膜蒸馏处理乳化油废水的实验研究     

王斯佳  蔡蕊  孙求实  袁文真  吕颖 《世界地质》2009,28(2):261-264

采用自制的中空纤维膜蒸馏组件对模拟的乳化油废水进行膜蒸馏处理研究, 分析了料液的浓度、流速、温度和处理时间等因素对膜通量及去除率的影响。实验结果表明: 在料液温度为50℃、流速为14 mL /min、乳化油浓度为500 mg/L 的条件下, 运行1 h后乳化油膜通量为21.20 g/m2 ·h, 去除率> 70%; 运行5 h后膜通量下降为5.141 g/m2 ·h, 去除率> 90%。  相似文献   

Determination of Trace Silver in Polymetallic Ore Samples by Flame Atomic Absorption Spectrometry after Solid‐Phase Extraction Using a Microcolumn Comprising Eggshell Membrane     

Xianzhong Cheng  Kun Shao  Shangyue Shen  Shenghong Hu  Haiou Qiu 《Geostandards and Geoanalytical Research》2011,35(4):461-469

A rapid and inexpensive method was developed for the determination of trace silver in polymetallic ore samples by use of eggshell membrane (ESM), a natural biomaterial, as the solid‐phase extraction (SPE) adsorbent coupled with flame atomic absorption spectrometry (FAAS). The ESM was used for the separation/pre‐concentration of silver, and the parameters affecting sensitivity, such as pH, sample flow rate, eluent volume and eluent flow rate, were carefully investigated. ESM was found to be an effective solid phase extractant for the adsorption of trace silver over a wide range of acidity from 0.02 to 0.50 mol l^?1 HNO₃. The sample solution in 0.4 mol l^?1 HNO₃ was pumped through an ESM microcolumn at the rate of 1.0 ml min^?1. Silver was absorbed, and then eluted with a solution of 1.0% m/v thiourea–0.5% v/v HCl. Under these optimal conditions, ESM exhibited a good enrichment efficiency for silver with a dynamic adsorption capacity of 1.7 mg g^?1. The proposed method was applied to the FAAS determination of trace silver in polymetallic ores and geological reference materials, GSO‐2, 3 and 5, and GSD‐11, GSD‐12, and the determined values were in good agreement with certified values.  相似文献   

溶质类型与矿化度对土壤水分扩散率的影响   总被引：3，自引：0，他引：3  

郭全恩  王益权  马忠明  车宗贤  南丽丽  徐世文  刘延东 《干旱区地理》2011,34(1):86-90

以甘肃省秦安县果园石灰性土壤为研究对象,采用水平土柱入渗法,探讨了不同矿化度下(lg/L、3g/L、5g/L、10g/L)的三种钠盐(Nacl、Na2SO4和Na2CO3)对石灰性土壤水分扩散率的影响.结果表明:在水盐复合迁移体系中盐分与水分迁移具有不同步性,影响不同步性的因子与盐分类型有很大关系.NaCl对水分移动速...  相似文献   

膜蒸馏处理糠醛废水的实验研究   总被引：2，自引：1，他引：1  

张凤君  李卿  马玖彤  于广菊 《吉林大学学报(地球科学版)》2006,36(2):270-273

采用中空纤维膜蒸馏技术研究了糠醛废水的膜蒸馏处理效果,考察了料液相的温度、醋酸浓度、流速、吸收液浓度等因素对处理效果的影响。结果表明：在温差为15℃、料液的浓度为0.306 mol/mL时,速度为8 mL/min;吸收液的质量浓度为25 g/L时,速度为3 mL/min。运行12 h后,料液的pH值由开始的1.9升高为5.1,醋酸的去除率为76.3％,糠醛的去除率为40.1％。此过程可降低料液中糠醛和醋酸的含量,减小了低分子量有机酸对微生物危害的影响,为后续生物处理奠定了基础。  相似文献   

电镀金刚石钻头镀前超声清洗机理及工艺研究   总被引：4，自引：0，他引：4  

刘晓东  霍宇翔  李子章 《地质与勘探》2006,42(1):89-92

电镀金刚石钻头镀前清洗是钻头生产的关键制造工艺.超声清洗作为一种精清洗技术,在不少领域获得了成功.本文阐述了超声波对金刚石钻头镀前清洗工艺的适应性,分析了电镀金刚石钻头中的主要清洗对象及超声清洗机理,对超声清洗中的各项工艺参数及工艺流程进行了研究,说明了超声清洗的经济适用性及可操作性.  相似文献   

赤魟软骨血管生成抑制因子的分离纯化   总被引：2，自引：0，他引：2  

余新威  钱晓  王婕妤  罗红宇  吴常文 《海洋学报》2008,30(1):113-118

确定了制备高纯度赤魟软骨血管生成抑制因子的纯化工艺,并通过胶原酶模型、CAM模型验证其生物学活性。正交实验确定了赤魟软骨组织抽提的最佳条件,抽提产率可达0.84%。丙酮分级沉淀对抽提产物进行粗分离,25~35%的丙酮分级产物的CAM血管生成抑制率达85%。优化离子交换层析、凝胶过滤、反相层析的条件,可进一步有效的获得高纯度的赤魟软骨血管生成抑制因子-I(DCAIF-I)。SDS-PAGE-考马斯亮蓝染色显示为一条带,分子量为62 kDa。活性验证结果表明,DCAIF-I对胶原酶具有一定的抑制活性,抑制率为36.3%,对CAM血管生成的抑制活性具有一定的剂量依赖关系。  相似文献   

赤魟软骨粗提物的血管生成抑制活性定量分析     

罗红宇  徐佳晶  余新威  杨涛 《海洋学研究》2008,26(4):61-65

以赤魟软骨为原料,对赤魟软骨中新生血管抑制组分的提取方法及其生物学活性进行了初步研究。采用盐酸胍抽提、冷冻离心、透析、冷冻干燥等方法,得到分子量为3~300 kDa的活性组分,活性鉴定采用改进的Robert法观察赤魟软骨提取物对鸡胚绒毛尿囊膜(CAM)血管生成的作用情况。赤魟软骨提取物活性给药组为质量分数为10%、1%、0.1%的甲基纤维素溶液,空白对照组为质量分数为10%的MC溶液,加样24 h后对各给药组样品给药部位进行形态学观察,并通过计算机图像分析软件原理编程进行血管数量统计。试验结果表明:赤魟软骨提取物具有抑制新生血管形成的作用,其活性与给药组质量分数成正比。且软骨血管生成抑制因子直接来源于动物组织,无明显毒副作用,在肿瘤治疗方面可能具有良好的应用前景。  相似文献   

PVDF管式超滤膜在低渗油田水处理中的研究及应用——以江苏台兴油田为例     

张奉东 《海洋地质译丛》2008,(2):92-94

根据低渗油田和特低渗油田的特点,研制出PVDF管式超滤膜,开展室内基础研究,并在江苏台兴油田进行中试和大规模的现场试验。经过处理后,水质标准达到油田回注水A1标准（SY／T5329-1994）,满足了低渗油田和特低渗油田的注水要求。  相似文献   

6种海洋致病性弧菌36kDa外膜蛋白特性分析   总被引：3，自引：0，他引：3  

唐小千  战文斌  周丽  绳秀珍 《中国海洋大学学报(自然科学版)》2009,39(2)

研究本着筛选和制备弧菌共同外膜蛋白亚单位疫苗,用十二烷基肌氨酸钠抽提并结合超速离心的方法提取了鳗弧菌(Vibrio anguillarum)、鱼肠道弧菌(V.ichthyoenteri)、溶藻弧菌(V.alginolyticus)、副溶血弧菌(V.parahaemolyticus)、哈维氏弧菌(V.harveyi)和创伤弧菌(V.vulnificus)6种海洋致病性弧菌的主要外膜蛋白, SDS-PAGE图谱比较发现这6种弧菌都存在36 kDa的外膜蛋白条带.通过电泳洗脱分离纯化这6种弧菌的36 kDa外膜蛋白,并制备了鳗弧菌菌株SJ060621的36 kDa外膜蛋白多抗.ELISA和Western-blot印迹结果显示,仅鳗弧菌SJ060621、S010610-1和哈维氏弧菌的36 kDa外膜蛋白存在免疫交叉反应;双向电泳分析了鳗弧菌SJ060621、S010610-1、哈维氏弧菌和溶藻弧菌的36 kDa外膜蛋白,2-DE图谱显示出鳗弧菌SJ060621和S010610-1均由3种等电点相近的蛋白组成,存在很高的同源性,2株鳗弧菌与溶藻弧菌和哈维氏弧菌在蛋白质组成数量和等电点上都存在较大的差异,结果说明通过主要外膜蛋白的分子量和免疫特性研究,可为筛选不同弧菌共同外膜蛋白的亚单位疫苗提供有利参考.  相似文献   

Theoretical aspects of cap-rock and fault seals for single- and two-phase hydrocarbon columns   总被引：6，自引：0，他引：6  

N.L. Watts   《Marine and Petroleum Geology》1987,4(4)

Cap-rock seals can be divided genetically into those that fail by capillary leakage (membrane seals) and those whose capillary entry pressures are so high that seal failure preferentially occurs by fracturing and/or wedging open of faults (hydraulic seals). A given membrane seal can trap a larger oil column than gas column at shallow depths, but below a critical depth (interval), gas is more easily sealed than oil. This critical depth increases with lower API gravity, lower oil GOR and overpressured conditions (for the gas phase). These observations arise from a series of modelling studies of membrane sealing and can be conveniently represented using pressure/ depth (P/D) profiles through sealed hydrocarbon columns. P/D diagrams have been applied to the more complex situation of the membrane sealing of a gas cap underlain by an oil rim; at seal capacity, such a two-phase column will be always greater than if only oil or gas occurs below the seal.These conclusions contrast with those for hydraulic seals where the seal capacity to oil always exceeds that for gas. Moreover, a trapped two-phase column, at hydraulic seal capacity will be less than the maximum-allowed oil-only column, but more than the maximum gas-only column. Unlike membrane seals, hydraulic seal capacity should be directly related to cap-rock thickness, in addition to the magnitude of the minimum effective stress in the sealing layer and the degree of overpressure development in the sequence as a whole.Fault-related seals are effectively analogous to membrane cap-rocks which have been tilted to the angle of the fault plane. Consequently, all of the above conclusions derived for membrane cap-rocks apply to both sealing faults sensu stricto (fault plane itself seals) and juxtaposition faults (hydrocarbon trapped laterally against a juxtaposed sealing unit). The maximum-allowed two-phase column trapped by a sealing fault is greater than for equivalent oil-only and gas-only columns, but less than that predicted for a horizontal membrane cap-rock under similar conditions. Where a two-phase column is present on both sides of a sealing fault (which is at two-phase seal capacity), a deeper oil/water contact (OWC) in one fault block is associated with a deeper gas/oil contact (GOC) compared with the adjacent fault block. If the fault seal is discontinuous in the gas leg, however, the deeper OWC is accompanied by a shallower GOC, whereas a break in the fault seal in the oil leg results in a common OWC in both fault blocks, even though separate GOC's exist. Schematic P/D profiles are provided for each of the above situations from which a series of fundamental equations governing single- and two-phase cap-rock and fault seal capacities can be derived. These relationships may have significant implications for exploration prospect appraisal exercises where more meaningful estimates of differential seal capacities can be made.The membrane sealing theory developed herein assumes that all reservoirs and seals are water-wet and no hydrodynamic flow exists. The conclusions on membrane seal capacity place constraints on the migration efficiency of gas along low-permeabiligy paths at depth where fracturing, wedging open of faults and/or diffusion process may be more important. Contrary to previous assertions, it is speculated that leakage of hydrocarbons through membrane seals occurs in distinct pulses such that the seal is at or near the theoretically calculated seal capacity, once this has been initially attained.Finally, the developed seal theory and P/D profile concepts are applied to a series of development geological problems including the effects of differential depletion, and degree of aquifer support, on sealing fault leakage, and the evaluation of barriers to vertical cross-flow using RFT profiles through depleted reservoirs. It is shown that imbibition processes and dynamic effects related to active cross-flow across such barriers often preclude quantitative analysis and solution of these problems for which simulation studies are usually required.  相似文献