南沙群岛海域水体漫衰减系数Kd(490)的特性研究   总被引：6，自引：1，他引：6  

张清凌  陈楚群  施平 《热带海洋学报》2003,22(1):9-16

对南沙群岛海区水体Kd(490）的特性进行了深入分析和探讨,研究结果表明：Kd（490）的垂直分布与同步测量的海水叶绿素a浓度的垂直分布有很强的相关性;Kd（490）的垂直分布反映出该区域海水存在较强的分层现象,研究中还发现上行辐亮度漫衰减系数KL（490）与Kd（490）垂直变化趋势相当一致,但是以二者达到最大值的深度为界,上层水体的KL（490）值稍大于Kd(490）值,在这一深度以下则相反。  相似文献   

Relationship between Cd and PO4 in the Subtropical Sea near the Ryukyu Islands     

Kazuo Abe 《Journal of Oceanography》2002,58(4):577-588

The relationship between dissolved cadmium (Cd) and phosphate (PO₄) was examined at three stations in the subtropical area near the Ryukyu Islands in May 1999. Preformed PO₄ was obtained using the Redfield ratio in order to separate the surface water and the other layers in this study area. Almost 0 μM (−0.043 μM to 0.094 μM) was estimated in the layers above 300 m and 250 m at Sts. 1 and 3 and at St. 2, respectively. Up to these depths, water was considered to be uniform, and these layers were defined as the surface water in this study area. In the surface water, the slopes of the regression lines of the Cd-PO₄ plot were 0.162, 0.156, and 0.226 (nM/μM) at Sts. 1, 2, and 3, respectively, and these values were much closer to the estimated regenerated ratio of Cd to PO₄ from the Apparent Oxygen Utilization (AOU)-Cd/PO₄ plots, which was 0.197 (nM/μM) in this study area. Below surface layers, the slopes of the Cd-PO₄ plot changed to 0.371, 0.352, and 0.362 (nM//μM) at Sts. 1, 2, and 3, respectively. In the relationships between Cd and PO₄, clear deviations or kinks were observed at three stations at a PO₄ concentration of approximately 0.2 μM in the plot, which was attributable to the discontinuity of surface water and the other layers across the North Pacific subtropical mode water. In studies of the interaction between surface water and biogenic particles concerning the Cd/PO₄ ratio, separate analyses of seawater (surface water and the other layers) should be carried out to obtain the individual surface water ratio because the Cd/PO₄ ratio in the surface water is expected to differ from that of the underlying water. Furthermore, the biological fractionation of these constituents is based on the surface water ratio. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

一种带自由面的三维船体贴体网络的数值生成     

李廷秋  缪国平  刘应中 《海洋工程》1996,(1)

本文提出了一个生成自由面的三维船体贴体网格的数值方法。文中以静水面以上的船体型线作为描述非定常自由面的计算网格域，进一步完善了我们以往开发的无法考虑兴波与静水面以上的船体型线相互作用对船舶粘性流动影响的网格生成方法。静水面以上的初始自由面网格分别沿船面法线η及切线ζ方向的曲线长的指数进行分布，即可极方便地调节自由面在船面及静水面附近的网格间距，也保证了在数值离散三维Ｐｏｉｓｓｏｎ方程时具有相当好的收敛性。这种方法的特点是计算量相当小，尤其能极方便地控制网格在船面簿粘性层中及静水面附近的分布。以Ｓｅｒｉｅｓ６０船模作为计算算例，带自由面的网格分布是相当满意的  相似文献   

南海北部水体叶绿素a浓度反演的生物光学模型   总被引：2，自引：0，他引：2  

许大志  曹文熙  王桂芬 《热带海洋学报》2007,26(2):15-21

利用2003年至2005年秋季在南海多个航次的现场观测数据,研究了南海北部海区遥感反射率的变化,并分析了用于全球海洋叶绿素a浓度反演的OC2和OC4模型在本海区的适用性。结果表明,在南海北部海域,OC2和OC4模型高估了叶绿素a浓度,高估范围一般约在80%—200%之间,其中最高可达640%,即OC2和OC4模型并不适用于南海海域。在此基础上,根据现场实测的表观光学数据,利用遥感反射率比值(Rrs(433)/Rrs(555))与叶绿素a浓度的关系建立了两套能够精确反演南海北部海域叶绿素a浓度的本地化经验算法———算法1和算法2,并利用其对南海北部海域的叶绿素a浓度进行反演。结果表明,由本地化模型反演得到的叶绿素a浓度与实测的叶绿素a浓度具有较好的相关关系,其平均相对偏差分别为51%和53%,相关系数为0.75。  相似文献   

Seasonal methyltin and (3-dimethylsulphonio)propionate concentrations in leaf tissue of Spartina alterniflora of the Great Bay estuary (NH)     

James H. Weber  Marilyn R. Billings  Anne M. Falke 《Estuarine, Coastal and Shelf Science》1991,33(6)

Concentrations of total recoverable inorganic tin (TRISn), monomethyltin (MeSn³⁺), dimethyltin (Me₂Sn²⁺), trimethyltin (Me₃Sn⁺) and (3-dimethylsulphonio)propionate (DMSP) were determined in leaves of Spartina alterniflora from three sites in the Great Bay estuary (NH) from 8 May to 15 September 1989. Total methyltin concentration increased from 8·9 ng g⁻¹ (fresh weight) on 8 May to 472 ng g⁻¹ on 23 May, decreased to 52 ng g⁻¹ on 7 June and 16ng g⁻¹ on 20 June, and remained low until the last sample on 18 September. Statistical calculations showed that methyltin concentrations varied significantly with sampling week, but not with site. DMSP concentrations showed very different behaviour. During the same sampling period DMSP concentrations varied only from 7·5 to 26 μmol g⁻¹ (fresh weight). DMSP concentrations varied significantly for site, but not sampling week.  相似文献   

Use of an optical oxygen sensor to measure dissolved oxygen in seawater     

Hiroshi Hasumoto  Tsuneo Imazu  Toshiaki Miura  Kazuhiro Kogure 《Journal of Oceanography》2006,62(1):99-103

The use of an optical oxygen sensor to measure dissolved oxygen in seawater was investigated. The sensor is based on the dynamic quenching of an oxygen-sensitive fluorochrome embedded in the tip. Dissolved oxygen in seawater samples collected from eight stations at depths ranging from 3000 to 6000 m was analyzed both with the optical sensor and by the Winkler titration method. The two sets of data did not differ significantly. The stability and simplicity of the method and the good agreement of the results with those of the titration method indicate that the sensor would be useful for fieldwork.  相似文献   

Variability of organic δC and C/N in the Mersey Estuary, U.K. and its implications for sea-level reconstruction studies     

Graham P. Wilson  Angela L. Lamb  Melanie J. Leng  Silvia Gonzalez  David Huddart 《Estuarine, Coastal and Shelf Science》2005,64(4):685-698

Microfossil analysis (e.g. diatoms, foraminifera and pollen) represents the cornerstone of Holocene relative sea-level (RSL) reconstruction because their distribution in the contemporary inter-tidal zone is principally controlled by ground elevation within the tidal frame. A combination of poor microfossil preservation and a limited range in the sediment record may severely restrict the accuracy of resulting RSL reconstructions. Organic δ¹³C and C/N analysis of inter-tidal sediments have shown some potential as coastal palaeoenvironmental proxies. Here we assess their viability for reconstructing RSL change by examining patterns of organic δ¹³C and C/N values in a modern estuarine environment. δ¹³C and C/N analysis of bulk organic inter-tidal sediments and vegetation, as well as suspended and bedload organic sediments of the Mersey Estuary, U.K., demonstrate that the two main sources of organic carbon to surface saltmarsh sediments (terrestrial vegetation and tidal-derived particulate organic matter) have distinctive δ¹³C and C/N signatures. The resulting relationship between ground elevation within the tidal frame and surface sediment δ¹³C and C/N is unaffected by decompositional changes. The potential of this technique for RSL reconstruction is demonstrated by the analysis of part of an early Holocene sediment core from the Mersey Estuary. Organic δ¹³C and C/N analysis is less time consuming than microfossil analysis and is likely to provide continuous records of RSL change.  相似文献   

海水中液-固界面的台阶型动力学曲线 Ⅱ.液膜扩散-递进扩散-界面分级交换反应联合控制的复合模型理论     

刘莲生  张正斌  蔡卫君  潘纲  杜恒清 《海洋与湖沼》1993,24(5):477-484

为定量解释海水中液-固界面的台阶型动力学曲线及其台阶的消长变化规律,在我们已提出的“液膜扩散和递进液膜扩散控制的复合模型”和“海水中液-固界面分级离子/配位子交换理论”基础上,吸取Crank的若干数学处理方法,进而提出适合于非稳态体系的“液膜扩散-递进扩散-界面分级交换反应联合控制的复合模型”。  相似文献   

Geochemical cycling in the Hooghly estuary, India     

B. L. K. Somayajulu  R. Rengarajan  R. A. Jani 《Marine Chemistry》2002,79(3-4)

U–Th decay series isotopes, δ¹⁸O and Si measurements in the river estuarine waters and sediments of the polluted Hooghly estuary as well as the surface waters of the Bay of Bengal, its high salinity end member, are reported. Dissolved Si indicates that there are probably two mixing regimes, dissolved U behaviour is nonconservative and δ¹⁸O behaves conservatively in the overall estuarine region. Isotopes of reactive elements, viz. ²³⁴Th and ²¹⁰Po, are removed from the estuarine waters in <2 days and <1 month, respectively, which is due to high suspended matter (30–301 mg l⁻¹). ²²⁸Ra and ²²⁶Ra are profusely released into the estuarine waters in the low to mid-salinity regions.As expected, the opposite trend is observed in the case of estuarine sediments and suspended matter. Reactive isotopes of Th, ²¹⁰Pb and ²¹⁰Po are enriched, whereas Ra isotopes are depleted with respect to their parent nuclides in the estuarine sediments and suspended matter. ²³²Th/Al ratio appears well suited to study the distribution and mixing of the bed load sediments of the Ganga–Brahmaputra (G–B) and the Hooghly rivers with those from other rivers on the Bay of Bengal floor.  相似文献   

溴素的有机化学──I．2，4，6－三溴苯甲酸溴代和非溴代芳酯的合成     

蔡月琴  钱佐国  孙明昆 《中国海洋大学学报(自然科学版)》1994,(3)

用ｍ－氨基苯甲酸作原料，经溴代、重氮化、还原脱氨、酰氯化和酯化反应等步骤，合成了六种新型的三溴苯甲酸的溴代和非溴代芳酯，即；双（２，４，６－三溴苯甲酸）－２＇，３＇，５＇，６＇－四溴－１＇，４＇－苯二酯，２，４，６－三溴苯甲酸－２＇，３＇，４＇，５＇，６＇－五溴苯酯，２，４，６－三溴苯甲酸－２＇，４＇，６＇－三溴苯酯，２，４，６－三溴苯甲酸－４＇－溴苯酯，２，４，６－三溴苯甲酸－４＇－甲基苯酯和２，４，６－三溴苯甲酸苯酯．通过对产物中碳、氢、溴元素的定量分析以及红外吸收光谱和氢核磁共振谱的研究，验证了合成产物的结构。  相似文献