least five-times larger than the previously suggested magnitude, i.e., 0.5 wt% of current Earth’s mass. The slightly lighter 205 Tl composition of BSE relative to chondrites is probable a sign of occurrence of Tlbearing sulfides, which probably were removed from the mantle in the last accretion stage of the Earth.  相似文献   

AN EXPERIMENTAL STUDY ON THE PROCESS OF INTERGRANULAR PRESSURE SOLUTION OF PLAGIOCLASE GOUGE UNDER HIGH TEMPERATURE AND PRESSURE: METHOD AND PRELIMINARY RESULTS          下载免费PDF全文

ZHANG Shu  HE Chang-rong 《地震地质》2019,41(4):1012-1026

To understand the mechanism of lower-crust earthquake and slow slips, it is necessary to study the frictional properties of mafic rocks and their major rock-forming minerals. Previous studies have performed a series of experimental researches on gabbro, basalt and their major constituents. According to the results of previous experiments, frictional sliding of plagioclase under hydrothermal conditions(100~600℃)shows a property of velocity weakening, and the experimental results show that both the direct rate effect parameter(a)and the healing effect parameter(b)increase with temperature, a typical feature for thermally-activated processes. Velocity weakening means property of a shear band that has a stronger friction healing effect than the direct rate effect in the rate and state friction constitutive framework, and the healing effect(b value)in constitutive relation mainly reflects the increase in contact area with time under hydrothermal conditions, with some minor effect of structural changes. Since the microphysical mechanism of feldspar minerals at the contacts is mainly brittle cataclasis for temperatures below 600℃, the significant frictional healing effect in this case can only be explained by the mechanism of pressure solution. In order to determine if the dissolution process of plagioclase actually occurs on the laboratory time scale, we conducted hydrostatic experiments on plagioclase powder samples under hydrothermal conditions whereby frequent contact switch between particles seen in frictional sliding experiments can be avoided, making the observation on the dissolution sites possible. Experimental temperatures were 400℃ and 500℃, with confining pressure of 90~150MPa, pore pressure of 30MPa, with 2mm initial thickness of fault gouge. The mechanical data show that a creep process occurred in the plagioclase fault gouge in the experimental temperature and pressure range; and the microstructures of the experiment show that precipitation of new grains is prevalent as the product of pressure solution process between plagioclase particles. At the same time, it is observed that the contact points have an appearance similar to fused, fuzzy structure as signatures of dissolution. The results of our experiments provide a definite experimental evidence for the healing mechanism in friction of plagioclase and for the theoretical relation between unstable slip and the pressure solution process. The results of the experiments are summarized as follows: (1)Drainage rate of pore water in plagioclase gouge was high in the first few hours of experiment, but gradually decreases over time for both temperature and pressure series of experiments slowing down to a steady state. This feature indicates that there is a creep process that evolves inside the plagioclase gouge. In the temperature-series experiments, the drainage rate of the pore water in the plagioclase gouge at 400℃ is relatively low than the cases for higher temperatures. Thus, the applied temperature is positively correlated with the creep of plagioclase gouge. (2)Scanning electron microscopy(SEM)observations of the experimentally deformed samples were performed on thin sections cut along the sample axis. Firstly, from the images of microstructure, it was found that the degree of particle fracture became more significant at a higher effective pressure, with smaller pore volume between particles. In the temperature-series experiments it was found that the degree of compaction of plagioclase gouge increased with increasing temperature. Precipitation of plagioclase grains in layered structures was generally observed in high-magnification images, indicating the presence of pressure solution processes. Contact points were also found to be in a state of ambiguity that seems to be a fused morphology, but the details of the structure remain to be determined by further observations. The above results indicate that the pressure solution process of plagioclase particles can occur on a typical laboratory time scale, and the results of this study provide robust experimental evidences for the theory that links between pressure solution and the mechanism of frictional healing and unstable slips for plagioclase.  相似文献   

地震减灾工程下格宾石笼拦挡坝支护技术研究     

王金华 《华南地震》2019,39(2):136-141

鉴于格宾石笼护岸、护坡等优质特性,对其应用至地震减灾工程进行研究。经分析可知,格宾石笼主要利用双绞合六边形金属网片组合为箱笼,再装填石料堆筑构成防护整体;格宾石笼具有高强度耐久性、透水性、整体性与柔韧性和施工过程简单便利等特征。依据格宾石笼构造与特性分析,分别将地震减灾工程下格宾石笼拦挡坝施工划分为格宾石笼护基与格宾石笼护坡两部分进行研究。利用测量放线、挖掘基础、规整地基、铺垫反滤层、格宾放置与连接、支顶加固、石料装填封盖等步骤实现格宾石笼护基施工。通过削坡、铺设土工布、砂砾垫层、安装网箱、装填石料和封盖等步骤实现格宾石笼护坡施工。分别在冲击力、位移和能量三方面验证格宾石笼拦挡坝支护技术,实验结果表明,冲击力和坝体自身材料性质有关联,格宾拦挡坝材料属于柔性材料,冲击力由此减小,耗费冲击力能量效果十分明显;坝体可以利用整个结构全部能量承担很大负载;格宾石笼拦挡坝体耗能效果显然优于浆砌石坝。  相似文献   

陕西铜川新区典型滑坡在不同强度地震作用下的稳定性——以铜川玉皇阁水库滑坡为例     

段蕊  楚迪 《华北地震科学》2019,37(4):34-39,47

采用极限平衡法和有限元强度折减法,对地震作用下的陕西铜川新区玉皇阁水库滑坡的稳定性进行计算分析,对比分析2种方法在天然、中震、大震3个工况下的安全系数,结果基本吻合,且随着地震动峰值加速度的增大边坡稳定性逐渐降低,安全系数最大降低幅度可达18%;根据计算结果进行稳定性评价,玉皇阁水库滑坡在大震作用下处于不稳定状态,中震作用下其稳定性也较低。该结果为该滑坡风险评价和防控提供参考,为铜川新区地震地质灾害评价提供基础性参考。  相似文献   

应变率效应对600 MPa级高强钢筋混凝土框架结构抗震性能影响研究          下载免费PDF全文

孙传智  李爱群  缪长青  乔燕  左工 《世界地震工程》2019,35(2):165-170

为了更真实地进行钢筋混凝土结构抗震性能评估,应该考虑材料的应变率效应影响。600 MPa级高强钢筋作为新一代建筑钢材,尚无考虑应变率效应影响的600 MPa级高强钢筋混凝土框架结构抗震性能研究。首先进行了不同应变率下600 MPa级高强钢筋拉伸力学性能试验,利用试验数据拟合得到600 MPa级高强钢筋在不同应变率下的强度提高系数表达式,并利用OpenSees软件进行了配置600 MPa级高强钢筋混凝土框架结构抗震性能模拟分析,研究了应变率效应对框架结构抗震性能的影响。研究结果表明:随着应变率的增大,钢筋的屈服强度和极限强度均得到提高,屈服强度最大提高11.5%,极限强度最大提高8.9%;随着所考虑的材料应变率增加,配置600 MPa级高强钢筋框架结构最大顶点位移总体上呈减小趋势,地震波强度越强,应变率效应影响越大,而层间位移角减小幅值相差不大。研究成果可作为600MPa级高强钢筋混凝土框架结构抗震评估的依据。  相似文献   

Fe3+纳米胶体颗粒的光吸收边蓝移与溶液中Al/Fe比的关系   总被引：4，自引：2，他引：2  

章兴华  孙传敏  周丽芸  陆洋  刘世荣 《矿物学报》2005,25(2):158-164

合成了n（Al）／n（Fe）和碱化度不同的45个聚合氯化铝铁（PAFC）样品,进行了光谱分析,结果显示光吸收边蓝移或红移以及Fe（Ⅲ）羟基氧化物和Al-Fe共聚体纳米胶体颗粒大小分布与溶液的Al／Fe比和碱化度（B=[OH]／[Al＋Fe]）密切相关。电镜观察和电子衍射分析表明：Al（Ⅲ）的加入使Fe（Ⅲ）羟基氧化物和Al-Fe共聚体纳米胶体颗粒变小、有序度降低是造成PAFE光吸收边蓝移和保持胶体颗粒在亚稳定状态下存在的重要原因。当n（Al）／n（Fe）〉8：2后,PAFC溶液中Fe（Ⅲ）羟基氧化物和Al-Fe共聚体胶体主要以〈10m的纳米颗粒形态存在,对应的光谱能级提高到26000cm^-1以上,且各种曰值下Fe^3＋的光谱能级趋于一致。这表明,在大量Al（Ⅲ）存在条件下,PAFE中Fe3^＋的所处的化学环境相似。点能谱分析显示,n（Al）／n（Fe）=4：6的样品中颗粒物的化学计量比最接近AlOOH,FeOOH,溶液的稳定性最差。  相似文献