GGR Critical Review of Analytical Developments in 2003     

Janet M. Hergt  L. Paul Bédard  Etienne Deloule  Kathryn L. Linge  Paul J. Sylvester  Michael Wiedenbeck  Jon D. Woodhead 《Geostandards and Geoanalytical Research》2005,29(1):5-52

The articles that comprise this critical review serve to draw attention to research papers published in specific fields of interest during 2003, provide critical comment on the relevance and importance of individual publications in these fields, and offer an overview of the comparative importance of advances in particular areas. In this way, these articles aim to assist experts in the field by keeping them informed of relevant recent publications, as well as providing an important resource for students or early career researchers who are embarking on studies in an area new to them. This year, five papers provide summaries of developments in bulk sample determinations employing (1) ICP-AES and ICP-MS (trace elements), (2) XRF and atomic absorption spectrometry and INAA, (3) isotope ratio measurements (TIMS, MC-ICP-MS, ICP-MS, ToF), as well as in situ measurements conducted using (4) secondary ion mass spectrometry and (5) laser ablation ICP-MS (trace element and isotope ratio determinations).  相似文献   

Determination of Lithium, Beryllium and Boron at Trace Levels by Laser Ablation-Inductively Coupled Plasma-Sector Field Mass Spectrometry   总被引：1，自引：2，他引：1  

Massimo Tiepolo  Alberto Zanetti  Riccardo Vannucci 《Geostandards and Geoanalytical Research》2005,29(2):211-224

The analytical capabilities of laser ablation (LA)-ICP-MS in determining Li, Be and B at trace levels in geological samples have been tested on a series of glass reference materials and natural samples. The LA-ICP-MS instrument used consisted of a sector-field ICP-MS coupled with a laser ablation microprobe operating at either 266 or 213 nm wavelength. Reference glasses from NIST (SRM 612, 614 and 616) and MPI-DING (KL2-G, ML3B-G, StHs6/80-G, GOR128-G, GOR132-G, T1-G and ATHO-G) were selected to develop the analytical method and to assess the best instrumental configuration. A series of calcic amphiboles with different Li, Be and B concentrations were also analysed using both LA-ICP-MS and SIMS to test the applicability of the method to natural minerals. Results indicated that with a spot size of 40 μm the agreement between measured and reference values of Li, Be and B is generally better than 10% for NIST SRM 612 and 20% for NIST SRM 614. Average reproducibility at the 2s level was 10% for Li, 20% for Be and 15% for B. Limits of detection were approximately 100 ng g^-1 for Be and B and 200 ng g^-1 for Li. These results were confirmed by analyses carried out on natural amphiboles and compared well in terms of precision and accuracy with those commonly achieved by SIMS.  相似文献   

Preliminary Characterisation of New Glass Reference Materials (GSA-1G, GSC-1G, GSD-1G and GSE-1G) by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry Using 193 nm, 213 nm and 266 nm Wavelengths   总被引：5，自引：1，他引：5  

Marcel Guillong  Kathrin Hametner  Eric Reusser  Stephen A. Wilson  Detlef Günther 《Geostandards and Geoanalytical Research》2005,29(3):315-331

New glass reference materials GSA-1G, GSC-1G, GSD-1G and GSE-1G have been characterised using a prototype solid state laser ablation system capable of producing wavelengths of 193 nm, 213 nm and 266 nm. This system allowed comparison of the effects of different laser wavelengths under nearly identical ablation and ICP operating conditions. The wavelengths 213 nm and 266 nm were also used at higher energy densities to evaluate the influence of energy density on quantitative analysis. In addition, the glass reference materials were analysed using commercially available 266 nm Nd:YAG and 193 nm ArF excimer lasers. Laser ablation analysis was carried out using both single spot and scanning mode ablation. Using laser ablation ICP-MS, concentrations of fifty-eight elements were determined with external calibration to the NIST SRM 610 glass reference material. Instead of applying the more common internal standardisation procedure, the total concentration of all element oxide concentrations was normalised to 100%. Major element concentrations were compared with those determined by electron microprobe. In addition to NIST SRM 610 for external calibration, USGS BCR-2G was used as a more closely matrix-matched reference material in order to compare the effect of matrix-matched and non matrix-matched calibration on quantitative analysis. The results show that the various laser wavelengths and energy densities applied produced similar results, with the exception of scanning mode ablation at 266 nm without matrix-matched calibration where deviations up to 60% from the average were found. However, results acquired using a scanning mode with a matrix-matched calibration agreed with results obtained by spot analysis. The increased abundance of large particles produced when using a scanning ablation mode with NIST SRM 610, is responsible for elemental fractionation effects caused by incomplete vaporisation of large particles in the ICP.  相似文献   

Microcrack networks in granite affected by a fault zone: Visualization by confocal laser scanning microscopy     

Celia T. Onishi  Ichiko Shimizu   《Journal of Structural Geology》2005,27(12):170

Microcracks in the Cretaceous Ryoke-type granite in Japan were investigated by using deep drilling core samples collected in the Mizunami Underground Research Project of the Japan Nuclear Cycle Development Institute (JNC). The granite body suffered brittle deformation associated with Tertiary thrust movement. Based on core-scale and microscopic deformation features, the drill core from a depth of 300 to 700 m is divided into four domains, i.e. (A) undeformed granite, (B) granite intruded by cataclastic seams, (C) fractured granite in the fault damage zone, and (D) foliated cataclasite at the fault center. To characterize microcrack geometries in each domain, we employed the impregnation method using a low-viscous acrylic resin doped with fluorescent agents and captured the microcrack images by confocal laser scanning microscopy (CLSM). The CLSM image in the fault damage zone revealed anisotropic development of microcrack networks related to the fault movement. Both CLSM observation and porosity measurements reveal a drastic increase of micro-pores in the foliated cataclasite, possibly caused by fragmentation, and granulation and crack sealing in the fault zone.  相似文献   

Critical Top Tension for Static Equilibrium Configuration of A Steel Catenary Riser     

Chainarong ATHISAKUL  Karun KLAYCHAM  Somchai CHUCHEEPSAKUL 《中国海洋工程》2014,(6):829-842

This paper aims to present the critical top tension for static equilibrium configurations of a steel catenary riser（SCR） by using the finite element method. The critical top tension is the minimum top tension that can maintain the equilibrium of the SCR. If the top tension is smaller than the critical value, the equilibrium of the SCR does not exist. If the top tension is larger than the critical value, there are two possible equilibrium configurations. These two configurations exhibit the nonlinear large displacement. The configuration with the smaller displacement is stable, while the one with larger displacement is unstable. The numerical results show that the increases in the riser＇s vertical distances, horizontal offsets, riser＇s weights, internal flow velocities, and current velocities increase the critical top tensions of the SCR. In addition, the parametric studies are also performed in order to investigate the limit states for the analysis and design of the SCR.  相似文献   

Response of Plant Community Carbon and Nitrogen Stoichiometry to Experimental Warming on the Qinghai-Tibet Plateau     

ZHANG Haorui  QIN Jiwei  FU Gang 《资源与生态学报(英文版)》2020,11(3):315-321

Low temperature is an important limiting factor for alpine ecosystems on the Tibetan Plateau. This study is based on data from on-site experimental warming platforms (open top chambers, OTC) at three elevations (4300 m, 4500 m, 4700 m) on the Qinghai-Tibet Plateau. The carbon and nitrogen stoichiometry characteristics of plant communities, both above-ground and below-ground, were observed in three alpine meadow ecosystems in August and September of 2011 and August of 2012. Experimental warming significantly increased above-ground nitrogen content by 21.4% in September 2011 at 4500 m, and reduced above-ground carbon content by 3.9% in August 2012 at 4300 m. Experimental warming significantly increased below-ground carbon content by 5.5% in August 2011 at 4500 m, and the below-ground ratio of carbon to nitrogen by 28.0% in September 2011 at 4300 m, but reduced below-ground nitrogen content by 15.7% in September 2011 at 4700 m, below-ground carbon content by 34.3% in August 2012 at 4700 m, and the below-ground ratio of carbon to nitrogen by 37.9% in August 2012 at 4700 m. Experimental warming had no significant effect on the characteristics of community carbon and nitrogen stoichiometry under other conditions. Therefore, experimental warming had inconsistent effects on the carbon and nitrogen stoichiometry of plant communities at different elevations and during different months. Soil ammonium nitrogen and nitrate nitrogen content were the main factors affecting plant community carbon and nitrogen stoichiometry.  相似文献   

利用3S技术及三维激光扫描仪进行耕地损毁勘测     

林学艺 《测绘与空间地理信息》2016,(2):88-90

利用RS技术发现耕地损毁,网络RTK测量耕地损毁范围及面积,GIS提取耕地被损毁前的分类面积和等别,以及利用网络RTK配合Maptek I-Site8810三维激光扫描仪重构损毁耕地三维模型。  相似文献   

地面三维激光扫描仪测量误差检定     

代志宇  肖昭然  王力  杨文峰 《测绘与空间地理信息》2016,(7):79-81

在利用三维激光扫描仪进行测量工作前,我们首先应了解其实际测量精度是否符合标称精度,而可靠的评价方式对得到精确的数据结果至关重要。本文利用北京卓立汉光TSA50-C型电动位移台作为评价标准,通过其精确的位移功能,准确地评价了RIGEL VZ-400三维激光扫描仪在测量单点位移时的误差,从而得到了其最佳工作距离。  相似文献   

三维激光扫描技术在曲面模型重建中的应用     

杨忞婧  刘丽  张金兰  王阳 《测绘与空间地理信息》2016,(8)

利用地面三维激光扫描仪对目标物体表面进行多方位、多角度的扫描,可以获取其表面大量且密集的高精度点的三维坐标信息以及反射率信息,将这些信息存储到电脑中,使用专业软件进行处理,再使用建模软件生成建筑物的三维模型。本文所研究的是使用地面三维激光扫描仪,通过高速激光测量方式,快速、全面、精确地获取建筑物表面的三维信息,经过一系列的点云数据处理及模型处理,最终完成曲面模型三维重建的过程。  相似文献   

浅析运营期间电力隧道自动化监测技术     

罗静  卢凌燕  任卫波  许业霞 《测绘与空间地理信息》2016,(8):204-206

针对城市电力隧道结构、走向多变、电缆设施多、电磁干扰大等因素,常规的监测方法难以顺利完成的现状,对目前先进的3种隧道结构自动化监测系统进行深入的研究比较,光纤传感自动技术解决了电力隧道结构监测点布设困难,数据受电磁干扰大的问题,能实时有效、可靠、高精度地监控电力隧道,及时掌握隧道的应力、应变及振动等主要结构参数,确保隧道结构安全。研究对类似的城市电力隧道自动化监测具有一定的参考意义。  相似文献