无机盐超细粉体制备技术的回顾与展望   总被引：3，自引：0，他引：3       下载免费PDF全文

吴健松  李海民 《盐湖研究》2004,12(3):50-54

评述了制备无机盐超细粉体的传统方法以及一些传统方法的改进 ,对当前几种新技术做了介绍与展望  相似文献   

InSAR用于南极测图的可行性研究   总被引：10，自引：1，他引：10  

周春霞  鄂栋臣  廖明生 《武汉大学学报(信息科学版)》2004,29(7):619-623

利用1996年ERS-1／2tandem方式的雷达影像数据进行了生成Grove山数字高程模型的试验研究，并与实测的DEM进行比较分析，论证了利用InSAR技术进行南极测图的可行性。试验证明，在南极研究中，InSAR是一种非常有效的手段，不仅可用于地图制图，而且在冰川动力学、冰貌环境变化等研究领域也有巨大的潜力。  相似文献   

Direct Current Plasma Emission Spectrometric Determination of Major, Minor and Trace Elements in Microwave Oven Acid Leachates of Powdered Whole Coal Samples     

Sandro Fadda 《Geostandards and Geoanalytical Research》2005,29(1):143-156

Major concentrations of Al₂O₃, Fe₂O₃, MgO, CaO, Na₂O and K₂O, minor levels of TiO₂, P₂O₅ and thirty petrologically, geochemically and environmentally significant trace elements have been determined in microwave oven acid leachates of whole powdered coal samples by direct current plasma‐atomic emission spectrometry (DCP‐AES). A single sample preparation procedure was suitable for all the determinations with no additional dilution step for major elements solution. Dried samples (0.5 g) were treated in low‐pressure PFA digestion vessels with HF/HCl/HNO₃/HClO₄ acids to quantitatively extract the analytes from the bulk material, while leaving the major part of organic matrix as a residue. The major constituents of geological samples, in particular the easily ionised elements (EIEs) such as alkali and alkaline earths, may complicate the instrumental determinations in DCP‐AES because of differential enhancements of elemental emission intensities and stray light interferences. Taking account of these factors, the coal matrix is considered to have very low major oxide totals as compared to many other common geo‐environmental and related materials (rocks, sediments, soil, ashes etc.). The sample size employed here, while yielding a relatively concentrated solution to cover a wide range of elemental determinations, provided a sample matrix that significantly diminished interferences for DCP measurements. The need for closely matching the unknowns and calibrators was eliminated except for overall acidity and an excess quantity of caesium for EIE buffering. Calibration of the spectrometer was accomplished by simple aqueous single element solutions as high concentration calibrators in addition to a reagent blank as a low concentration calibrator. Two point working curves were established to allow for the maximum concentrations of each element expected in the unknowns. The precision of determinations under routine conditions as well as the reproducibility of the leaching and precision of instrumental measurements have been evaluated. Relative standard deviations (RSD) were of 1–2% for those elements whose concentrations in solid samples were well above the limits of quantification. Method detection limits in the buffered solutions were also evaluated. To evaluate the accuracy of the microwave oven‐DCP method a suite of eight certified coal reference materials of differing rank, were analysed with good agreement with the certified and/or available published data. Results are presented for the uncertified major oxides in the AR series reference materials.  相似文献   

High-T phase transition of synthetic ANaB(LiMg)CMg5Si8O22(OH)2 amphibole: an X-ray synchrotron powder diffraction and FTIR spectroscopic study     

Gianluca Iezzi  Mario Tribaudino  Giancarlo Della Ventura  Fabrizio Nestola  Fabio Bellatreccia 《Physics and Chemistry of Minerals》2005,32(7):515-523

The synthetic amphibole Na_0.95(Li_0.95Mg_1.05)Mg₅Si₈O₂₂(OH)₂ was studied in situ at high-T, using IR OH-stretching spectroscopy and synchrotron X-ray powder diffraction. At room-T the sample has P2₁ /m symmetry, as shown by the FTIR spectrum. It shows in the OH region two well-defined and intense absorptions at 3,748 and 3,712 cm⁻¹, respectively, and two minor bands at 3,667 and 3,687 cm⁻¹. The main bands are assigned to the two independent O–H groups in the primitive structure. The two minor bands evidencing the presence of small amount of vacant A-site (^A□_0.05). With increasing T, these bands shift continuously and merge into a unique absorption at high temperature. A change as a function of increasing T is revealed by the evolution of the refined unit-cell parameters, whose trend shows a transition to C2/m at about 320–330°C. The spontaneous scalar strain, fitted with a tricritical 2–6 Landau potential, gives a T _c of 325(10)°C (β parameter = 0.27). Comparison with the second-order P2₁ /m ⇔ C2/m phase transition at 255°C for synthetic amphibole ^ANa_0.8^B(Na_0.8Mg_1.2)^CMg₅Si₈O₂₂(OH)₂ indicates that the substitution of Na with Li at the B-sites strongly affects the thermodynamic character and the T _c of the phase transition. The comparison of LNMSH amphiboles with cummingtonitic ones shows that the high-T thermodynamic behaviour is affected by A-site occupancy.  相似文献   

基于散射计风场数据的台风强度诊断方法——以海洋二号卫星数据为例   总被引：2，自引：2，他引：0  

杨典  宋清涛  蒋兴伟  刘宇昕  刘圆 《海洋学报》2019,41(1):151-159

本文提出了一种基于散射计风场数据的台风定强方法。该方法定义了台风所在海区的一个圆形区域上的风速平均值来对台风进行定强，并使用海洋二号卫星散射计历史数据对该方法进行了验证。验证结果表明，该台风定强方法可以克服散射计反演台风风速过低的问题。与台风强度监测的历史记录比较的结果显示，在台风强度低于"强台风"这一强度等级时，该方法能够有效估算台风强度。  相似文献   

Development of a rain‐on‐snow detection algorithm using passive microwave radiometry          下载免费PDF全文

Caroline Dolant  Alexandre Langlois  Benoit Montpetit  Ludovic Brucker  Alexandre Roy  Alain Royer 《水文研究》2016,30(18):3184-3196

Currently observed climate warming in the Arctic has numerous consequences. Of particular relevance, the precipitation regime is modified where mixed and liquid precipitation can occur during the winter season leading to rain‐on‐snow (ROS) events. This phenomenon is responsible for ice crust formation, which has a significant impact on ecosystems (such as biological, hydrological, ecological and physical processes). The spatially and temporally sporadic nature of ROS events makes the phenomenon difficult to monitor using meteorological observations. This paper focuses on the detection of ROS events using passive microwave (PMW) data from a modified brightness temperature (T_B) gradient approach at 19 and 37 GHz. The approach presented here was developed empirically for observed ROS events with coincident ground‐based PMW measurements in Sherbrooke, Quebec, Canada. It was then tested in Nunavik, Quebec, with the Advanced Microwave Scanning Radiometer for the Earth Observing System (AMSR‐E). We obtained a detection accuracy of 57, 71 and 89% for ROS detection for three AMSR‐E grid cells with a maximum error of 7% when considering all omissions and commissions with regard to the total number of AMSR‐E passes throughout the winter period. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

基于一维综合孔径微波辐射计的海面温度反演研究   总被引：1，自引：0，他引：1  

艾未华  冯梦延  陈冠宇  陆文 《海洋学报(英文版)》2020,42(5):115-122

Due to the low spatial resolution of sea surface temperature(T_S) retrieval by real aperture microwave radiometers,in this study, an iterative retrieval method that minimizes the differences between brightness temperature(T_B)measured and modeled was used to retrieve sea surface temperature with a one-dimensional synthetic aperture microwave radiometer, temporarily named 1 D-SAMR. Regarding the configuration of the radiometer, an angular resolution of 0.43° was reached by theoretical calculation. Experiments on sea surface temperature retrieval were carried out with ideal parameters; the results show that the main factors affecting the retrieval accuracy of sea surface temperature are the accuracy of radiometer calibration and the precision of auxiliary geophysical parameters. In the case of no auxiliary parameter errors, the greatest error in retrieved sea surface temperature is obtained at low T_S scene(i.e., 0.710 6 K for the incidence angle of 35° under the radiometer calibration accuracy of0.5 K). While errors on auxiliary parameters are assumed to follow a Gaussian distribution, the greatest error on retrieved sea surface temperature was 1.330 5 K at an incidence angle of 65° in poorly known sea surface wind speed(W)(the error on W of 1.0 m/s) over high W scene, for the radiometer calibration accuracy of 0.5 K.  相似文献   

2010-2018年北极夏季中国北极科学考察航行期间被动微波遥感海冰密集度与船基目视观测资料的比较   总被引：2，自引：0，他引：2  

修苑人  李志军  雷瑞波  王庆凯  卢鹏  Lepp&#;ranta Matti 《海洋学报(英文版)》2020,39(9):38-49

为了更有效地将卫星数据应用于北极航行导航，被动微波（PM）产品的海冰密集度（SIC）与从中国北极科学考察中收集到的船基目视观测（OBS）资料进行了比较。在2010、2012、2014、2016和2018年的北极夏季总共收集了3667组目测数据。PM SIC取自基于SSMIS传感器的NASA-Team（NT）、Bootstrap（BT）以及Climate Data Record（CDR）算法和基于AMSR-E/AMSR-2传感器的BT、enhanced NT（NT2）以及ARTIST Sea Ice（ASI）算法。使用PM SIC的日算术平均值和OBS SIC的日加权平均值进行比较。比较了PM SIC和OBS SIC之间的相关系数，偏差和均方根偏差，包括总体趋势以及在轻度/普通/严重冰况下的情况。使用OBS数据，浮冰尺寸和冰厚对不同PM产品SIC反演的影响可以通过计算浮冰尺寸编码和冰厚的日加权平均值来评估。我们的结果显示相关系数的范围为0.89（AMSR-E/AMSR-2 NT2）到0.95（SSMIS NT），偏差的范围为-3.96%（SSMIS NT）到12.05%（AMSR-E/AMSR-2），均方根偏差的范围为10.81%（SSMIS NT）到20.15%（AMSR-E/AMSR-2 NT2）。浮冰尺寸对PM产品的SIC反演有显著的影响，大多数PM产品倾向于在小浮冰尺寸情况下低估SIC，而在大浮冰尺寸情况下高估SIC。超过30 cm的冰厚对于PM产品的SIC反演没有明显影响。总体来看，在北极夏季，SSMIS NT SIC与OBS SIC之间有着最好的一致性，而AMSR-E/AMSR-2 NT2 SIC与OBS SIC的一致性最差。  相似文献   

电感耦合等离子体质谱法测定铅合金中的微量杂质元素镉和锡   总被引：1，自引：1，他引：0  

郝原芳  刘新  宋丽华  李丽君  徐英奎 《岩矿测试》2016,35(4):378-383

铅合金中的镉和锡由于含量较低,国家标准方法均为单一元素分析,步骤繁琐,检出限高,难以达到理想的检出要求。本文建立了应用电感耦合等离子体质谱法(ICP-MS)测定铅合金中微量级(μg/g级)杂质元素镉和锡的分析方法。采用单一的低浓度硝酸溶解铅合金,用低温慢溶的方式使样品溶解更加完全,减少了多离子对仪器的干扰;通过铅基体匹配和加入酒石酸保证了标准与样品介质的一致性,同时避免了锡的水解;以~(103)Rh作为内标元素,~(111)Cd和~(118)Sn作为测量同位素克服了质谱干扰。方法检出限为镉0.05 ng/g、锡0.04 ng/g,比国家标准方法的检出限(1~6μg/g)低,精密度小于4%。该方法试剂用量少,减少了处理样品的复杂性,实现了合金中微量级元素的准确测定。  相似文献   

利用微波等离子体炬四极杆质谱在线测定稀土矿样中的多种稀土元素     

初晨  张瑛  王尚贤  周润芝  蒋涛  朱志强  卢爱民 《岩矿测试》2016,35(5):468-474

随着稀土的应用越来越广泛,开发稀土元素的快速在线检测技术已日趋成为行业发展的需求。本文以微波等离子体炬(MPT)为离子源,以四极杆质谱仪(QMS)作为质量分析器建立了一种快速、直接检测水样中稀土元素的质谱检测方法,并将其应用于分析稀土矿样中的多种稀土元素。研究表明,应用MPT-QMS测定水样中的钇、镧、铈、钕、铕五种稀土元素,检出限(LOD)可达11.0~60.5μg/L,测定范围为50~1000μg/L。当分析固体稀土矿样时,样品经酸溶处理后通过气动雾化形成气溶胶,再进行冷却干燥,气溶胶由MPT的中心管道进入等离子体中,产生稀土元素复合离子,再引入QMS中进行分析,即可以定量地测定矿样中稀土元素的含量。同一样品用电感耦合等离子体质谱(ICP-MS)进行对比实验,两者的检测结果在数量级上接近,证明了MPTQMS方法在半定量的意义下是准确、可靠的,因而这种快速的检测方法可发展成为水体中金属元素的现场分析方法,应用于环境水、生活水质量在线监测等领域。  相似文献