Carbon and oxygen isotopic composition of car- bonate cements of different phases in terrigenous siliciclastic reservoirs and significance for their origin： A case study from sandstones of the Triassic Yanchang Formation, southwestern Ordos Basin, China     

Qi Wang  Xizhun Zhuo  Guojun Chen  Xiaoyan Li 《中国地球化学学报》2008,27(3):249-256

Early carbonate cements in the Yanchang Formation sandstones are composed mainly of calcite with relatively heavier carbon isotope （their δ^18O values range from -0.3‰- -0.1‰） and lighter oxygen isotope （their δ^18O values range from -22.1‰- -19.5‰）. Generally, they are closely related to the direct precipitation of oversaturated calcium carbonate from alkaline lake water. This kind of cementation plays an important role in enhancing the anti-compaction ability of sandstones, preserving intragranular volume and providing the mass basis for later disso- lution caused by acidic fluid flow to produce secondary porosity. Ferriferous calcites are characterized by relatively light carbon isotope with δ^13C values ranging from -8.02‰ to -3.23‰, and lighter oxygen isotope with δ^18O values ranging from -22.9‰ to -19.7‰, which is obviously related to the decarboxylation of organic matter during the late period of early diagenesis to the early period of late diagenesis. As the mid-late diagenetic products, ferriferous cal- cites in the study area are considered as the characteristic authigenic minerals for indicating large-scaled hydrocarbon influx and migration within the clastic reservoir. The late ankerite is relatively heavy in carbon isotope with δ^13C values ranging from -1.92‰ to -0.84‰, and shows a wide range of variations in oxygen isotopic composition, with δ^18O values ranging from -20.5‰ to -12.6‰. They are believed to have nothing to do with decarboxylation, but the previously formed marine carbonate rock fragments may serve as the chief carbon source for their precipitation, and the alkaline diagenetic environment at the mid-late stage would promote this process.  相似文献   

Environmental Redox Changes of the Ancient Sea in the Yangtze Area during the Ordo-Silurian Transition     

YAN Detian  CHEN Daizhao  WANG Qingchen  WANG Jianguo  CHU Yang 《《地质学报》英文版》2008,82(3):679-689

Extensive organic-matter （OM） rich facies （black shales） occur in the Ordo-Silurian boundary successions in the Yangtze area, South China. To investigate the redox changes of the Yangtze Sea during the Ordo-Silurian transition, two OM sections （Wangjiawan in Yichang, Hubei Province, and Sanjiaguan in Zhangjiajie, Hunan Province） straddling the Ordo-Silurian boundary are studied. The measurements finished in this study include contents of the total organic carbon （TOC）, pyrite sulphur, and different species of Fe, including dithionite-extractable Fe （FED）, pyrite Fe （FeP）, HCl-extractable Fe （FeH）, and total Fe （FeT）, in black shales, as well as other redox proxies, such as the SIC ratio, the ratio between highly reactive Fe （FeHR = FeD ＋ FeP） and FeT, and the FeP/（FeP ＋ FeH） ratio, known as the degree of pyritization （DOP）. In the Wangjiawan section, the Middle Ashgill sediments have high FeHR/FeT ratios （0.20-0.77; avg. 0.45）, high DOP values （0.21-0.72; avg. 0.54）, and a relatively constant sulfur content independent of the organic carbon content. By the contrast, the mid-early Hirnantian deposits generally have low FeHR/FeT ratios （0.10-0.35; avg. 0.21）, low DOP values （0.11- 0.40; avg. 0.28）, and SIC values are clustering on the normal marine value （SIC = 0.36）. The late Hirnantian and early Rhuddanian deposits, similar to those of the Middle Ashgill deposits, are characterized by high FeHR/FeT ratios （0.32-0.49; avg. 0.41）, high DOP values （0.46-0.68; avg. 0.53） and fairly constant sulfur contents. These data suggest the occurrences of marine anoxia on the Yangtze Sea shelf during intervals of the Mid Ashgill, Late Hirnantian and Early Rhuddanian, and ventilated and oxygenated marine conditions during the mid-early Hirnantian time. The mid-early Hirnantian ventilated event was concomitant with the global glacial period, likely resulted from the glacio-eustatic sea-level fall and subsequent circulation of cold, dense oxygenated waters  相似文献   

波流共存场中多向随机波浪传播变形数学模型   总被引：1，自引：0，他引：1       下载免费PDF全文

郑金海  Hajime Mase 《水科学进展》2008,19(1):78-83

基于波作用量守恒方程建立了波流共存场中多向随机波浪传播变形数学模型,模型中考虑了波浪绕射的影响和水流引起的波浪弥散多普勒效应,应用包含水流和地形影响的激破波模式计算波浪破碎的能量耗散,采用一阶上迎风有限差分格式离散控制方程。分别计算了有无近岸流情况下单向和多向随机波浪的波高分布,考虑水流影响的数值计算结果与物理模型实验数据吻合良好,比较分析表明,所建立的数学模型能够复演由于离岸流引起的波高增大,可用于波流共存场多向随机波浪传播变形的模拟和预报。  相似文献   

利用参考重力场模型基于能量法确定GRACE加速度计校准参数   总被引：1，自引：0，他引：1  

徐新禹  李建成  王正涛  邹贤才 《武汉大学学报(信息科学版)》2008,33(1):72-75

利用多个参考重力场模型分别对GRACE一个月的实测加速度计观测数据进行检校.数值计算结果的比较分析表明了利用参考重力场模型确定加速度计校准参数是有效的.  相似文献   

评价生物气生成量、生成期的元素平衡法及其应用   总被引：2，自引：0，他引：2  

卢双舫  刘绍军  申家年  薛海涛  徐庆霞  胡慧婷  王民 《地学前缘》2008,15(2):195-199

生物气的生成期对其成藏有至关重要的制约作用,但目前国内外尚缺少可信、有效方法来对此进行评价。针对这一难题,考虑到无论生物气的生成机理如何,都是一个有机元素之间的物质平衡过程,文章探索并建立了评价生物气生成量的元素平衡法,并利用松辽盆地大量的实际分析数据,对这一评价方法(模型)进行了标定和应用。结果表明,松辽盆地生物气的生成可能主要发生在800m以浅的埋深条件下;区内源岩生物气的生成量约为285.0×1012m3;生物气的主要生成期在嫩江组沉积末期之前。  相似文献   

生物气CO_2还原途径中碳同位素分馏作用研究及应用   总被引：2，自引：0，他引：2  

李谨  胡国艺  张英  杨贵芳  崔会英  曹宏明  胡须龙 《地学前缘》2008,15(5):357

地质历史中,CO2/H2还原产甲烷作用对生物气的形成具有十分重要的意义。中国柴达木盆地第四系生物气主要为CO2/H2还原型生物气。笔者以CO2/H2还原生气理论为指导,进行不同初始碳同位素值和不同赋存状态碳源的生物模拟实验,研究CO2/H2还原产气过程中发生的碳同位素分馏作用。实验结果表明,产物中δ13CH4值与底物的δ13C值呈很好的正相关关系;在反应母质过量的情况下,碳源的赋存状态可以影响产物甲烷的碳同位素组成。以游离形式CO2还原产生的甲烷δ13C值,相对于以HCO3-、CO23-离子形式产生的甲烷δ13C值轻。通过柴达木盆地东部第四系生物气田实例分析,探讨了该区生物气的主要底物CO2的来源及赋存状态,对评价盆地生物气资源和有利勘探区预测有重要的参考价值。  相似文献   

大民屯凹陷烃源岩有机质丰度的恢复   总被引：2，自引：0，他引：2       下载免费PDF全文

逯向阳 《沉积与特提斯地质》2008,28(4):14-17

烃源岩有机质丰度的恢复具有重要的现实和理论意义。笔者在对比多种方法的基础上,对大民屯凹陷的烃源岩的有机质丰度进行了恢复。  相似文献   

Time-dependent stress change during failure of rocks     

V.T. Belikov  A.F. Shestakov 《Russian Geology and Geophysics》2008,49(5):350-356

The energy balance of a solid subject to fracture has been explored using heat and mass transfer equations with regard to the volumetric and superficial components. In the suggested model, brittle fracture of a cracked solid considered as a heterogeneous two-phase medium is described by an equation analogous to the Griffith’s criterion for propagation of a single crack. The derived equation is used, together with estimates of relative change in specific interface area, to study the respective change of free strain energy and pressure in rocks associated with failure.  相似文献   

Holocene climate reconstructions of Ulungur Lake (Xinjiang,China) inferred from ostracod species assemblages and stable isotopes     

Qingfeng JIANG  Ji SHEN  Xingqi LIU  Enlou ZHANG 《Frontiers of Earth Science》2008,2(1):31-40

In this paper, the data on the paleoclimatic and paleoenvironmental changes during the Holocene are presented and a discussion is made on a 225-cm-long sediment core from Ulungur Lake, located in Northwest China. The chronology is constructed from six AMS radiocarbon dates on the bulk organic matter. On the basis of the analysis of ostracod assemblages and the shell stable isotopes, the core is divided into three paleoclimatic and paleoenvironmental evolution stages: 9 985–5 250 cal.aB.P. stage is the wettest phase of the core section. The climate changed from moderate-dry to cool-wet, and then to warm-wet in turn, and the lake level rose accordingly, showing the characteristic of a high lake level. 5 250–1 255 cal.aB.P. stage was the driest phase of the core sediment. The climate turned from the early warm-dry to the late warm-wet and the lake level fell and rose again. Finally, the 1 255 cal.aB.P. stage was the medium stage of the section. The temperature was low and then increased after the 1920s and the climate was dry. The whole climatic and environmental evolution records of Lake Ulungur were not only in agreement with the sporopollen record of the same core but also in agreement with the record of environmental changes of adjacent areas. It responded to regional environmental changes and global abrupt climate events, following the westerly climate change mode on 100-year-scale, primarily with cold-wet and warmdry characteristics. __________ Translated from Quaternary Sciences, 2007, 27(3):382–391 [译自:第四纪研究]  相似文献   

封闭体系有机质与有机碳氢氮恢复动力学研究   总被引：3，自引：0，他引：3  

彭平安  秦艳  张辉  刘大永  张善文  隋风贵  李钜源  李政 《海相油气地质》2008,13(2):27-36

在封闭体系的条件下,对典型的Ⅰ、Ⅱ、Ⅲ型干酪根在热演化过程中的损失进行生烃动力学研究,获得了Ⅰ、Ⅱ、Ⅲ型干酪根的总量、有机碳、氢以及氮质量损失动力学参数。用Kinetics软件计算了封闭体系干酪根有机碳丰度、氢碳原子比和氮碳原子比的恢复系数。认为在对高成熟—过成熟干酪根进行生烃评价时,Ⅰ、Ⅲ型干酪根残余有机碳丰度需要进行恢复,而Ⅱ型干酪根残余有机碳丰度不需要恢复。三种类型干酪根的氢碳原子比均需要进行恢复。  相似文献