Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

海岸破波带内悬沙空间分布试验研究和解析表达式     

张洋  邹志利  孙大鹏  薛武山 《海洋工程》2018,36(1):28-46

关于海岸破波带内悬沙浓度水平和垂向分布的研究对于计算海岸输沙率和地形演变具有重要意义。本研究进行了规则波、波群和不规则波三种波浪情况破波带内悬沙浓度的水平和垂向分布的试验测量。试验在大尺度波浪水槽进行,接近实际海岸波况尺度。给出了破波带内多断面悬沙垂向分布的细致测量结果,并以此为基础给出了预报实际海岸破波带内悬沙浓度水平和垂向分布解析表达式,讨论了形成这些分布的物理原因和不同波况、不同破波带区域对分布的影响。  相似文献   

300 BC-1900 AD无定河流域城镇时空格局演变   总被引：2，自引：1，他引：1  

佟彪  党安荣  许剑 《地理学报》2019,74(8):1508-1524

通过分析和整理从战国中晚期（约300 BC）至清末（约1900 AD）无定河流域历代县级及以上城址的位置、兴废年代数据,结合行政区划沿革、经济社会发展、政权更迭等资料,分析流域城镇格局的时空演变过程。研究表明：① 受气候周期性波动影响,无定河流域城镇的兴起与衰废具有明显的周期性特征,城镇几何中心的移动轨迹具有明显的“西北—东南”向潮汐性运动特征;② 城址存续年限普遍较短,具有明显的阶段性特征,流域内曾存在过4个阶段性中心城镇,中心城镇移动的方向和过程与城镇几何中心的潮汐性移动过程趋势一致;③ 流域城镇空间格局可分为3种类型,即秦汉与隋唐时期的沿河流谷地分布,宋、明两代的沿边境线与长城分布,以及元、清两代集中于流域下游分布。流域城镇未来的发展布局应重视气候变化对城镇分布的长期影响,关注区域环境的脆弱性,合理安排城镇体系发展规模与布局。  相似文献   

Parallelization of the flow-path network model using a particle-set strategy     

Fangli Zhang 《International journal of geographical information science》2019,33(10):1984-2010

High-performance simulation of flow dynamics remains a major challenge in the use of physical-based, fully distributed hydrologic models. Parallel computing has been widely used to overcome efficiency limitation by partitioning a basin into sub-basins and executing calculations among multiple processors. However, existing partition-based parallelization strategies are still hampered by the dependency between inter-connected sub-basins. This study proposed a particle-set strategy to parallelize the flow-path network (FPN) model for achieving higher performance in the simulation of flow dynamics. The FPN model replaced the hydrological calculations on sub-basins with the movements of water packages along the upstream and downstream flow paths. Unlike previous partition-based task decomposition approaches, the proposed particle-set strategy decomposes the computational workload by randomly allocating runoff particles to concurrent computing processors. Simulation experiments of the flow routing process were undertaken to validate the developed particle-set FPN model. The outcomes of hourly outlet discharges were compared with field gauged records, and up to 128 computing processors were tested to explore its speedup capability in parallel computing. The experimental results showed that the proposed framework can achieve similar prediction accuracy and parallel efficiency to that of the Triangulated Irregular Network (TIN)-based Real-Time Integrated Basin Simulator (tRIBS).  相似文献   

利用超快速精密星历约束的北斗卫星实时精密定轨     

范磊  施闯  李敏 《大地测量与地球动力学》2018,38(9):937-942

以广播星历为起算轨道的北斗卫星实时滤波精密定轨往往需要较长收敛时间，针对此，提出利用超快速精密星历约束的实时精密定轨方法。通过MGEX跟踪网全球分布的51个测站连续7 d的实测数据，利用平方根信息滤波对北斗卫星实时精密轨道进行确定，并以3 d解事后轨道作为参考，评估北斗卫星实时滤波轨道精度。结果表明，利用广播星历作起算轨道时，北斗实时滤波轨道平均需要经过15 h收敛才能达到稳定，而新方法在这段时间内轨道变化较为平稳，未出现明显的收敛现象，并且7 d时间内GEO卫星在切向、法向和径向上RMS分别优于2.5 m、20 cm和30 cm，IGSO和MEO卫星在3个方向上分别优于30 cm、15 cm和10 cm。
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基于高斯两步移动搜寻法的村镇避难场所可达性研究     

但文羽  肖映辉  胡周灵  詹庆明 《地球信息科学学报》2018,20(10):1412-1421

避难场所可达性是指避难场所与受灾居民之间的通达性,即灾害发生时,避难人员通过避难疏散通道到达避难场所的难易程度,是评价避难场所布局合理性的重要指标。本研究结合高斯两步移动搜寻法和网络分析法,从供需双向出发对村镇地区避难场所进行可达性分析。2种方法的结合,既充分考虑了需求点与设施点的相互作用,又充分考虑了设施点的吸引力随距离的衰减关系,并基于实际道路,以步行疏散时间作为搜索半径,降低了传统研究中因忽略供需间相互作用及实际距离而引起的可达性结果的误差。最后,以神农架松柏镇区为例,验证该方法的实际应用价值。结果表明,该方法能够有效测定村镇地区避难场所的空间可达性,同时,基于GIS软件可以直观地揭示研究区域内避难场所可达性空间分布差异。该方法可为制定科学的村镇防灾减灾规划提供方法支持。  相似文献   

山东省地面沉降监测与防治工作进展          下载免费PDF全文

张永伟  邵明  肖敏 《山东国土资源》2018,34(8)

近年来,山东省地面沉降监测与防治工作取得了重要进展,初步建立了以二等水准路线、全球定位系统(GPS)、基岩标分层标和地下水监测为基础的"四网合一"地面沉降监测体系,INSAR监测实现了山东全省覆盖。监测成果显示,山东省地面沉降主要位于东营市广饶县、滨州市博兴县、聊城市茌平县,沉降速率呈加快趋势,造成建筑物地基下沉、房屋开裂、地下管道破损等一系列地质环境问题。  相似文献   

涉密矢量数字地图中敏感要素几何信息量的测度方法     

李安波  陈楹  姚蒙蒙  吴赛松 《地球信息科学学报》2018,20(1):7-16

涉密矢量数字地图中敏感要素几何信息的定量测度,是实现定量化密级评定的基础和前提。如何进行敏感要素几何信息量的计算,目前尚缺乏相关研究。在现有地图信息论研究成果的基础上,论文主要开展了3方面的研究工作：首先,从地理对象的敏感性入手,探讨了地图要素敏感性的定义与要素集合的敏感性表征指标;然后,基于任意发生元的Voronoi构建方法,实现了对点要素集、线要素集、部分覆盖面要素集及综合要素集的信息单元自动化剖分;最后,基于长度系数、面积系数和角度系数,提出了线、面要素图形复杂度的计算方法,并在此基础上形成了涉密矢量数字地图中敏感几何信息量的测度方法。实验表明,该方法的计算结果遵循了信息量的非负性、连续性、可加性等特点,较为合理地反映了相关因素（地图比例尺、要素空间分布、要素图形复杂度、要素敏感系数等）对计算结果的影响。相关成果将支持矢量数字地图的定量化密级评定,并有助于完善地理信息安全监管的理论和方法体系。  相似文献   

基于圆柱多段拟合的隧道中轴线提取方法研究     

荆海峰  李广云  王力  杨文锋 《大地测量与地球动力学》2018,38(2):211-215

提出基于圆柱多段拟合的隧道中轴线提取方法。首先对隧道点云数据进行预处理，并将点云按隧道走向分成不同区段；然后对各区段依据轴线与表面点云法线垂直关系，提取精度较低的中轴线；最后对各区段利用圆柱多段拟合，提取精度较高的中轴线。实验表明，隧道中轴线的提取在一定的采样区间具有较高的稳定性，对直线和弯曲的圆形隧道有良好的适用性，算法可靠，精度较高。  相似文献   

基于GIS的石家庄市雾霾分析     

苏亚聪  史娟  徐爽 《北京测绘》2020,(2):233-237

为了得出雾霾气象成因机制、影响因素和时空分布特征,以石家庄市区与郊县为研究区域,将2013年9月至2016年12月石家庄市各市区、郊县的PM2.5历史监测数据中的有效数据进行了数据分析处理得到雾霾浓度数据,还有温度、降水、风速、地形和人口密度等数据,运用GIS分析的方法,模拟绘制石家庄雾霾的时空分布图、雾霾与各影响因子的专题对比图,得到雾霾形成机制的因子、雾霾的时空分布规律、雾霾季节变化特征、雾霾与地形间的关系等;运用数据分析软件OriginPro8.SR3分析雾霾浓度与风速数据、降雨数据、温度数据间的相关性。  相似文献