Influence of Temporal Variations in River Discharge, pH, Alkalinity and Ca on the Speciation and Concentration of Heavy Metals in Some Mining Polluted Rivers     

Pål Gundersen  Eiliv Steinnes 《Aquatic Geochemistry》2001,7(3):173-193

Dissolved (dialysis in situ) and total concentrations ofCu, Zn, Cd and Al in eight mining polluted rivers in the Røros area, central Norway, were determinedby atomic absorption spectrometry (flame and graphite furnace) and compared to pH, Caconcentration and alkalinity through seasonal variations in river discharge. Totalconcentrations of the metals were highest during early spring flood and during summer andautumn rain episodes. Dissolved concentrations also increased as the spring floodproceeded, but small discharge peaks within this 2 month period as well as a considerableautumn flood episode appeared to lower rather than to raise the dissolved metal concentrations.Consequently the dissolved fractions of Zn, Cd and Al showed a significant negative correlationwith river discharge, and were low at the discharge peaks. Possibly high sediment concentrationsoccurring at high flood conditions more than counteracted desorption induced by pHdecrease, and led to decreased dissolved fractions through adsorption. Cu speciationon the other hand seemed to be more closely linked to pH. Alkalinity and Ca concentration,both assumed to protect aquatic life from metal pollution, were significantly lowerduring episodes with high Cu and Al total concentrations.  相似文献   

云南白水台钙华水池中水化学日变化及其生物控制的发现   总被引：11，自引：0，他引：11  

刘再华  李强  孙海龙  汪进良  吴孔运 《水文地质工程地质》2005,32(6):10-15

为弄清云南白水台泉及其下游钙华水池中水化学的日变化,选取1号泉及其流经的两个钙华水池(6号和10号)作为研究对象并对其水温、pH值和电导率进行了自动监测。根据Ca2 、HCO3-与电导率存在的线性关系,用WATSPAC软件计算了水中方解石的饱和指数和PCO2。监测发现:泉水不存在显著的水化学日动态变化,而两个钙华水池表现出显著的日动态变化。其中10号钙华水池在白天温度较高时水中的CO2大量逸出并通过水下水生植物的光合作用加速了水中碳酸钙的沉积。6号钙华水池水生植物生长茂盛,其叶片和部分枝干露出水面,因而光合作用主要发生在空中,所以此处水化学表现为白天pH值降低和电导率升高的反常现象,即由温度主导的根呼吸作用,在白天释放更多的CO2进入水体而使沉积下来的碳酸钙重新溶解。  相似文献   

Research on runoff variations based on wavelet analysis and wavelet neural network model: A case study of the Heihe River drainage basin (1944?2005)     

WANG Jun  MENG Jijun 《地理学报》2007,17(3):327-338

The Heihe River drainage basin is one of the endangered ecological regions of China. The shortage of water resources is the bottleneck, which constrains the sustainable development of the region. Many scholars in China have done researches concerning this problem. Based on previous researches, this paper analyzed characteristics, tendencies, and causes of annual runoff variations in the Yingluo Gorge (1944–2005) and the Zhengyi Gorge (1954–2005), which are the boundaries of the upper reaches, the middle reaches, and the lower reaches of the Heihe River drainage basin, by wavelet analysis, wavelet neural network model, and GIS spatial analysis. The results show that: (1) annual runoff variations of the Yingluo Gorge have principal periods of 7 years and 25 years, and its increasing rate is 1.04 m3/s·10y; (2) annual runoff variations of the Zhengyi Gorge have principal periods of 6 years and 27 years, and its decreasing rate is 2.25 m3/s·10y; (3) prediction results show that: during 2006–2015, annual runoff variations of the Yingluo and Zhengyi gorges have ascending tendencies, and the increasing rates are respectively 2.04 m3/s·10y and 1.61 m3/s·10y; (4) the increase of annual runoff in the Yingluo Gorge has causal relationship with increased temperature and precipitation in the upper reaches, and the decrease of annual runoff in the Zhengyi Gorge in the past decades was mainly caused by the increased human consumption of water resources in the middle researches. The study results will provide scientific basis for making rational use and allocation schemes of water resources in the Heihe River drainage basin.  相似文献   

Crustacean zooplankton distribution patterns and their biomass as related to trophic indicators of 29 shallow subtropical lakes   总被引：3，自引：0，他引：3  

Songbo Wang  Ping Xie  Shikai Wu  Aiping Wu 《Limnologica》2007,37(3):242-249

A comparative limnological study was carried out to present a snapshot of crustacean zooplankton communities and their relations to environmental factors to test whether there is a consistent relationship between crustacean biomass and trophic indicators among lake groups with similar trophic conditions. The study lakes showed a wide range of trophic status, with total phosphorus (TP) ranging from 0.008 to 1.448 mg L⁻¹, and chlorophyll a from 0.7 to 146.1 μg L⁻¹, respectively. About 38 species of Crustacea were found, of which Cladocera were represented by 25 taxa (20 genera), and Copepoda by 13 taxa (11 genera). The most common and dominant species were Bosmina coregoni, Moina micrura, Diaphanosoma brachyurum, Cyclops vicinus, Thermocyclops taihokuensis, Mesocyclops notius and Sinocalanus dorrii. Daphnia was rare in abundance. Canonical correspondence analysis showed that except for four species (D. hyalina, S. dorrii, C. vicinus and M. micrura), almost all the dominant species had the same preference for environmental factors. Temperature, predatory cyclopoids and planktivorous fishes seem to be the key factors determining species distribution. TP was a relatively better trophic indicator than chlorophyll a to predict crustacean biomass. Within the three groups of lakes, however, there was no consistent relationship between crustacean biomass and trophic indicators. The possible reason might be that top-down and bottom-up control on crustaceans vary with lake trophic state. The lack of significant negative correlation between crustacean biomass and chlorophyll a suggests that there was little control of phytoplankton biomass by macrozooplankton in these shallow subtropical lakes.  相似文献   

Stratospheric warming effects on the tropical mesospheric temperature field   总被引：1，自引：0，他引：1  

M.G. Shepherd  D.L. Wu  I.N. Fedulina  S. Gurubaran  J.M. Russell  M.G. Mlynczak  G.G. Shepherd 《Journal of Atmospheric and Solar》2007,69(17-18):2309

Temperature observations at 20–90 km height and 5–15°N during the winter of 1992–1993, 1993–1994 and 2003–2004, from the Wind Imaging Interferometer (WINDII) and Microwave Limb Sounder (MLS) experiments on the Upper Atmosphere Research Satellite (UARS) satellite and the Sounding the Atmosphere using Broadband Emission Radiometry (SABER) experiment on the Thermosphere, Ionosphere, Mesosphere Energetics and Dynamics (TIMED) satellite are analyzed together with MF radar winds and UK Meteorological Office (UKMO) assimilated fields. Mesospheric cooling is observed at the time of stratospheric warming at the tropics correlative with stratospheric warming events at middle and high latitudes. Planetary waves m=1 with periods of 4–5, 6–8, 10 and 12–18 days are found to dominate the period. Westward 7- and 16-day waves at the tropics appear enhanced by stationary planetary waves during sudden stratospheric warming events.  相似文献   

Thermal surface characteristics of coal fires 1 results of in-situ measurements     

Jianzhong Zhang  Claudia Kuenzer   《Journal of Applied Geophysics》2007,63(3-4):117-134

Natural underground coal fires are fires in coal seams occurring subsurface. The fires are ignited through a process named spontaneous combustion, which occurs based on a natural reaction but is usually triggered through human interaction. Coal mining activities expose coal to the air. This leads to the exothermal oxidation of the carbon in the coal with the air's oxygen to CO₂ and – under certain circumstances – to spontaneous combustion. Coal fires occur in many countries world wide – however, currently the Chinese coal mining industry faces the biggest problems with coal fires. Coal fires destroy the valuable resource coal and furthermore lead to many environmental degradation phenomena such as the deterioration of surrounding vegetation, land subsidence and the emission of toxic gasses (CO, N₂O). They additionally contribute to the emission of green house relevant gasses such as CO₂ and CH₄ to the atmosphere.In this paper we present thermal characteristics of coal fires as measured in-situ during a field campaign to the Wuda coal fire area in south-central Inner Mongolia, China. Thermal characteristics include temperature anomaly measurements at the surface, spatial surface temperature profiles of fire areas and unaffected background areas, diurnal temperature profiles, and temperature measurements inside of coal fire induced cracks in the overlying bedrock. For all the measurements the effects of uneven solar heating through influences of slope and aspect are considered.Our findings show that coal fires result in strong or subtle thermal surface anomalies. Especially the latter can easily be influenced by heating of the surrounding background material through solar influences. Temperature variation of background rocks with different albedo, slope, aspect or vegetation cover can substantially influence the detectability of thermal anomalies. In the worst case coal fire related thermal anomalies can be completely masked by solar patterns during the daytime. Thus, night-time analysis is the most suitable for thermal anomaly mapping of underground coal fires, although this is not always feasible. The heat of underground coal fires only progresses very slowly through conduction in the rock material. Anomalies of coal fires completely covered by solid unfractured bedrock are very weak and were only measured during the night. The thermal pattern of underground coal fires manifested on the surface during the daytime is thus the pattern of cracks and vents, which occur due to the volume loss underground and which support radiation and convective energy transport of hot gasses. Inside coal fire temperatures can hardly be measured and can only be recorded if the glowing coal is exposed through a wider crack in the overlaying bedrock. Direct coal fire temperatures measured ranged between 233 °C and 854 °C. The results presented can substantially support the planning of thermal mapping campaigns, analyses of coal fire thermal anomalies in remotely sensed data, and can provide initial and boundary conditions for coal fire related numerical modeling.In a second paper named “Thermal Characteristics of Coal Fires 2: results of measurements on simulated coal fires” [Zhang J., Kuenzer C., Tetzlaff A., Oettl D., Zhukov B., Wagner W., 2007. Thermal Characteristics of Coal Fires 2: Result of measurements on simulated coal fires. Accepted for publication at Journal of Applied Geophysics. doi:10.1016/j.jappgeo.2007.08.003] we report about thermal characteristics of simulated coal fires simulated under simplified conditions. The simulated set up allowed us to measure even more parameters under undisturbed conditions — especially inside fire temperatures. Furthermore we could demonstrate the differences between open surface coal fires and covered underground coal fires. Thermal signals of coal fires in near range thermal remotely sensed imagery from an observing tower and from an airplane are presented and discussed.  相似文献   

Application of wavelet transformation to determine wavelengths and phase velocities of gravity waves observed by lidar measurements     

R. Werner  K. Stebel  G.H. Hansen  U. Blum  U.-P. Hoppe  M. Gausa  K.-H. Fricke 《Journal of Atmospheric and Solar》2007,69(17-18):2249

During the last two decades, important advances have been made in the investigation of gravity waves. However, more efforts are needed to study certain aspects of gravity waves. In the real atmosphere, gravity waves occur with different properties at different altitudes and, most often, simultaneously. In this case, when there is more than one dominant wave, the determination of gravity wave characteristics, such as the vertical wavelength and the phase velocity, is difficult. The interpretation of temperature perturbation plots versus the altitude and time as well as the application of the Fourier spectral analysis can produce errors.Exact knowledge of the wave characteristics is important both for determination of other characteristics, for example, the horizontal wave components, and for study of wave climatology. The wavelet analysis of vertical temperature profiles allows one to examine the wave's location in space. Up to now, gravity waves have been studied mainly by continuous wavelet transformation to determine dominant waves. We apply wavelet analysis to a time series of temperature profiles, observed by the ALOMAR ozone lidar at Andoya, Norway, and by the U. Bonn lidar system at ESRANGE, Sweden, both for determination of the dominant waves and for specifying the vertical wavelengths and the vertical component of the phase velocities. For this purpose, the wavelet amplitude spectra and the wavelet phase spectra are filtered and Hovmöller diagrams for dominant wavelengths are constructed. The advantage of this type of diagrams is that they give clear evidence for the localization of the dominant waves in space and time and for the development of their phase fronts.  相似文献   

降水和温度MOS预报方法探讨     

吴爱敏 《干旱气象》2002,20(3):1-3

文中分析了庆阳地区春季降水气候特征和环流形势 ,用 1995～ 1998年 3～ 5月T10 6资料建立了该区 8县 (市 )春季降水、温度MOS预报方程 ,进行了回代检验和试报 ,并提出了模式更换后的处理方法  相似文献   

近40年高层温度场和高度场的时空变化特征   总被引：3，自引：0，他引：3  

毕云  钱永甫 《南京气象学院学报》2001,24(1):59-65

用4种方式对NCEP／NCAR全球再分析资料中1958－1997年300hPa月均温度、100hPa月均高度资料序列进行对比分析，发现300hPa温度资料可靠性高于100hPa高度资料；详细考察近40a高层温度场、高度场的时空变化特征，并通过Morlet小波进一步分析两要素场的周期变化发现，温度场和高度场的EOF第1模态具有很好的空间整体民生和明显的年际和年代际变化，以10a左右和3a左右的周期为主要周期。  相似文献   

一种插值相似方法作温度预测的应用研究   总被引：1，自引：1，他引：1  

张万诚  解明恩等 《气象科学》2001,21(2):241-245

将插值方法运用到短期气象预测中，其基本原理是按照相似原理将产生相似结果来作预报。对云南昆明等四站温度进行了九年定性和定量预报检验，结果表明：这种方法具有良好的预报能力，可以作要素预报应用。  相似文献