Speciation of sulfate components in size-fractionated aerosol particles using sulfur K-edge X-ray absorption near-edge structure （XANES）     

Yoshio Takahashi Yutaka Kanai Hikari Kamioka Atsuyuki Ohta Takuro Miyoshi Hiroshi Shimizu 《中国地球化学学报》2006,25(B08):222-222

Sulfates are a main constituent of aerosols, which sulfate aerosols, it is necessary to determine what can cause various environmental problems sulfate ions are contained in these aerosols In the evaluation of the influence of In this study, sulfur K-edge XANES was used to determine sulfate species present in size-fractionated aerosol particles based on the post-edge structure after the main absorption peak in the XANES region. Aerosol samples were collected as part of the Japan-China joint project, ＂Asian Dust Experiment on Climate Impact＂ using a low-volume Andersen-type air sampler. XANES was measured at Beamline BL-9A at Photon Factory, Japan. A comparison of the XANES spectra of reference sulfate materials and aerosol samples collected in Tsukuba in Japan clearly showed that （NH4）2SO4 was the main sulfur species in particles with a smaller diameter and gypsum was the main sulfur species in particles with a larger diameter. A simulation of the XANES spectra by reference materials allows us to obtain the quantitative mixing ratios of the different sulfate species present in the aerosol samples. The presence of minor sulfur species other than （NH4）2SO4 and gypsum at the surface of mineral aerosols is suggested in our simulations and by a surface-sensitive conversion electron/He-ion yield XANES. In the absence of a contribution from a large dust event, the mole concentration of gypsum in the mineral aerosol fraction determined by XANES is similar to that of Ca which is determined independently using ion chromatography. This shows that the Ca and sulfate in the mineral aerosols are present only as gypsum. Considering that calcite is the main Ca mineral in the original material arising from an arid and semi-arid area in China, it is strongly suggested that gypsum is formed in aerosol during its long-range transportation by a reaction between calcite and sulfate ions.  相似文献   

Naturally acidic and metalliferous waters at unmined volcanogenic massive sulfide deposits in the Bonnifield mining district, Alaska Range, east-central Alaska     

Robert G. Eppinger Paul H. Briggs Cynthia Dusel-Bacon Stuart A. Giles Larry P. Gough Jane M.Hammarstrom Bernard E. Hubbard 《中国地球化学学报》2006,25(B08):232-232

The Bonnifield district hosts 26 tmmined volcanogenic massive sulfide （VMS） occurrences. Environmental geochemical samples of water and stream sediment were collected at several occurrences, concentrating on the two best-exposed and largest deposits, Red Mountain （RM） and Sheep Creek （SC）. Limited samples were also collected at the poorly exposed WTF deposit. The deposits are Late Devonian to Early Mississippian, and are hosted by felsic metavolcanic and carbonaceous schist members of the Totatlanika Schist or Keevy Peak Fm. Spring and stream waters at RM and SC have pH values commonly 〈3.5 （as low as 2.4 at RM and 2.5 at SC）, high conductivity （up to 11000 μS/cm）, and very high （Is to 100s mg/L） dissolved contents of Al, Cd, Co, Cu, Fe, Ni, and Pb. Waters at RM are characterized by extremely high REE contents （summed REE median 3200 μg/L, n=33）. At both RM and SC, pyrite oxidation and dissolution produce low pH waters that interact with and dissolve bedrock minerals, resulting in acidic, metal-laden, naturally degraded streams that are mostly devoid of aquatic life. Ferricrete is common. In contrast, WTF barely produces a surficial environmental footprint, mostly due to topography and relief. RM and SC are well exposed in the areas of relatively high relief, and both exhibit extensive areas of quartz-sericite-pyrite-alteration. While WTF shares many of the same deposit-and alteration characteristics, it is concealed by tundra in a large, nearly flat area. Surface water at WTF is absent and outcrops are sparse. Even though WTF is roughly the same size as Red Mountain （both around 3 million tonnes） and has similar base- and precious-metal grades, the surficial geochemical manifestation of WTF is minimal. However, exposure through mining of the altered, mineralized rock at WTF potentially could initiate the same processes of pyrite oxidation, acid generation, and mineral dissolution that are observed naturally at RM and SC.  相似文献   

“地震与火山”公开课后的启示     

钱文群 《地理教学》2006,(12):20-21

在波澜起伏的教改浪潮中，我尝试开设了“地震与火山”这堂公开课。在备课过程中查寻整理资料、制作修改课件、设计创立课堂流程，自然化了不少心思，然而作为教师的我，在这一过程中所学到的远不止课程本身或其所涉及到的相关领域知识、能力。几次“模拟演习”师生都能按事先设计好的环节逐一展开，当时我感到自然、流畅、顺利，然而在有众多领导、专家、教师在场的公开课堂上，学生、课堂带给我的却是另外一种东西，那是一种感动、一种启示，甚至是一种震撼。课后我及时与学生交流沟通，我想用字表达一下几个方面的感想与启示。  相似文献   

东准噶尔纸房地区晚石炭世巴塔玛依内山组陆相火山-沉积体系特征   总被引：24，自引：0，他引：24  

朱志新  李少贞  李嵩龄 《新疆地质》2005,23(1):14-18

东准噶尔巴塔玛依内山组是典型陆相火山．沉积体系(盆地)，主体由基性及中酸性火山熔岩组成，火山碎屑岩及火山碎屑沉积岩较少，通过对纸房地区晚石炭世巴塔玛依内山组陆相火山岩的岩石化学、地球化学特征进行系统研究，认为它属于造山期后固结初期，新陆壳裂谷向高原火山岩演化的同岩浆源、同沉积盆地、同火山作用的钙碱系列双峰式火山岩．  相似文献   

伊宁吐拉苏火山盆地热液活动与金成矿关系     

漆树基  安其桂  伊发源 《新疆地质》2005,23(4):351-354

吐拉苏火山盆地中与金成矿有关的热液富含K^＋、Na^＋、F、SO4^2-和N2、O2等，是一种主要来源于岩浆．火山的热液，有大气水参于的次生热液．平均均一温度96～158℃，平均盐度0．26％～1．08％，热液活动深度0．26～0．67km，具有低温、低盐度、在地壳浅部活动的基本特征．热液活动生成围绕金矿体由内向外环状展布的黄英岩化、高级泥化、泥化和绿泥石碳酸盐化4个围岩蚀变带．与其有关的金成矿期分为原生沉积富集和次生热液交代蚀变2期，后者包括毒砂黄铁矿化、面状硅化、脉状硅化和绿泥石碳酸盐化4个成矿阶段．金富集成矿主要与黄英岩化蚀变带和面状硅化、脉状硅化2个成矿阶段密切相关．  相似文献   

北京晴天紫外波段气溶胶光学厚度反演与分析   总被引：4，自引：1，他引：4  

刘新罡  吕达仁  肖稳安  刘春田  屈玉 《南京气象学院学报》2005,28(1):51-57

利用太阳一大气紫外光谱辐射计(SAUVS)，测量到达北京地表的太阳直接和散射紫外光谱辐射，给出反演大气气溶胶光学厚度的一种方法。结果表明：在紫外波段，大气气溶胶的光学厚度随波长的增加而单调减小，用指数函数可以很好地拟合反演结果。统计得到了3个水平能见度状况下拟合函数的系数值，与全球气溶胶监测网络(AERONET)北京站的资料对比，表明反演结果基本合理。  相似文献   

城市环境气象的研究进展   总被引：2，自引：0，他引：2  

陈碧辉李跃清  闵文彬罗磊 《四川气象》2005,25(2):27-29

重点介绍了国内外对城市热岛的研究现状和研究成果。简单介绍了绿化对改善城市热环境的研究成果。目前城市气象服务中的气象指标以及城市灾害性天气监测中存在的不足。总结了城市气候研究的热点为城市热环境和大气气溶胶，指出了利用数值模拟研究气溶胶气候效应是今后发展的趋势。  相似文献   

中国北方地区春季气溶胶光学特性地基遥感研究   总被引：12，自引：1，他引：12  

夏祥鳌  王普才  陈洪滨  PhilippeGoulou  章文星 《遥感学报》2005,9(4):429-437

基于中国北方地区地基太阳直接/散射辐射计观测,分析了2001年春季气溶胶光学厚度、尺度和吸收特性。沙尘期间,气溶胶光学厚度显著升高,而尺度上升,粗粒子浓度显著增加,大气气溶胶表现出中性或异常消光特征。除沙尘活动之外,中国华北地区人为排放也是导致气溶胶光学厚度偏高的一个重要原因。中国沙尘源区气溶胶单次散射反照率小于以往观测和模式结果。北京和香河两地气溶胶光学厚度、Angstrom指数和尺度谱基本相似,说明华北地区人为排放与沙尘活动类似,也表现出区域尺度的特点。由于沙尘气溶胶与人为排放气溶胶相比,折射指数实部偏大、虚部偏小,从而北京地区沙尘期间单次散射反照率明显大于非沙尘期间,特别是在近红外波段,说明沙尘活动不仅可以通过增加气溶胶光学厚度,同时也通过改变气溶胶物理、辐射特性来影响下游地区的气溶胶辐射强迫。  相似文献   

海盐气溶胶和硫酸盐气溶胶在云微物理过程中的作用   总被引：14，自引：2，他引：14       下载免费PDF全文

赵春生  彭大勇段英 《应用气象学报》2005,16(4):417-425

利用大气气溶胶和云分档模式研究海盐气溶胶和硫酸盐气溶胶在云微物理过程中的作用, 计算结果表明:云中液态水含量随高度的分布并不随海盐、硫酸盐的数目以及云团上升速度的变化而变化; 随着云滴数目的增加, 云滴的有效半径会减小; 硫酸盐对云滴数目影响起主导作用, 海盐在水汽相对充足情况下增加了云滴数目, 在水汽相对不足的情况下减少了云滴数目; 硫酸盐粒子浓度特别强的情况下 (人类活动污染比较严重时), 如果水汽相对不足, 云滴数目会明显小于硫酸盐粒子浓度; 而海盐粒子的存在, 加剧了水汽的供应不足, 从而可以在很大程度上进一步降低云滴数目。也就是说, 在有些情况下, 如果不考虑海盐气溶胶的作用, 硫酸盐气溶胶对云特性的影响会被过高估计。  相似文献   

双差分激光雷达——一组可以提高臭氧测量精度的波长   总被引：1，自引：0，他引：1  

胡顺星  胡欢陵  周军  吴永华 《气象学报》2002,60(4):486-493

模拟了气溶胶影响三波长双差分 (2 6 6 - 2 89- 30 8nm)方法和双波长差分 (2 6 6 - 2 89nm和 2 6 6 - 30 8nm)方法测量对流层臭氧的误差 ,并在合肥测量了对流层 2～ 3.6km高度的臭氧分布。结果表明 ,三波长双差分方法比常规的双波长差分方法能更有效地克服气溶胶的影响 ,三波长差分测量的结果比常规的双波长差分的结果更精确。同时还揭示了气溶胶影响双波长差分方法测量臭氧的规律。模拟结论与测量结果是一致的  相似文献