MCM-41/β介孔—微孔复合分子筛的合成、表征及催化性能     

王东青  魏静  于春梅  王锐  李宗奇 《东北石油大学学报》2013,37(3):100-104,129

以β分子筛为前驱体,水玻璃和硫酸铝为外加硅铝源,采用二元混合表面活性剂为结构导向剂,水热晶化合成MCM-41/β介孔—微孔复合分子筛,并利用XRD、SEM、TEM、N2吸附—脱附和Py-IR等对复合分子筛进行表征,以十氢萘为模型化合物考察复合样品的催化裂解反应性能.结果表明:MCM-41/β介孔—微孔复合分子筛中存在MCM-41分子筛六方介孔结构和β分子筛微孔结构,对十氢萘具有较强的催化反应活性,催化裂解转化率为93.16%.  相似文献   

Seepage response along an alluvial valley in a semi‐arid catchment in north‐central California     

Rohit Salve  Tetsu K. Tokunaga 《水文研究》2002,16(1):65-86

Over a period of 12 months, soil moisture content and potential was monitored in an annual‐grass‐dominated 20 ha catchment in order to determine flow paths leading to exfiltration at the catchment outlet. Water was found to enter the catchment valley either through flow originating in the slopes or through surface infiltration during rainfall events. Although subsurface flow from the slopes to the catchment outlet occurred throughout the year, surface recharge was restricted to a few events during the wet season. In the deeper saturated profile of the valley, flow was directed upwards along the valley edges and gradually became horizontal towards the central axis of the valley. During the peak of the rainfall season, horizontal flow close to the catchment outlet intercepted the gradually sloping surface, resulting in exfiltration. Plants influenced the hydrology of the catchment by removing moisture from the root zone during spring and early summer, resulting in evapotranspiration losses from the vadose zone. Heterogeneities within the valley soil were evident as variable‐permeability layers that resulted in a seasonally confined water table within the valley. This investigation shows that the vadose zone plays an important role in redistributing surface recharge and emphasizes the importance of accounting for effective moisture in low‐yielding catchments with ephemeral surface runoff. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

Controls on P–T–t deformation path from amphibole zonation during progressive metamorphism of basic rocks (estuary of the River Vilaine, South Brittany, France)     

Cl. TRIBOULET  Cl. AUDREN 《Journal of Metamorphic Geology》1988,6(2):117-133

Abstract Edenite/tremolite and edenite/magnesio-hornblende in equilibrium with plagioclase, chlorite, epidote, quartz and vapour involve several types of reactions for which K _D can be related to T and P. Thermodynamic calculation of these equilibria leads to isopleth systems. Given knowledge of the progressive changes of end-member activities in zoned Ca–Mg amphiboles (based on microprobe analyses), it is possible to construct precise pressure–temperature–time paths ( P–T–t paths) which have been followed by metabasites during polyphase metamorphism. When applied to basic rocks from the River Vilaine area, this method allows us to construct a P–T–t path that can be compared directly to the P–T–t path constructed from interbedded acid rocks (aluminous micaschists) in the same structural unit. Through time, both basic and acid rocks underwent the same complex deformation history that can be described conveniently in the L–S fabric system of Flinn. This allows us to construct a P–T–t deformation path for this structural unit.
These paths are interpreted in terms of an under/overthrusting continental collision belt (the Hercynian belt), and represent an illustration of the time delay caused by stacking of more than two crustal units.  相似文献   

长江下游越冬期冷暖长期变化与大型环流低频振动     

汪铎  张镡 《地理学报》1988,(4)

本文运用上海112年月平均温度资料和1月、10月的月平均海平面气压场110年资料,分析了以上海资料为代表的长江下游地区越冬季节温度由偏冷转向偏暖的长期变化及其有关联的大型环流系统的低频振动。发现近百年中前冬11月、12月和后冬2月这三个月的冷暖长期变化相似,特点是前50年左右偏冷占优势;后50年左右偏暖占优势,相应地10月大型环流中亚洲大陆冷高压的优势是前50年偏强偏东;后50年偏弱偏西,北太平洋高压的变化趋势则是前50年偏弱;后50年偏强。1月气温的长期变化与上述11月、12月和2月的冷暖变化不同,对应的大型环流低频振动也不同。  相似文献   

Observations of the OH Radical in Comet C/1995 O1 (Hale-Bopp) with the Nançay Radio Telescope     

Colom  P.  Gérard  E.  Crovisier  J.  Bockelé-Morvan  D.  Biver  N.  Rauer  H. 《Earth, Moon, and Planets》1997,78(1-3):37-43

We present OH 18-cm observations of comet Hale-Bopp (C/1995 O1) at the Nançay radio telescope. On nucleus and offset position observations allowed us to obtain both OH production rates and quenching radii. The maximum OH production rate was reached around perihelion, at about10³¹ s^-1.  相似文献   

北太平洋夏季海平面气压场的时空分布及其与黄河、长江流域旱涝的关联^*     

李月洪  吴祥定 《地理研究》1991,10(3):30-36

本文应用复经验正交函数分析方法对1899—1980年期间北太平洋夏季海平面气压距平场进行分析。第一主分量表明,北太平洋海平面气压场是以副热带太平洋高压存在和位移为主要特征,其空间波动的传播方向有较大的差异。另外二个主分量则分别与我国多雨和少雨的型式相配合。此外,本文还探讨了北太平洋夏季海平面气压场与黄河、长江流域各分区旱涝的关系。  相似文献   

Composite spectra     

R. & R. Griffin 《Journal of Astrophysics and Astronomy》1990,11(3):281-290

HD 201270/1 is a composite-spectrum binary whose components have spectral types close to G8 III and A2 V. They are in a circular orbit with a period of only 40 days. Photometric variability of RS CVn character is therefore not unlikely  相似文献   

Effective Hamiltonian for the D'Alembert Planetary Model Near a Spin/Orbit Resonance     

Luca Biasco  Luigi Chierchia 《Celestial Mechanics and Dynamical Astronomy》2002,83(1-4):223-237

The D'Alembert model for the spin/orbit problem in celestial mechanics is considered. Using a Hamiltonian formalism, it is shown that in a small neighborhood of a p:q spin/orbit resonance with (p,q) different from (1,1) and (2,1) the 'effective' D'Alembert Hamiltonian is a completely integrable system with phase space foliated by maximal invariant curves; instead, in a small neighborhood of a p:q spin/orbit resonance with (p,q) equal to (1,1) or (2,1) the 'effective' D'Alembert Hamiltonian has a phase portrait similar to that of the standard pendulum (elliptic and hyperbolic equilibria, separatrices, invariant curves of different homotopy). A fast averaging with respect to the 'mean anomaly' is also performed (by means of Nekhoroshev techniques) showing that, up to exponentially small terms, the resonant D'Alembert Hamiltonian is described by a two-degrees-of-freedom, properly degenerate Hamiltonian having the lowest order terms corresponding to the 'effective' Hamiltonian mentioned above.  相似文献   

图书情报资料工作在测绘教育中的地位与作用     

张春香  陈德云 《地理信息世界》2001,(2)

学校图书馆是图书资料的供应与服务基地 ,其藏书量与藏书类别的多少 ,以及图书馆各专业情报资料源的数量与管理和服务水平 ,是办学条件的重要标志之一 ,因而 ,测绘图书情报资料的信息源建设、测绘科技文献的开发与利用和测绘科技情报资料为师生的服务 ,在测绘教育中有着举足轻重的地位与作用。  相似文献   

致密星的X射线辐射时延现象     

屈进禄  宋黎明  吴枚  李年福 《天文学进展》2002,20(2):144-157

能谱仅反映了高能天体辐射的部分性质，而高能X射线辐射的时变可以反映致密天体的动态性质。因此，在构造高能辐射的理论模型时，既要考虑X辐射的能谱性质，也要考虑其时变性质。特别对高能天体X辐射的快速光变，一般认为其发生在致密天体附近，致密天体快速光变的研究可以揭示出致密天体附近的物理性质，因此，时变可以对X辐射模型给以很强的限制。X射线源不同能量光子到达观测者的时间差称为X射线辐射的时延。介绍了高能X辐射时变中的时延分析方法及其最新发展，综述了致密双星系统中黑洞侯选林和中子星的时延现象，并简单介绍了为解释这些现象所发展的模型，以及时延对模型的限制。  相似文献