Automated Extraction of a Five‐Year LA‐ICP‐MS Trace Element Data Set of Ten Common Glass and Carbonate Reference Materials: Long‐Term Data Quality,Optimisation and Laser Cell Homogeneity          下载免费PDF全文

David Evans  Wolfgang Müller 《Geostandards and Geoanalytical Research》2018,42(2):159-188

LA‐ICP‐MS is increasingly applied to obtain quantitative multi‐element data with minimal sample preparation, usually achieved by calibration using reference materials (RMs). However, some ubiquitous RMs, for example the NIST SRM 61× series glasses, suffer from reported value uncertainties for certain elements. Moreover, no long‐term data set of analyses conducted over a range of ablation and tuning conditions exists. Thus, there has been little rigorous examination of the extent to which offsets between measured and reported values are the result of error in these values rather than analytically induced fractionation. We present new software (‘LA‐MINE’), capable of extracting LA‐ICP‐MS data with no user input, and apply this to our system, yielding over 5 years of data (~ 5700 analyses of ten glass and carbonate RMs). We examine the relative importance of systematic analytical bias and possible error in reported values through a mass‐specific breakdown of fourteen of the most commonly determined elements. Furthermore, these data, obtained under a wide range of different ablation conditions, enable specific recommendations of how data quality may be improved, for example the role of diatomic gas, the effect of differential inter‐glass fractionation factors and choice of transport tubing material. Finally, these data demonstrate that the two‐volume Laurin ablation cell is characterised by no discernible spatial heterogeneity in measured trace element ratios.  相似文献   

基于面向对象分类的稀土开采区遥感信息提取方法研究     

代晶晶  吴亚楠  王登红  令天宇  王俊华 《地球学报》2018,39(1):111-118

离子吸附型稀土矿是我国宝贵的矿产资源,运用遥感影像分类技术提取稀土开采区可以准确地实现对稀土开采状况的监测,但仅利用光谱信息往往难以保证分类精度。本文以江西寻乌稀土矿区为研究区,以IKONOS影像为数据源,应用面向对象分类方法提取了稀土开采区的遥感信息。针对稀土开采区的分布特点,选择基于边缘的分割算法进行影像分割;结合地形信息、光谱信息及几何信息建立规则集,进行特征提取;最后采用隶属度函数法实现面向对象分类,并与传统的光谱角填图分类进行对比分析。研究结果表明,面向对象分类法提取稀土开采区的总体精度为92.49%,Kappa系数为0.857 6,与传统监督分类方法相比有了很大的提高。  相似文献   

Object- and pixel-based classifications of macroalgae farming area with high spatial resolution imagery     

Yuhan Zheng  Anqi Wang  Jiang Chen 《国际地球制图》2018,33(10):1048-1063

Macroalgae plays an important role in coastal ecosystems. The accurate delineation of macroalgae areas is important for environmental management. This study compared the pixel- and object-based methods using Gaofen satellite no. 2 image to explore an efficient classification approach. Expert system rules and nearest neighbour classifier were adopted for object-based classification, whereas maximum likelihood classifier was implemented in the pixel-based approach. Normalized difference vegetation index, normalized difference water index, mean value of the blue band and geometric characteristics were selected as features to distinguish macroalgae farms by considering the spectral and spatial characteristics. Results show that the object-based method achieved a higher overall accuracy and kappa coefficient than the pixel-based method. Moreover, the object-based approach displayed superiority in identifying Porphyra class. These findings suggest that the object-based method can delineate macroalgae farming areas efficiently and be applied in the future to monitor the macroalgae farms with high spatial resolution imagery.  相似文献   

广西城镇天气预报质量分析评估     

陆小玉  李佳颖  陈伟斌 《气象研究与应用》2019,40(1):99-103

根据全国城镇天气预报产品质量评估报告,从预报准确率和预报技巧评分上对2013-2017年广西城镇天气预报质量进行分析评估。结果表明:广西城镇天气预报24-72h最低温度预报准确率逐年提高,24-72h最高温度预报准确率稳步提升,24-72h晴雨预报和一般性降水预报准确率明显提升,24-72h暴雨和暴雨以上预报准确率保持稳定。24h晴雨、最低温度预报技巧评分较高,24h最高温度、一般性降水预报技巧评分波动较大,暴雨以上预报技巧评分较低。  相似文献   

降水现象仪观测应用评估   总被引：1，自引：0，他引：1  

杜传耀  尹佳莉  李林  伍永学  姜涛 《气象》2019,45(5):730-737

利用2017年9月至2018年8月北京20个站降水现象仪采集数据与人工平行观测数据,对降水现象仪进行了对比评估。结果表明:降水现象仪的缺测率为0.01%,空报率为0.6%,捕获率为93.5%,漏报率为27.9%,错报率为10.0%。从统计结果可知,降水现象仪的缺测率、空报率较低,捕获率较高,体现出设备性能良好的一面,漏报率和错报率偏高,表明设备漏识别和错误识别的情况较多,漏报主要发生在弱降水过程中,错报主要出现在毛毛雨的识别上。设备测量和人工观测降水开始时间一致性较好,终止时间一致性偏差;降水现象仪现存问题:在大雨强时易出现雨滴叠加误识别,在小雨强时识别率会降低,在无降水错误输出降水现象方面缺少质控。  相似文献   

Use of SPOT 5 and IKONOS imagery for mapping biocenoses in a Tunisian Coastal Lagoon (Mediterranean Sea)     

A. Vela  V. Pasqualini  V. Leoni  A. Djelouli  H. Langar  G. Pergent  C. Pergent-Martini  L. Ferrat  M. Ridha  H. Djabou 《Estuarine, Coastal and Shelf Science》2008,79(4):591-598

Mapping marine biocenoses is an efficient method for providing useful data for the management and conservation of Mediterranean lagoons. Fused images from two satellites, SPOT 5 and IKONOS, were tested as management tools for identifying specific ecosystems in the El Bibane lagoon, situated in southern Tunisia near the Libyan border. The objectives of this study were to provide a precise map of the entire El Bibane lagoon using fused images from SPOT 5 and to compare fused images from SPOT 5 and IKONOS over a test-area. After applying a supervised classification, pixels are automatically classified in four classes: low seagrass cover, high seagrass cover, superficial mobile sediments and deep mobile sediments. The maps of the lagoon revealed and confirmed an extremely wide distribution of seagrass meadows within the lagoon (essentially Cymodocea nodosa; 19 546 ha) and a large area of mobile sediments more or less parallel to the shore (3 697 ha). A direct comparison of overall accuracy between SPOT 5 over the entire area, SPOT 5 over the test-area and IKONOS over the test-area revealed that these tools provided accurate mapping of the lagoon environment (83.25%, 85.91% and 73.41% accuracy, respectively). The SPOT 5 images provided greater overall accuracy than the IKONOS image, but did not take into account the heterogeneous spatial structure of the seagrasses and sediments present in the lagoon environment. Although IKONOS imagery provided lower overall accuracy than SPOT 5, it proved a very useful tool for the mapping of heterogeneous structures as it enabled the patchiness of formations to be better taken into account. The use of SPOT 5 and IKONOS fused images appears to be very promising for completing the mapping of lagoons in other regions and countries of the Mediterranean Sea.  相似文献   

SPOT影像光束法平差复共线性消除          下载免费PDF全文

岳庆兴  马福诚  邱振戈  张春玲 《海洋测绘》2008,28(2):17-20

CCD卫星影像空间后方交会时,存在系数矩阵列向量间的强相关的问题,用光束法平差同样存在这个问题,将光束法平差与线角元素分求法、广义岭估计、附有限制条件的平差结合,证实三种方法都可以克服平差时外元素和变率改正数震荡大的缺点,并且取得了合理的空间后方交会精度和地面点定位精度。  相似文献   

航空矢量重力测量中科里奥利加速度对测速精度要求分析          下载免费PDF全文

王丽红  张传定 《海洋测绘》2008,28(2):1-4

首先论述了航空矢量重力测量中科里奥利加速度的计算模型,给出了科里奥利加速度改正对水平、垂直速度要求的分析模型。数值表明,在低纬地区欲达到1mGal的科里奥利加速度的精度,要求速度的精度为5cm／s左右;依据实测数据,目前GPS测得的载体速度精度为0．3mm／s,完全能够满足航空矢量重力测量对科里奥利加速度改正的要求。  相似文献   

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陈正宇  刘春 《大地测量与地球动力学》2008,28(1):92-95

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VRS RTK在地籍测量中的应用与研究   总被引：1，自引：0，他引：1  

赵俊义  毛钧 《测绘与空间地理信息》2009,32(1)

为了解决地籍测量外业要求时间短、精度较高等技术问题,在理论研究的基础上,在某市城区采用了VRS RTK技术建立测量控制网.通过成果分析得知.由于基于载波相位的GPS相对定位具有较高精度,只要控制网变形可以忽略或者进行建模,则不需要进行相邻控制点的联测,因此布设VRS RTK是非常适合的,减少了传统控制网埋石造标工作量.在RTK多测站解算中,建立了由电离层、对流层和卫星轨道引起的GPS观测误差在空间和时间的相关模型,得出在人口密集或重要经济地区布设局域GPS网的设计与测量模式.  相似文献