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Heavy metal concentrations were investigated in overbank sediments of the Mala Panew River, southern Poland. Samples were collected from seven vertical profiles located within channel infills of a 20th century floodplain at three sites, each up to 50 m wide. In each profile, 15–24 samples were collected and analysed for Ba, Cd, Cu, Pb, and Zn. Sequential extraction of these elements was carried out in the 0.063-mm fraction of selected samples. Additionally, the age of the oldest trees growing close to the profiles has been used to estimate the initiation of sediment accumulation there. Ba, Cu, and Pb, which occur mostly in less mobile, moderately reducible, and residual fractions, were used for sediment dating. Zn and Cd, which in 50–75% occur in the mobile exchangeable fraction, were not suitable for dating. Correlation of Ba, Cu, and Pb concentrations in vertical profiles with changes in the load of effluents discharged to the river showed abrupt changes in the thickness of the strongly polluted sediments across the floodplains. A comparison of the relative changes between heavy metal peaks in sediments of similar age in the different profiles suggests a variable rate of downward metal migration. In general, none of the heavy metals investigated seems to have been mobilised within the stratigraphic layers above the water table. In layers located at stratigraphically lower levels, the Zn and Cd peaks seem to migrate several centimetres to several decimetres down in the profile. In profiles inundated for several weeks every year, Zn and Cd, as well as the relatively less mobile Ba, Cu, and Pb, have migrated downward by several decimetres. The investigation shows that frequent fluctuations of the water table have blurred the original depositional metal patterns of metal concentrations within a period of less than 40 years. 相似文献
44.
开封大雾气候特征及预报 总被引:1,自引:0,他引:1
利用1961~2000年气象资料,分析了开封市大雾天气分布规律、天气特征,并总结出大雾产生的几种天气形势,找出预报指标。 相似文献
45.
One of the most cost-effective in situ technologies for soil and groundwater (i.e., aquifer) remediation is electrokinetic remediation. In electrokinetic remediation, electromigration due to electric field is combined with hydromigration due to hydraulic flow by purge water to remove pollutants from aquifers through the pore water. This study aims at investigating theoretically the role of electromigration (as active movement) of pollutants and the role of hydromigration (as passive movement) of pollutants in electrokinetic remediation, and making it clear that the control variables for electrokinetic remediation are the applied voltage and the hydraulic flow rate. These aims are pursued by construction of a mathematical model based on physico-chemical considerations and by model simulations of the electrokinetic remediation applied to the virtual aquifer polluted by heavy metals of copper sulfate. According to numerical simulations with the model: (1) heavy metal (nonanionic copper) is removed from the upstream anode region and accumulated in the downstream cathode region; (2) to carry away the heavy metal outside the aquifer (global removal), hydromigration by purge water flow is essential; and (3) electromigration contributes mainly to the redistribution of heavy metals within the aquifer (local removal and local accumulation). 相似文献
46.
Correlation between magnetic susceptibility and heavy metals in urban topsoil: a case study from the city of Xuzhou, China 总被引:7,自引:0,他引:7
Anthropogenic influence, mainly due to urban and industrial activities and traffic exhaust, may affect urban topsoil via atmospheric contamination and solid waste. Magnetic susceptibility measurements were conducted on 21 urban topsoil samples from the city of Xuzhou, China. High intensities of magnetic susceptibility were detected in the majority of the samples. SEM analysis shows that magnetic minerals are in the form of spherules and mainly due to anthropogenic inputs. The heavy metals Pb, Cu, Zn, Se, Sc, Mo, Fe, and Bi show strong correlations with magnetic susceptibility, and Ag, Ba, Cd, Ni, Cr, Sb, and Sn, on the other hand, show a weak correlation with magnetic susceptibility. Whereas, of these metals studied, only Hg has no significant correlation with the susceptibility. The Tomlinson pollution load index (PLI) also shows significant correlation with the susceptibility (χ). The present study shows that magnetic susceptibility is a fast, inexpensive, and non-destructive method for the detection and mapping of contaminated soils. 相似文献
47.
Brijraj K. Das 《Environmental Geology》2005,49(2):230-239
A study of the water and sediment chemistry of the Nainital, Bhimtal, Naukuchiyatal and Sattal Lakes of Kumaun, has shown that the water of these lakes are alkaline and that electrical conductivity, total dissolved solid and bicarbonate HCO
3
−
are much higher in Nainital than in the other three lakes. The weathering of limestone lithology and anthropogenic pollution, the latter due to the very high density of population in the Nainital valley, are the primary sources of enhanced parameters. The low pH of Nainital Lake water is due to low photosynthesis and enhanced respiration, increasing CO2 in the water and the consequent enhancement of Ca2+ and HCO
3
−
. The dissolved oxygen in Nainital Lake is less compared to other lakes, indicating anoxic conditions developing at the mud–water interface at depth. The PO
4
3−
content in Nainital is higher (124 μg/l), showing an increasing trend over time leading to eutrophic conditions. The trace metals (Cu, Co, Zn, Ni, Mn, and Sr) are present in greater amounts in the water of Nainital Lake than in the other three lakes, though Fe and Cr are high in Bhimtal and Fe in Naukuchiyatal. The higher abundance is derived from the leaching of Fe–Mg from metavolcanic and metabasic rocks. Most of the heavy metals (Cr, Ni, Cu, Mn, Fe, Sr, and Zn) significantly enrich the suspended sediments of the lakes compared to the bed sediments which due to their adsorption on finer particles and owing to multiple hydroxide coating and organic content, except for Fe, which is enriched in the bed sediments. The high rate of sedimentation, 11.5 mm/year in Nainital, compared to Bhimtal with 4.70 mm/year, Naukuchiyatal with 3.72 mm/year, and Sattal with 2.99 mm/year, has resulted in shorter residence time, poor sorting of grains, and lesser adsorption of heavy metals, leading consequently, their depletion in the bed sediments of Nainital Lake. 相似文献
48.
The preliminary study of streams and rivers from the Roşia Montană area revealed that the concntration of heavy metals— Cd,
Mn, Cu, Pb, and Zn—are above accepted limits. The gold extraction method is based on flotation. The most important pollution
sources are mine tailings. The determinations were performed for samples collected in: April 2004, July 2004, September 2004,
November 2004, February 2005 and May 2005. The highest concentrations were found for cadmium in September 2004: 0.17 mg/L;
for copper in September 2004: 1.38 mg/L; for manganese in July 2004: 239.4 mg/L; for lead in May 2005: 0.54 mg/L; and for
zinc in September 2004: 35.37 mg/L;. This study involved three small rivers (streams) that flow into the Mureş River and finally
into the Danube River, having a great impact on human health and environmental stability in the area. In May 2005, a sample
of drinking water from the mining district was also collected. 相似文献
49.
On Shikoku Island, which is one of the four main islands of Japan, a large number of large-scale crystalline schist landslides have been revealed and are being monitored by an observation system. Seasonal heavy rainfall is the most active meteorological factor that can threaten the stability of this kind of site-specific landslide. In this paper, on the basis of the study of the rainfall-related behavior of a typical crystalline schist landslide, the Zentoku landslide, by analyzing the precisely and continuously observed piezometric and movement data, a method was developed to quantitatively assess the effect of heavy rainfall on a large-scale landslide. The results indicated that heavy rainfall-induced landslide displacement shows good correlation with the variation of groundwater levels. Variations of groundwater level have been simulated with the use of a tank model. The simulation using this model permits the change in water levels for future rainfall events to be predicted. By combining the predicted results with the empirical relation between displacements and water levels, rainfall-induced landslide movement during extreme rainfall events can be estimated in advance. The effect of heavy rainfall on sliding behavior can be quantified in terms of the change in displacement. Thus warning information or advisories for the local residents can be provided. 相似文献
50.
雷暴中的闪电放电能够产生强静电场以及电磁辐射场,从而对空间电离层产生重要影响,引起电离层电子密度分布的扰动。研究表明:闪电放电引起电离层扰动的方式有两种:直接耦合和间接耦合。其中,直接耦合主要来自于闪电产生的准静电场及电磁场的作用,在甚低频 (VLF) 反射信号上表现出快VLF事件, 而间接耦合主要是闪电低频电磁波在传播过程中与磁层相互作用,在辐射带产生闪电诱导电子沉降 (LEP) 现象。雷暴闪电活动能够改变电离层从D层到F层的电子密度分布,影响对流层大气和电离层之间的场,导致中高层瞬态放电淘气精灵 (elves) 及红闪 (sprite) 等现象的激发。闪电VLF传输反射信号可用于反演电离层密度的变化,目前已成为一种探测电离层扰动的常用方法,而引起电离层扰动的强度不但和闪电放电参量密切相关,也和闪电放电过程、类型有关。该文重点阐述了闪电放电与电离层直接耦合和间接耦合作用以及导致的相关现象。 相似文献