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91.
在 L i Br与水的物质量比分别为 1∶ 64、1∶ 32、1∶ 16、1∶ 8、1∶ 4和 1∶ 3的情况下 ,对 L i Br溶液从低温到高温的分子动力学模拟进行了研究。随浓度增加 ,锂离子的水合数量呈减少趋势但同时又从 L i+- Br-接触离子对的数量增加中得到补偿 ,而 L i离子的第一配位壳层的配位数量保持不变。在高浓度 Li Br溶液中 ,Br- O之间的距离有所增加 ,Br-- O的径向分布的形状更趋于非对称 ,从而很好地确定了 Br离子水合壳层 L i+- Br-接触离子对可以在更稀的溶液中产生 ,但随浓度增加而增加。L i+- Br-距离明显短于溶液中 Li离子与 Br离子的离子半径之和 ,也短于 L i Br晶体中两者离子半径之和。高浓度溶液中水分子的结构几乎被破坏 ,水分子间的氢键明显增加 ,但没有消失。对 L i+、Br-和水的扩数系数计算值与实验值进行了比较 相似文献
92.
93.
A new technique to determine geoid and orthometric heights from satellite positioning and geopotential numbers 总被引:1,自引:0,他引:1
L. E. Sjöberg 《Journal of Geodesy》2006,80(6):304-312
This paper takes advantage of space-technique-derived positions on the Earth’s surface and the known normal gravity field to determine the height anomaly from geopotential numbers. A new method is also presented to downward-continue the height anomaly to the geoid height. The orthometric height is determined as the difference between the geodetic (ellipsoidal) height derived by space-geodetic techniques and the geoid height. It is shown that, due to the very high correlation between the geodetic height and the computed geoid height, the error of the orthometric height determined by this method is usually much smaller than that provided by standard GPS/levelling. Also included is a practical formula to correct the Helmert orthometric height by adding two correction terms: a topographic roughness term and a correction term for lateral topographic mass–density variations. 相似文献
94.
We investigate the relative dispersion properties of the well-mixed class of Lagrangian stochastic models. Dimensional analysis
shows that, given a model in the class, its properties depend solely on a non-dimensional parameter, which measures the relative
weight of Lagrangian-to-Eulerian scales. This parameter is formulated in terms of Kolmogorov constants, and model properties
are then studied by modifying its value in a range that contains the experimental variability. Large variations are found
for the quantity, g* = 2gC0− 1, where g is the Richardson constant. 相似文献
95.
96.
A cross-sectional non-hydrostatic model with idealized topography was used to examine the processes influencing tidal mixing
in the region of sills. Initial calculations with appropriate parameters for the sill at the entrance to Loch Etive showed
that the model could reproduce the main features of the observed mixing in the region. In particular, the hydraulic jump in
the sill region was reproduced, as was an intense mid-water jet that was observed to separate from the lee side of the sill.
Shear instabilities associated with the jet appeared to be a source of mixing within the thermocline. In addition, internal
lee waves were generated on the lee side of the sill, with the observed amplification because of trapping during the flood
stage. Their magnitude and hence the mixing increased with increasing Froude number (F
r). In the case of vertically varying buoyancy frequency, its value near the sill top determined the F
r number, with its value below influencing internal waves magnitude at depth. At high F
r values particularly with strong currents, short waves and overturning occurred. 相似文献
97.
98.
The atmospheric spectral transparency variations at 344 nm and 369 nm, averaged at eight Soviet stations between 69°N and 55°N, have been compared with sunspot numbers, or Wolf numbers (WN). The data were taken for the seasonal interval May-August during the period 1972 – 1989. Good negative correlations –0.76 and –0.82 have been found. The correlation coefficient between aerosol extinction at 344 nm and WN is equal to +0.75. Insignificant correlation is found for the transparency variations at 344 nm for stations situated to the south of latitude 50°. The best correlation with WN for both transparency and aerosol extinction at northern stations occurs for the shift of WN ahead of the optical parameters by 6 months.
The connection of transparency with cosmic rays in Apatity is also examined. It displays a sign opposite to that for WN, smaller values of the correlation coefficient, and an improbable shift of transparency ahead of cosmic ray intensity.
The relative changes of the transparency during a solar cycle can be evaluated at 10% in the ozone-free UVA region 相似文献
99.
Abstract The physically-based flood frequency models use readily available rainfall data and catchment characteristics to derive the flood frequency distribution. In the present study, a new physically-based flood frequency distribution has been developed. This model uses bivariate exponential distribution for rainfall intensity and duration, and the Soil Conservation Service-Curve Number (SCS-CN) method for deriving the probability density function (pdf) of effective rainfall. The effective rainfall-runoff model is based on kinematic-wave theory. The results of application of this derived model to three Indian basins indicate that the model is a useful alternative for estimating flood flow quantiles at ungauged sites. 相似文献
100.
The curve number (CN) method is widely used for rainfall–runoff modelling in continuous hydrologic simulation models. A sound continuous soil moisture accounting procedure is necessary for models using the CN method. For shallow soils and soils with low storage, the existing methods have limitations in their ability to reproduce the observed runoff. Therefore, a simple one‐parameter model based on the Soil Conservation Society CN procedure is developed for use in continuous hydrologic simulation. The sensitivity of the model parameter to runoff predictions was also analysed. In addition, the behaviour of the procedure developed and the existing continuous soil moisture accounting procedure used in hydrologic models, in combination with Penman–Monteith and Hargreaves evapotranspiration (ET) methods was also analysed. The new CN methodology, its behaviour and the sensitivity of the depletion coefficient (model parameter) were tested in four United States Geological Survey defined eight‐digit watersheds in different water resources regions of the USA using the SWAT model. In addition to easy parameterization for calibration, the one‐parameter model developed performed adequately in predicting runoff. When tested for shallow soils, the parameter is found to be very sensitive to surface runoff and subsurface flow and less sensitive to ET. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献