Heavy metals in marine sediments of Taranto Gulf (Ionian Sea, Southern Italy)   总被引：5，自引：0，他引：5  

Alessandro Buccolieri  Giovanni Buccolieri  Nicola Cardellicchio  Angelo Dell'Atti  Antonella Di Leo  Antonella Maci 《Marine Chemistry》2006,99(1-4):227

Al, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Ti and Zn concentrations have been determined in surface sediment samples collected in the Taranto Gulf (Ionian Sea, Southern Italy) in order to evaluate their levels and spatial distribution in this important area of the Mediterranean Sea. For various metals, the geoaccumulation index has been calculated as a criterion to assess if their concentrations represent contamination levels or can be considered as background levels. The results show that metals concentrations in sediments can be considered near the background levels found in the Mediterranean Sea.Analytical results have been elaborated by using a Geographical Information System (GIS) software to show metals accumulation areas. Using multivariate statistical analysis, we evaluate the possibility to distinguish the sampling stations, in relation to their geographical position. Results have showed metals distribution in the Taranto Gulf is principally influenced by industrial and urban wastes, located mostly in the northern coastal area of the Ionian Sea. Rivers in the Basilicata region and prevailing anticlockwise marine currents are further factors influencing metal accumulation in sediments.  相似文献   

Coupling a two-way nested primitive equation model and a statistical SST predictor of the Ligurian Sea via data assimilation     

A. Barth  A. Alvera-Azcrate  J.-M. Beckers  M. Rixen 《Ocean Modelling》2006,13(3-4):255-270

A primitive equation model and a statistical predictor are coupled by data assimilation in order to combine the strength of both approaches. In this work, the system of two-way nested models centred in the Ligurian Sea and the satellite-based ocean forecasting (SOFT) system predicting the sea surface temperature (SST) are used. The data assimilation scheme is a simplified reduced order Kalman filter based on a constant error space. The assimilation of predicted SST improves the forecast of the hydrodynamic model compared to the forecast obtained by assimilating past SST observations used by the statistical predictor. This study shows that the SST of the SOFT predictor can be used to correct atmospheric heat fluxes. Traditionally this is done by relaxing the model SST towards the climatological SST. Therefore, the assimilation of SOFT SST and climatological SST are also compared.  相似文献   

Prediction of UT1–UTC,LOD and AAM χ<Subscript>3</Subscript> by combination of least-squares and multivariate stochastic methods     

Tomasz Niedzielski  Wiesław Kosek 《Journal of Geodesy》2008,82(2):83-92

This article presents the application of a multivariate prediction technique for predicting universal time (UT1–UTC), length of day (LOD) and the axial component of atmospheric angular momentum (AAM χ ₃). The multivariate predictions of LOD and UT1–UTC are generated by means of the combination of (1) least-squares (LS) extrapolation of models for annual, semiannual, 18.6-year, 9.3-year oscillations and for the linear trend, and (2) multivariate autoregressive (MAR) stochastic prediction of LS residuals (LS + MAR). The MAR technique enables the use of the AAM χ ₃ time-series as the explanatory variable for the computation of LOD or UT1–UTC predictions. In order to evaluate the performance of this approach, two other prediction schemes are also applied: (1) LS extrapolation, (2) combination of LS extrapolation and univariate autoregressive (AR) prediction of LS residuals (LS + AR). The multivariate predictions of AAM χ ₃ data, however, are computed as a combination of the extrapolation of the LS model for annual and semiannual oscillations and the LS + MAR. The AAM χ ₃ predictions are also compared with LS extrapolation and LS + AR prediction. It is shown that the predictions of LOD and UT1–UTC based on LS + MAR taking into account the axial component of AAM are more accurate than the predictions of LOD and UT1–UTC based on LS extrapolation or on LS + AR. In particular, the UT1–UTC predictions based on LS + MAR during El Niño/La Niña events exhibit considerably smaller prediction errors than those calculated by means of LS or LS + AR. The AAM χ ₃ time-series is predicted using LS + MAR with higher accuracy than applying LS extrapolation itself in the case of medium-term predictions (up to 100 days in the future). However, the predictions of AAM χ ₃ reveal the best accuracy for LS + AR.  相似文献   

On the multivariate total least-squares approach to empirical coordinate transformations. Three algorithms   总被引：2，自引：1，他引：1  

Burkhard Schaffrin  Yaron A. Felus 《Journal of Geodesy》2008,82(6):373-383

The multivariate total least-squares (MTLS) approach aims at estimating a matrix of parameters, Ξ, from a linear model (Y−E _Y = (X−E _X ) · Ξ) that includes an observation matrix, Y, another observation matrix, X, and matrices of randomly distributed errors, E _Y and E _X . Two special cases of the MTLS approach include the standard multivariate least-squares approach where only the observation matrix, Y, is perturbed by random errors and, on the other hand, the data least-squares approach where only the coefficient matrix X is affected by random errors. In a previous contribution, the authors derived an iterative algorithm to solve the MTLS problem by using the nonlinear Euler–Lagrange conditions. In this contribution, new lemmas are developed to analyze the iterative algorithm, modify it, and compare it with a new ‘closed form’ solution that is based on the singular-value decomposition. For an application, the total least-squares approach is used to estimate the affine transformation parameters that convert cadastral data from the old to the new Israeli datum. Technical aspects of this approach, such as scaling the data and fixing the columns in the coefficient matrix are investigated. This case study illuminates the issue of “symmetry” in the treatment of two sets of coordinates for identical point fields, a topic that had already been emphasized by Teunissen (1989, Festschrift to Torben Krarup, Geodetic Institute Bull no. 58, Copenhagen, Denmark, pp 335–342). The differences between the standard least-squares and the TLS approach are analyzed in terms of the estimated variance component and a first-order approximation of the dispersion matrix of the estimated parameters.  相似文献   

Dynamic data integration for structural modeling: model screening approach using a distance-based model parameterization   总被引：2，自引：0，他引：2  

Satomi Suzuki  Guillaume Caumon  Jef Caers 《Computational Geosciences》2008,12(1):105-119

This paper proposes a novel history-matching method where reservoir structure is inverted from dynamic fluid flow response. The proposed workflow consists of searching for models that match production history from a large set of prior structural model realizations. This prior set represents the reservoir structural uncertainty because of interpretation uncertainty on seismic sections. To make such a search effective, we introduce a parameter space defined with a “similarity distance” for accommodating this large set of realizations. The inverse solutions are found using a stochastic search method. Realistic reservoir examples are presented to prove the applicability of the proposed method.  相似文献   

A multivariate statistical and geostatistical study on the geochemistry of allochtonous karst bauxite deposits in Hungary     

Bárdossy  George  Kovács  Ó. 《Natural Resources Research》1995,4(2):138-153

A geochemical evaluation of the Szc-Halimba-Kisld area, Hungary, covering an area of more than 200 km² is presented using different statistical and geostatistical methods. The study area is a representative example of allochtonous karst bauxite accumulation. The three groups of deposits studied here have been explored and mined since 1950. Several thousand boreholes have been drilled, and bauxite cores were analyzed for the five main chemical components. A total of 80,000 pleces of analytical data were processed, followed by a geological examination of borehole logs and of mining excavations.The quantitative geochemical evaluation of the data set led to both geochemical and practical results: The geochemical behavior of the allochtonous, clastic karst bauxite deposits differs essentially from that of the autochtonous and parautochtonous ones, as well as that of the lateritic bauxite deposits. The deposits of the study area can be split into several subsequent geochemical-sedimentological units, each representing an event of bauxite transport and accumulation. Clear regional patterns can be revealed in the composition of these units. The geostatistically measured chemical variability of the geochemical units is rather different, the lowest units showing the smallest variability. The interrelations of the main chemical components are weaker and more irregular in the studied deposits than in the autochtonous lateritic bauxite deposits. Additional local genetic features, such as transport routes, can be delineated by the methods applied. Within each deposit, local changes of chemical composition and of its variability can be determined more precisely. These results can be used in bauxite prospecting and exploration, because areas of high or low bauxite quality can be predicted.  相似文献   

A way to synchronize models with seismic faults for earthquake forecasting: Insights from a simple stochastic model     

lvaro Gonzlez  Miguel Vzquez-Prada  Javier B. Gmez  Amalio F. Pacheco 《Tectonophysics》2006,424(3-4):319

Numerical models are starting to be used for determining the future behaviour of seismic faults and fault networks. Their final goal would be to forecast future large earthquakes. In order to use them for this task, it is necessary to synchronize each model with the current status of the actual fault or fault network it simulates (just as, for example, meteorologists synchronize their models with the atmosphere by incorporating current atmospheric data in them). However, lithospheric dynamics is largely unobservable: important parameters cannot (or can rarely) be measured in Nature. Earthquakes, though, provide indirect but measurable clues of the stress and strain status in the lithosphere, which should be helpful for the synchronization of the models.The rupture area is one of the measurable parameters of earthquakes. Here we explore how it can be used to at least synchronize fault models between themselves and forecast synthetic earthquakes. Our purpose here is to forecast synthetic earthquakes in a simple but stochastic (random) fault model. By imposing the rupture area of the synthetic earthquakes of this model on other models, the latter become partially synchronized with the first one. We use these partially synchronized models to successfully forecast most of the largest earthquakes generated by the first model. This forecasting strategy outperforms others that only take into account the earthquake series. Our results suggest that probably a good way to synchronize more detailed models with real faults is to force them to reproduce the sequence of previous earthquake ruptures on the faults. This hypothesis could be tested in the future with more detailed models and actual seismic data.  相似文献   

伴随模式同化系统在修正模式地形中的应用   总被引：7，自引：1，他引：7  

李华宏  沈桐立  王曼  洪萍 《南京气象学院学报》2005,28(3):330-336

任何模式都只是实际大气的一种近似模拟，存在误差。鉴于传统的四维资料伴随模式同化系统都是假设模式完全正确仅对初始场进行修正。将伴随模式同化系统应用于修正模式地形误差，通过对不同初始地形的修正试验表明，MM5伴随模式同化系统能很好地对地形误差进行修正，能够反演出与初始气象要素场分辨率相匹配、与模式更协调的地形场，为伴随模式同化系统的广泛应用提供了一种新的思路。  相似文献   

变分同化方法在Lorenz系统中的简单应用研究   总被引：1，自引：0，他引：1       下载免费PDF全文

杜川利  黄向宇  俞小鼎 《气象》2005,31(2):23-26

利用Lorenz模式作变分同化数值试验，通过对一个简单系统的讨论，介绍四维变分同化方法。对初值敏感性和观测点的个数及观测值作了对比试验，发现随着模式对初值敏感性的增加，同化效果会越来越差；观测点越少，观测值误差越大，这些都会影响同化效果，甚至导致同化失败。  相似文献   

改进的切线性模式对一个边界层模式变分资料同化的改善   总被引：7，自引：0，他引：7  

Zhu Jiang  Wang Hui  Masafumi Kamachi 《大气科学进展》2002,19(4):563-582

大气、海洋中边界层物理过程的强非线性会对切线性模式近似（尤其是当积分时间长时）有较大的影响，从而给相应的4维变分资料同化问题的求解造成困难。本构造了Mellor-Yamada湍流封闭模式（level 2.5)的一个改进的切线性模式，相比通常的切线性模式和简化的切线性模式可以提高对非线性扰动的逼近。利用这个改进的切线性模式的伴随模式分别进行了1到7天的变分资料同化试验，得到了满意的结果。而用通常的伴随模式和简化的伴随模式都无法得到令人满意的结果。  相似文献