The ANICE (Atmospheric Nitrogen Inputs into the Coastal Ecosystem) project addressed the atmospheric deposition of nitrogen to the North Sea, with emphasis on coastal effects. ANICE focused on quantifying the deposition of inorganic nitrogen compounds to the North Sea and the governing processes. An overview of the results from modelling and experimental efforts is presented. They serve to identify the role of the atmosphere as a source of biologically essential chemical species to the marine biota. Data from the Weybourne Atmospheric Observatory (UK) are used to evaluate the effect of short episodes with very high atmospheric nitrogen concentrations. One such episode resulted in an average deposition of 0.8 mmol N m−2 day−1, which has the potential to promote primary productivity of 5.3 mmol C m−2 day−1. This value is compared to long-term effects determined from model results. The total calculated atmospheric deposition to the North Sea in 1999 is 948 kg N km−1, i.e. 0.19 mmol N m−2 day−1 which has the potential to promote primary productivity of 1.2 mmol C m−2 day−1. Detailed results for August 1999 show strong gradients across the North Sea due to adjacent areas where emissions of NOx and NH3 are among the highest in Europe. The average atmospheric deposition to the southern part of the North Sea in August 1999 could potentially promote primary production of 2.0 mmol C m−2 day−1, i.e. 5.5% of the total production at this time of the year in this area of the North Sea. For the entire study area the atmospheric contribution to the primary production per m2 is about two-third of this value. Most of the deposition occurs during short periods with high atmospheric concentrations. This atmospheric nitrogen is almost entirely anthropogenic in origin and thus represents a human-induced perturbation of the ecosystem. 相似文献
A geochronological study of the Filicudi, Salina, Lipari and Vulcano Islands (Aeolian Archipelago) using the unspiked potassium2013;argon technique provides new age data which, combined with stratigraphic correlation, better constrain the temporal evolution of volcanism. The unspiked K2013;Ar age of the oldest exposed lavas on Filicudi, 219±5 ka, is significantly younger than the previous estimation of 1.02 Ma. In the general context of Aeolian volcanism, this new date suggests that the volcanism of the western sector of the Aeolian Archipelago is younger than previously thought. Geochronological data point out on the rapid transition from calc2013;alkaline to potassic volcanism. The distribution of the K2013;Ar ages within the Salina2013;Lipari2013;Vulcano group shows that the volcanism started on Lipari and propagated over time northward on Salina and southward on Vulcano. Geochronological and geophysical data suggest that the onset of volcanism in the central sector of the Aeolian Arc may be due to a mantle upwelling structure located below Lipari. A change in the style of the eruptions occurred in the Salina2013;Lipari2013;Vulcano system at about 100 ka from the present. Low-energy magmatic eruptions occurred between 188 and about 100 ka. From about 100 ka to the present, higher-energy eruptions and low-energy events due to magma2013;water interaction also occurred. This change in the style of activity, together with the appearance of evolved products (i.e. rhyolites) during the last 50 ka, is consistent with the formation of magmatic reservoirs located at shallower depth with respect to those of the 1882013;100-ka period. The new geochronological data and available petrological models reveal that a change in the deep source of the primary magmas occurred in a relatively short time interval. 相似文献
The methodology for dealing with spatial variability of ground motion, site effects and soil–structure interaction phenomena in the context of inelastic dynamic analysis of bridge structures, and the associated analytical tools established and validated in a companion paper are used herein for a detailed parametric analysis, aiming to evaluate the importance of the above effects in seismic design. For a total of 20 bridge structures differing in terms of structural type (fundamental period, symmetry, regularity, abutment conditions, pier‐to‐deck connections), dimensions (span and overall length), and ground motion characteristics (earthquake frequency content and direction of excitation), the dynamic response corresponding to nine levels of increasing analysis complexity was calculated and compared with the ‘standard’ case of a fixed base, uniformly excited, elastic structure for which site effects were totally ignored. It is concluded that the dynamic response of RC bridges is indeed strongly affected by the coupling of the above phenomena that may adversely affect displacements and/or action effects under certain circumstances. Evidence is also presented that some bridge types are relatively more sensitive to the above phenomena, hence a more refined analysis approach should be considered in their case. Copyright @ 2003 John Wiley & Sons, Ltd. 相似文献
This paper first reports a high precision U2013;Pb age of 218±1.2 Ma for rutile in coesite-bearing eclogite from Jinheqiao in the Dabie Mounteins, east2013;central China. This work shows that the U2013;Pb mineral (rutile+omphacite) isochron age of 218±2.5 Ma and conventional rutile U2013;Pb concordia age of 218±1.2 Ma obtained by common Pb correction based on the Pb isotopic composition of omphacite in the same eclogite sample are consistent, proving that the omphacite with low U/Pb ratio (μ=2.8) can be used for common Pb correction in U2013;Pb dating of rutile. Oxygen isotope analysis of rutile aliquots gave the consistent δ18O values of −6.1±0.1%, demonstrating oxygen isotope homogenization in the rutile of different grains as inclusion in garnet and grain in matrix. Oxygen isotope thermometry yields temperatures of 695±35 and 460±15 °C for quartz2013;garnet and quartz2013;rutile pairs, respectively. These oxygen isotopic observations suggest that the diffusion of oxygen in rutile as inclusion in garnet is not controlled by garnet. According to field-based thermochronological studies of rutile, an estimate of the Tc of about 460 °C for U2013;Pb system in rutile under rapid cooling conditions (20 °C/Ma) was advised. Based on this U2013;Pb age as well as the reported chronological data with their corresponding metamorphic and/or closure temperature, an improved T2013;t path has been constructed. The T2013;t path confirms that the UHPM rocks in South Dabie experienced a rapid cooling following the peak metamorphism before 220 Ma and a long isothermal stage from 213 to 180 Ma around 425 °C. 相似文献
Accidental spills of hydrocarbons, such as Light Non-Aqueous Phase Liquids (LNAPLs), are one of the most common sources of subsurface contamination. Migration of LNAPL in a porous medium is influenced by various factors such as the number of fluids present in the unsaturated/saturated zones and the proportion of pores occupied by each fluid. The results for relationship between matric suction and degree of saturation are presented in this paper for water2013;air, water2013;LNAPL and LNAPL2013;air systems in a sand. A simple and reliable setup using Buchner funnel was designed to obtain these relations. It was found that the relationship between matric suction head and degree of saturation is hysteretic for all the fluid systems (water2013;air, water2013;LNAPL and LNAPL2013;air). Furthermore, the amount of hysteresis depended upon the fluid system, with the maximum hysteresis occurring for water2013;air system. The results suggest that the amount of trapped air depends upon the reversal degree of saturation from drying to wetting. 相似文献
The Dulan eclogite2013;gneiss region is located in the eastern part of the North Qaidam eclogite belt, NW China. Widespread evidence demonstrates that this region is a typical ultrahigh-pressure (UHP) metamorphic terrane. Eclogites occur as lenses or layers in both granitic and pelitic gneisses. Two distinguished sub-belts can be recognized and differ in mineralogy, petrology and geochemistry. The North Dulan Belt (NDB) has tholeiitic protoliths with high TiO2 and lower Al2O3 and MgO contents. REE patterns and trace element contents resemble those of N-type and E-type MORB. In contrast, eclogites in the South Dulan Belt (SDB) are of island arc protoliths with low TiO2, high Al2O3 and show LREE-enriched and HFSE-depleted patterns. Sm2013;Nd isotope analyses give isochron ages of 4582013;497 Ma for eclogite-facies metamorphism for the two sub-belts. The ages are similar to those of Yuka and Altun eclogites in the western extension of the North Qaidam-Altun eclogite belt. The Dulan UHP metamorphic terrane, together with several other recently recognized eclogite-bearing terrenes within the North Qaidam-Altun HP-UHP belt, constitute the key to the understanding of the tectonic evolution of the northern Tibetan Plateau. The entire UHP belt extends for more than 1000 km from the Dulan UHP terrane in the southeast to the Altun eclogite2013;gneiss terrane in the west. This super-belt marks an early Paleozoic continental collision zone between the Qaidam Massif and the Qilian Massif. 相似文献
Minor granulites (believed to be pre-Triassic), surrounded by abundant amphibolite-facies orthogneiss, occur in the same region as the well-documented Triassic high- and ultrahigh-pressure (HP and UHP) eclogites in the Dabie2013;Sulu terranes, eastern China. Moreover, some eclogites and garnet clinopyroxenites have been metamorphosed at granulite- to amphibolite-facies conditions during exhumation. Granulitized HP eclogites/garnet clinopyroxenites at Huangweihe and Baizhangyan record estimated eclogite-facies metamorphic conditions of 7752013;805 °C and ≥15 kbar, followed by granulite- to amphibolite-facies overprint of ca. 7502013;800 °C and 62013;11 kbar. The presence of (Na, Ca, Ba, Sr)-feldspars in garnet and omphacite corresponds to amphibolite-facies conditions. Metamorphic mineral assemblages and P2013;T estimates for felsic granulite at Huangtuling and mafic granulite at Huilanshan indicate peak conditions of 850 °C and 12 kbar for the granulite-facies metamorphism and 700 °C and 6 kbar for amphibolite-facies retrograde metamorphism. Cordierite2013;orthopyroxene and ferropargasite2013;plagioclase coronas and symplectites around garnet record a strong, rapid decompression, possibly contemporaneous with the uplift of neighbouring HP/UHP eclogites.
Carbonic fluid (CO2-rich) inclusions are predominant in both HP granulites and granulitized HP/UHP eclogites/garnet clinopyroxenites. They have low densities, having been reset during decompression. Minor amounts of CH4 and/or N2 as well as carbonate are present. In the granulitized HP/UHP eclogites/garnet clinopyroxenites, early fluids are high-salinity brines with minor N2, whereas low-salinity fluids formed during retrogression. Syn-granulite-facies carbonic fluid inclusions occur either in quartz rods in clinopyroxene (granulitized HP garnet clinopyxeronite) or in quartz blebs in garnet and quartz matrices (UHP eclogite). For HP granulites, a limited number of primary CO2 and mixed H2O2013;CO2(liquid) inclusions have also been observed in undeformed quartz inclusions within garnet, orthopyroxene, and plagioclase which contain abundant, low-density CO2±carbonate inclusions. It is suggested that the primary fluid in the HP granulites was high-density CO2, mixed with a significant quantity of water. The water was consumed by retrograde metamorphic mineral reactions and may also have been responsible for metasomatic reactions (“giant myrmekites”) occurring at quartz2013;feldspar boundaries. Compared with the UHP eclogites in this region, the granulites were exhumed in the presence of massive, externally derived carbonic fluids and subsequently limited low-salinity aqueous fluids, probably derived from the surrounding gneisses. 相似文献