Speciation and role of iron in cloud droplets at the puy de Dôme station     

Marius Parazols  Angela Marinoni  Pierre Amato  Otman Abida  Paolo Laj  Gilles Mailhot 《Journal of Atmospheric Chemistry》2006,54(3):267-281

Iron is the most abundant transition metal in the atmosphere and can play a significant role in cloudwater chemistry where its reactivity is closely related to the partitioning between Fe(II) and Fe(III). The objective of this work is to determine the total iron content and the iron speciation in a free tropospheric site, and to understand which factors influence these parameters. We collected 147 samples of cloudwater during 34 cloud events over a period of four years at the puy de Dôme summit. Besides iron we measured other chemical compounds, solar radiation, physico-chemical and meteorological parameters potentially connected with iron reactivity. The total iron concentrations ranged from 0.1 to 9.1 μM with the major frequency occurring at low levels. The pH and presence of organic complexants seem to be the most significant factors connected with total dissolved iron; while the iron oxidation state seems to be an independent factor. Light intensity, presence of complexants or oxidants (H₂O₂) do not influence the Fe(II)/Fe(Total) ratio, that was quite constant at about 0.75. This could be due to the potential redox that forces the Fe(II)-Fe(III) couple to the reduced form or, more probably to the complexation by Natural Organic Matter, that can stabilize iron in its reduced form and prevent further oxidation. Our field measurements did not show the diurnal cycle observed in surface water and predicted by models of atmospheric chemistry. This result prompts a more careful review of the role of iron and, by analogy, all the transition metals in atmospheric liquid phase, often over-estimated in the literature.  相似文献   

2维DLT变换用于建筑物变形监测的试验研究     

赵卿  尹晖 《测绘与空间地理信息》2006,29(6):17-19

直接线性变换(D irect LinearTransformation)解法是建立观测点像方空间坐标和同名点物方空间坐标之间直接线性关系的算法。本次试验通过使用普通数码相机,并应用2维直接线性变换进行了建筑物变形监测的试验研究,试验结果表明,使用普通数码相机代替常规测量方法能够满足变形监测三等精度要求。  相似文献   

Detection of model voids by identifying reverberation phenomena in GPR records   总被引：2，自引：1，他引：2  

Lev Kofman  Amit Ronen  Sam Frydman   《Journal of Applied Geophysics》2006,59(4):284-299

In order to improve the reliability of the ground penetrating radar (GPR) method in identifying subsurface sinkholes and karst cavities, laboratory investigations have been performed. The main objective of this work was to examine the relationship between horizontal/vertical voids dimensions and wavelengths of various antennas, and the corresponding GPR responses. Emphasis was given to the investigation of the factors that cause the appearance of reverberation phenomena in the signal pattern.The tests were conducted in 5 m × 10 m area by 2-m-deep trench filled with homogenous, dry sand. The voids models (empty fiberglass cylinders in diameters of 0.6 m, 1.0 m, 1.5 m and 2.4 m, with various heights) were buried vertically with their tops at depths of between 0.7 and 1.5 m. Investigations were performed for the various model conditions by towing 500, 300 and 100 MHz antennas along a pre-established grid, for the various model conditions.The GPR data collected using the 500 MHz bistatic antenna above the 1.0-m- and the 1.5-m-diameter cylinders, and using the 300 MHz bistatic antenna above the 1.5-m-diameter cylinder, confirmed the presence of a reverberation phenomenon, i.e. a strong convex signal pattern, containing a series of high amplitude extending oscillations with reduced frequency.Based on past practical GPR experience of void detection and presently obtained experimental data, two rules of thumbs may be adopted for the prediction of the appearance of resonant radar pictures:

1. The void diameter larger than the wavelength in air of the antenna used.

2. The vertical size of the empty void not significantly smaller than its horizontal dimension.

The strong reverberations generated by the inner surface of the void targets were found to approximate standing waves generated in cylindrical waveguides and waveguide resonators. The theoretical, experimental and practical results obtained concur.  相似文献   

地震学在减轻矿山地质灾害中的应用进展   总被引：10，自引：1，他引：10  

李世愚  和雪松  张天中  王林瑛  许忠淮  陆其鹄  陈佩燕  沈萍  张少泉  蒋秀琴  潘科  佟晓辉  宋绪友  李铁  金贵杰  左艳  管恩福  孙学会  李国宏  吕毓国 《国际地震动态》2006,(4):1-9

综述了煤矿安全对于地球物理应用的需求,以及近年来地震学在煤矿减轻地质灾害的应用进展,特别是微震监测分析在若干典型煤矿应用得到的初步成果。这些成果不但对于煤矿安全具有重要意义,而且对于认识构造地震成因和验证预测方法,也具有中尺度试验意义。  相似文献   

密闭体系与开放体系模拟实验结果的比较研究及其意义   总被引：3，自引：0，他引：3  

卢双舫  王民  王跃文  徐立恒  薛海涛  李吉君 《沉积学报》2006,24(2):282-288

利用广泛应用的高压釜和Rock Eval热解实验技术，对松辽盆地3个有机质样品同时进行了密闭条件下的加水恒温热解实验和开放条件下的恒速升温热解实验。利用后一实验数据所标定得到的化学动力学模型计算了与高压釜相同实验条件下的有机质产油、产气率。结果表明，在线计量的恒速升温Rock Eval实验方法由于不损失C6—C13的轻质烃组分，在计量液态油的产量方面较需要抽提、恒重的高压釜实验方法更为准确。因此为解决热模拟实验中难以计量、但对成烃评价有重要意义的C6—C13组分的计量问题提供了一条有效的途经。这可能也表明，先由实验数据建立有关的化学动力学模型，之后由它来进一步计算有机质的成烃率，不仅是可行的，而且应该更为准确。  相似文献   

Sandbox Experimental Study on the Influence of Rock Strength and Gravity on Formation of Thrusts     

魏春光  周建勋  何雨丹 《中国地质大学学报(英文版)》2006,17(1):43-48

INTRODUCTIONRock deformation is normally explained by tec-tonic stress as rock deformation results fromthe tec-tonic stress field. The classic tools that explainedfracture mechanisms were the Coulomb shear fracturerule and the Anderson mode derived fromit (Zhu,1999) . More and more studies have shown that it isdifficult to explain rock deformation in a large strainrange using only the Coulomb shear fracture rule( Waltham,2002 ; Gutscher et al .,2001 ; Tikoff andWojtal ,1999) . As a ver…  相似文献   

煤矸石浸泡污染物溶解释放规律研究--阜新市新邱露天煤矿不同风化煤矸石在不同固液比条件下浸泡实验   总被引：2，自引：0，他引：2  

肖利萍  梁冰  陆海军  毕业武  张传成  狄军贞 《中国地质灾害与防治学报》2006,17(2):151-155,163

论文对新邱露天矿不同风化程度的煤矸石在不同固液比条件下溶解释放污染物的规律进行了浸泡实验研究。结果表明:煤矸石溶解释放的主要污染物为总硬度(CaCO3)、硫酸盐(SO42-)、钠(Na )、总溶解性固体(TDS)、氟化物(F-)、耗氧量(OC)和总铁(Fe)等,氯化物(Cl-)、锰(Mn)、锌(Zn)等少量,其它重金属和砷等微量。pH值接近中性。煤矸石风化程度越高,溶解释放的无机盐类污染物量越多,新鲜混合煤矸石溶解释放出较高的氟化物(F-)、耗氧量(OC)和总铁(Fe);固液比对煤矸石中污染物的溶解释放有重要影响。固液比越小,浸泡液中污染物浓度越低,越有利于煤矸石中污染物的溶解释放,单位质量煤矸石溶解释放的污染物量越多,煤矸石中污染物的溶解释放规律受扩散控制;在同一固液比条件下,各污染物浓度变化与浸泡时间成对数曲线关系,即Ct=a bLogt。  相似文献   

小型多功能生态氡室的设计与研制     

张丽娇  张松川  刘庆成 《铀矿地质》2006,22(5):311-314

本文介绍了智能型测氡仪器标定装置——HD 5型多功能生态氡室的结构及氡浓度定值的计量过程,并分析了该氡室的性能指标。  相似文献   

THE APPLICATION OF HOMEMADE FY-2 SATELLITE INFRARED DATA TO MM5     

刘清  沈桐立 《热带气象学报(英文版)》2006,12(1):103-104

1 INTRODUCTIONIn the end of 1980’s, an operational system for 3-Dvariation and assimilation of meteorological data wasset up in the U.S.A that supplemented data assimilation,retrieval of satellite data and numerical prediction eachother. NWP was thus imp…  相似文献   

极冰气候效应的数值试验   总被引：1，自引：0，他引：1  

杨梅玉  刘屹岷  李骥 《气象学报》1998,56(4):476-484

利用一个大气环流模式（ＡＧＣＭ）和一个全球耦合海气模式（ＣＯＡＧＣＭ）,模拟了北极海冰边界范围的变化对月平均气候的影响。结果表明,极冰边缘的异常完全可以改变中高纬度某些地区的局地气候。受冷源的影响,北半球中高纬度冷高压加强,低纬度暖高压减弱。同时利用一个全球三维大气环流模式,作了海冰反照率参数化的数值试验,用两种不同的海冰反照率参数化方案,检验对地表面温度、海平面气压、极地表面对太阳辐射吸收的影响。模拟试验表明了冰雪圈反照率的反馈作用,对气候变化的影响十分重要。  相似文献