镍为基体改进剂—石墨炉原子吸收法连续测定岩石矿物中痕量铊和镓     

姜凤华  姜春姬 《吉林地质》1993,12(2):66-70

本法采用镍为基体改进剂,消除较复杂试样的基体干扰,直接用石墨炉原子吸收法测定岩石矿物中痕量铊和镓。该法简便、快速、准确。国家一级标样测定值与推荐值吻合。对于镓的测定经过100多个实际样品考查分析质量符合要求。  相似文献   

膨润土负载纳米铁镍同步修复地下水中三氯乙烯和六价铬复合污染     

邓日欣  罗伟嘉  韩奕彤  李志雄  陈家玮 《岩矿测试》2018,37(5):541-548

纳米零价铁原位注射修复地下水污染是近年发展的新技术,以往研究多侧重于单一目标污染物的去除效果及作用机理,但是地下水多种污染物共存问题不容忽视。本文针对典型污染物三氯乙烯TCE和六价铬Cr(Ⅵ),运用合成的活性高、稳定性强的膨润土负载纳米铁镍(B-Fe/Ni)开展修复实验,研究B-Fe/Ni对TCE和Cr(Ⅵ)共存复合污染的修复效果及其作用机制。通过一步法合成B-Fe/Ni,对TCE和不同浓度Cr(Ⅵ)混合污染的去除进行试验研究,对反应前后的样品B-Fe/Ni进行表征,并跟踪反应过程中TCE和Cr(Ⅵ)的浓度变化。结果表明:B-Fe/Ni同步去除水中TCE和Cr(Ⅵ)快速高效,50 mg/L Cr(Ⅵ)在2 h内能被B-Fe/Ni (1 g/L)完全去除而不受共存TCE(0. 1 mmol/L)的影响,然而TCE降解速率会随共存Cr(Ⅵ)的浓度(0、10、30、50 mg/L)增大而降低。经透射电镜-电子能谱及X射线光电子能谱表征验证,这是由于B-Fe/Ni与Cr(Ⅵ)快速反应,生成部分Fe-Cr共沉淀会覆盖B-Fe/Ni表面的活性位点,抑制了TCE的降解,但通过分析TCE降解产物可知,B-Fe/Ni同样能对TCE完全脱氯。因此,B-Fe/Ni适用于地下水复合污染修复,实际应用时需考虑多种污染物共存的相互影响,选择适宜试剂用量和注射方式,这对纳米零价铁修复技术的发展具有重要理论意义和应用参考价值。  相似文献   

两类厄尔尼诺事件对金华气候的影响     

项素清  舒素芳  邱小伟 《海洋预报》2015,32(3):13-18

利用金华本站历史观测资料,分别就两类厄尔尼诺事件次年降水量、梅雨、高温日数、日照时数和台风等情况逐一进行分析探讨。结果表明:两类厄尔尼诺事件对金华气候的影响存在显著的差别,第1类影响年金华年降水量偏多,是涝年。入梅偏早,出梅偏晚,梅期偏长,降水量比常年偏多。日照时数比常年偏少,出现高温天数少,高温天气不严重。第2类影响年正好相反,金华年降水偏少,是旱年,入梅容易偏晚,出梅偏早,梅期偏短,梅雨量偏少,日照比常年偏多,高温出现也多,是高温天气比较严重的年份。  相似文献   

CHARACTERISTICS OF TROPICAL CYCLONE GENESIS IN THE WESTERN NORTH PACIFIC DURING THE DEVELOPING AND DECAYING PHASES OF TWO TYPES OF EL NI?O     

钟佩瑄  李天明 《热带气象学报(英文版)》2015,21(1):14-22

During the developing phase of central Pacific El Nio(CPEN), more frequent TC genesis over the northwest quadrant of the western North Pacific(WNP) is attributed to the horizontal shift of environmental vorticity field.Such a northwestward shift resembles the La Nia composite, even though factors that cause the shift differ(in the La Nia case the relative humidity effect is crucial). Greater reduction of TC frequency over WNP happened during the decaying phase of eastern Pacific El Nio(EPEN) than CPEN, due to the difference of the anomalous Philippine Sea anticyclone strength. The TC genesis exhibits an upward(downward) trend over the northern(southern) part of the WNP,which is linked to SST and associated circulation changes through local and remote effects.  相似文献   

The bivalve Anopaea (Inoceramidae) from the Upper Jurassic–lowermost Cretaceous of Mexico     

《Journal of South American Earth Sciences》2015

In Mexico, the Upper Jurassic to lowermost Cretaceous La Casita and coeval La Caja and La Pimienta formations are well-known for their abundant and well-preserved marine vertebrates and invertebrates. The latter include conspicuous inoceramid bivalves of the genus Anopaea not formally described previously from Mexico. Anopaea bassei (Lecolle de Cantú, 1967), Anopaea cf. stoliczkai (Holdhaus, 1913), Anopaea cf. callistoensis Crame and Kelly, 1995 and Anopaea sp. are rare constituents in distinctive Tithonian–lower Berriasian levels of the La Caja Formation and one Tithonian horizon of the La Pimienta Formation. Anopaea bassei was previously documented from the Tithonian of central Mexico and Cuba, while most other members of Anopaea described here are only known from southern high latitudes. The Mexican assemblage also includes taxa which closely resemble Anopaea stoliczkai from the Tithonian of India, Indonesia and the Antarctic Peninsula, and Anopaea callistoensis from the late Tithonian to ?early Berriasian of the Antarctic Peninsula. Our new data expand the palaeogeographical distribution of the high latitude Anopaea to the Gulf of Mexico region and substantiate faunal exchange, in the Late Jurassic–earliest Cretaceous, between Mexico and the Antarctic Realm.  相似文献   

Magnetotelluric characterization through the Ambargasta-Sumampa Range: The connection between the northern and southern trace of the Río de La Plata Craton – Pampean Terrane tectonic boundary     

《Journal of South American Earth Sciences》2015

The South American Platform was part of the Western Gondwana, a collage of plates of different ages assembled in late Neoproterozoic to Cambrian times. The Transbrasiliano Lineament, a continental shear belt that transversely intersects this platform from NE to SW, has its southern expression in the tectonic boundary between the Río de La Plata Craton and the Pampean Terrane. Magnetotelluric long-period data in a W–E profile (29°30′ S) that crosses the Ambargasta-Sumampa Range and the Chaco-Pampean Plain were obtained to connect information of this mostly inferred tectonic boundary. A 2-D inversion model shows the Chacoparanense basin, Río Dulce lineament, Ambargasta-Sumampa Range and Salina de Ambargasta in the upper crust. At mid-to-lower crust and 40 km to the east of the Ambargasta-Sumampa Range, a discontinuity (500–2000 Ω m) of 20-km-wide separates two highly resistive blocks, the Río de La Plata Craton (6000–20,000 Ω m) in the east, and the Pampean Terrane (5000–20,000 Ω m) in the west. This discontinuity represents the tectonic boundary between both cratons and could be explained by the presence of graphite. The geometry of the Pampean Terrane suggests an east-dipping paleo-subduction. Our results are consistent with gravimetric and seismicity data of the study area. A more conductive feature beneath the range and the tectonic boundary was associated with the NE–SW dextral transpressive system evidenced by the mylonitic belts exposed in the Eastern Pampean Ranges. This belt represents a conjugate of the mega-shear Transbrasiliano Lineament and could be explained by fluid–rock interaction by shearing during hundreds of years. The eastern border of the Ambargasta-Sumampa Range extends the trace of the Transbrasiliano Lineament. The electrical Moho depth (40 km to the west and 35 km to the east) was identified by a high electrical contrast between the crust and upper mantle. The upper mantle shows a resistive structure beneath the Río de La Plata Craton that could have been originated by stationary delamination by the presence of hydrated lithosphere.  相似文献   

Vertical structure of larval fish assemblages during diel cycles in summer and winter in the southern part of Bahía de La Paz, México     

Gerardo Aceves-Medina  Ricardo Saldierna-Martínez  Alejandro Hinojosa-Medina  Sylvia P.A. Jimnez-Rosenberg  Martín E. Hernndez-Rivas  Raúl Morales-vila 《Estuarine, Coastal and Shelf Science》2008,76(4):889-901

The effect of environmental variables on the vertical structure of larval fish assemblages in a tropical coastal lagoon was analyzed. Ichthyoplankton samples were collected from the near-bottom and surface strata near the mouth of a subtropical lagoon during contrasting seasonal conditions of temperature, photoperiod, light intensity, and tidal heights. During summer, larval fish assemblages had high species richness (R) and were dominated by tropical species. During winter, assemblages had lower R values and were dominated by subtropical and temperate species. Vertical distribution patterns of the taxa were determined by the interaction of environmental variables and behavior of each species to maintain their position in a stratum in the water column, or to achieve vertical migrations induced by environmental stimuli that, in this case, were thermal gradient, column water stratification, and intensity of light. Depth position and vertical migration of fish larvae, coupled with the flood and ebb tide conditions, played an important role in their retention and displacement toward the lagoon. Fish larvae with distribution restricted to the inner part of the inlet, such as Achirus mazatlanus, Etropus sp., and several gobies, were more abundant in the near-bottom stratum during the ebb tide, allowing them to avoid exportation, whereas those that could spawn outside, but depended on the inlet as a nursery area, were more abundant near the surface during flood tide, such as Abudefduf troschelii and Stegastes rectifraenum.  相似文献   

Changes and variation in the discharge regime of the Upper Suriname River Basin and its relationship with the tropical Pacific and Atlantic SST anomalies     

Riad Nurmohamed  Sieuwnath Naipal  Cor Becker 《水文研究》2008,22(11):1650-1659

Long‐term changes and variability in river flows in the tropical Upper Suriname River Basin in Suriname (2–6°N, 54–58°W) are analysed, including the relation to sea surface temperatures (SSTs) in the tropical Atlantic and Pacific Ocean. To analyse variability, lag correlation and statistical properties of the data series are used. Long‐term changes are analysed using parametric and non‐parametric statistical techniques. The analyses are performed for the period 1952–1985. The results show that both river discharge series at Semoisie and Pokigron are non‐stationary and have a negative trend. The negative rainfall trend in the centre of Suriname may be responsible for the negative trend in the annual river discharges in the basin. The highest correlation (Pearson's coefficient c) is obtained when the Tropical North Atlantic (TNA) SSTs lags the monthly discharges at Pokigron by 3–4 months (c = 0·7) and when the Tropical South Atlantic (TSA) SSTs lags the discharges by 4 months (c = ? 0·7). It also follows that the high (low) monthly flows, from April–August (September–March) are associated with increasing (decreasing) SSTs in the TNA and with decreasing (increasing) SSTs in the TSA. The results also reveal that years with low (high) discharges are more related to warmer (colder) SSTs during the year in the TNA region and a southward displacement of the Inter‐Tropical Convergence Zone (ITCZ). However, the Pacific El Niño (La Niña) events may also be responsible for low (high) flow years in this basin. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Perturbed solution of sea-air oscillator for the El Niño/La Niña-Southern Oscillation mechanism     

ZHOU Xianchun  LIN Yihu  WANG Hui  MO Jiaqi 《海洋学报(英文版)》2009,28(3):1-4

A class of coupled system of the El Niño/La Niña-Southern Oscillation (ENSO) mechanism is studied. Using the perturbed theory, the asymptotic expansions of the solution for ENSO model are obtained and the asymptotic behavior of solution for corresponding problem is considered.  相似文献   

El Niño influence on streamflow forecasting     

J. Kelman  A. de M. Vieira  J. E. Rodriguez-Amaya 《Stochastic Environmental Research and Risk Assessment (SERRA)》2000,14(2):123-138

Stochastic models are often fitted to historical data in order to produce streamflow scenarios. These scenarios are used as input data for simulation/optimization models that support operational decisions for water resource systems. The streamflow scenarios are sampled from probability distributions conditioned on the available information, such as recent streamflow data. In this paper we introduce a procedure for further conditioning the probability distributions by considering the recent measurements of climatic variables, such as sea temperatures, that are used to describe the occurrence of El Ni?o. We adopt an auto-regressive model and use the “El Ni?o information” to refine the parameter estimation process for each time step. The corresponding methodology is tested for the monthly energy time series, “inflowing” to the power plants of Colombia. This is a linear combination of streamflow values for the 18 most important rivers of the country.  相似文献