Complexation of mercury by dissolved organic matter in surface waters of Galveston Bay, Texas   总被引：3，自引：0，他引：3  

Seunghee Han  Gary A. Gill  Ronald D. Lehman  Key-Young Choe 《Marine Chemistry》2006,98(2-4):156-166

The chemical speciation of dissolved mercury in surface waters of Galveston Bay was determined using the concentrations of mercury-complexing ligands and conditional stability constants of mercury-ligand complexes. Two classes of natural ligands associated with dissolved organic matter were determined by a competitive ligand exchange-solvent solvent extraction (CLE-SSE) method: a strong class (L_s), ranging from 19 to 93 pM with an average conditional stability constant (K_HgLs) of 10²⁸, and a weak class (L_w) ranging from 1.4 to 9.8 nM with an average K_HgLs of 10²³. The range of conditional stability constants between mercury and natural ligands suggested that sulfides and thiolates are important binding sites for dissolved mercury in estuarine waters. A positive correlation between the estuarine distribution of dissolved glutathione and that of mercury-complexing ligands supported this suggestion. Thermodynamic equilibrium modeling using stability constants for HgL, HgCl_x, Hg(OH)_x, and HgCl(OH) and concentrations of each ligand demonstrated that almost all of the dissolved mercury (> 99%) in Galveston Bay was complexed by natural ligands associated with dissolved organic matter. The importance of low concentrations of high-affinity ligands that may originate in the biological system (i.e., glutathione and phytochelatin) suggests that the greater portion of bulk dissolved organic matter may not be important for mercury complexation in estuarine surface waters.  相似文献   

Nutrient dynamics and seasonal succession of phytoplankton assemblages in a Southern European Estuary: Ria de Aveiro, Portugal   总被引：2，自引：1，他引：2  

C.B. Lopes  A.I. Lilleb  J.M. Dias  E. Pereira  C. Vale  A.C. Duarte 《Estuarine, Coastal and Shelf Science》2007,71(3-4):480-490

The spatial and temporal dynamics of dissolved inorganic nitrogen, dissolved phosphate, dissolved silica and chlorophyll a were measured seasonally at eight stations in the Ria de Aveiro. Between December 2000 and September 2001, the seasonal succession of phytoplankton assemblages, inferred after the spatial and seasonal variation of silica and of chlorophyll a concentrations, showed that diatoms (μmol Si L⁻¹) dominated from late autumn until early spring, while chlorophytes (μg Chl a L⁻¹) bloomed during late spring and summer. The Si:N:P ratios and Si concentrations indicated no seasonal depletion in dissolved silica, as in other temperate systems, possibly because of abnormal precipitation and flood events prolonging the supply of dissolved Si to the system. The Si:N:P ratios suggested P limitation at the system level. Despite the relative proportions of available nutrients, the mean phosphorus concentration (5.3 μmol L⁻¹) was above the reported half-saturation constants for P uptake by phytoplankton. Thus, in Ria de Aveiro, the seasonal succession of phytoplankton assemblages may also be dependent on the grazing capacity of the pelagic community through top-down regulation.  相似文献   

Grey Prediction of Siltation in North Channel of Yangtze Estuary     

Yu Cimei Shanghai Waterways Design & Research Institute  Shanghai 《中国海洋工程》1994,(2)

-The North Channel in the Yangtze Estuary is one of sea-leading waterways of Shanghai Harbour, in which yearly dredging volume reaches over ten million cubic meters, and it tends to increase year by year. Based on the channel regime similarity and through the relational grade, a GM (2, 1) is set up. It reveals the course of development of channel regime similarity under the action of various factors, and predicts the siltation volume in the nearest future which is the basis of dredging planning for relevant dredging departments.  相似文献   

Prediction of Load Carrying Capacity of Corroded Reinforced Concrete Beam     

范颖芳  周晶冯新 《中国海洋工程》2004,18(1):107-118

A novel method for prediction of the load carrying capacity of a corroded reinforced concrete beam (CRCB) is presented in the paper. Nine reinforced concrete beams, which had been working in an aggressive environment for more than 10 years, were tested in the laboratory. Comprehensive tests, including flexural test, strength test for corroded concrete and rusty rebar, and pullout test for bond strength between concrete and rebar, were condueted. The flexural test results of CRCBs reveal that the distribution of surface cracks on the beams shows a fractal behavior. The relationship between the fractal dimensions and mechanical properties of CRCBs is then studied. A prediction model based on artificial neural network (ANN) is established by the use of the fractal dimension as the corrosion index, together with the basic intbrmation of the beam. The validity of the prediction model is demonstrated through the experimental data, and satisfactory resuits are achieved.  相似文献   

刀额新对虾染色体核型及细胞核DNA含量   总被引：9，自引：0，他引：9  

张晓军  周岭华  相建海 《海洋与湖沼》2002,33(3):225-231

以刀额新对虾胚胎、无节幼体、卵巢、精巢等为材料 ,空气干燥法制备染色体 ,并初步进行核型分析。结果表明 ,刀额新对虾的染色体数目为 2n=78,n =39,核型为 2n=78=40M 1 0SM 1 4ST 1 4T。以刀额新对虾血淋巴、卵巢、肌肉、鳃为材料 ,以鸡血细胞为DNA标准 (2 50pg/ 2c) ,使用PartecCCAⅡ型流式细胞仪测定了刀额新对虾细胞的基因组DNA含量 ,其值为鸡血细胞的 1 75倍 ,绝对含量为 4 375pg/ 2c。  相似文献   

台风移速突变的诊断分析及路径预报     

仲荣根 《海洋湖沼通报》1994,(2):149-154

本文利用台风移动方程对作用在台风上的各力进行了诊断分析：主要力是气压梯度力和地转偏向力，二者同量级，其他各力约小１－３个量级；当台风加速移动时，气压梯度力小于地转编向力；减速移动时，气压梯度力大于地转偏向力。用预报方程计算得到的台风路径与实际台风路径在趋势上近于一致，预报误差约为２００ｋｍ。  相似文献   

沉降监测多项式回归分析与神经网络预测     

田丰  文鸿雁  张静 《海洋测绘》2007,27(4):23-27

使用多项式和切比雪夫(Tchebyshev)多项式分别对沉降监测数据进行回归分析以预测未来沉降值,其中切比雪夫多项式的外推效果较好;应用前向BP神经网络对两种不同的单因子输入模式进行非线性函数逼近,并进行了不同采样步长的比较,实例表明将时间点作为网络的输入对沉降进行预测效果较好。  相似文献   

Modelling the timing of plankton production and its effect on recruitment of cod (Gadus morhua)     

Brander  K. M.; Dickson  R. R.; Shepherd  J. G. 《ICES Journal of Marine Science》2001,58(5):962-966

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基于模糊神经网络(FNN)的赤潮预警预测研究   总被引：1，自引：0，他引：1  

张容  阎红  杜丽萍 《海洋通报(英文版)》2006,8(1):83-91

为研究各种理化因子与赤潮藻类浓度间的非线性对应规律和有效预测赤潮藻类浓度,构建了基于BP 算法的一个四层模糊神经网络模型。将模糊神经网络(FNN)技术引入赤潮预测研究,并与普通 BP 网络、RBF 网络的结果作比较,结果表明,该模型能够较好地反演出各种理化因子与夜光藻密度的非线性对应变化规律,有更好的预测功能。  相似文献   

Indirect economic indicators in bio-economic fishery models: agricultural price indicators and fish stocks in Lake Victoria   总被引：2，自引：0，他引：2  

Simonit  Silvio; Perrings  Charles 《ICES Journal of Marine Science》2005,62(3):483-492

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