Nitrogen and sulfur species in Antarctic aerosols at Mawson,Palmer Station,and Marsh (King George Island)   总被引：4，自引：0，他引：4  

D. L. Savoie  J. M. Prospero  R. J. Larsen  F. Huang  M. A. Izaguirre  T. Huang  T. H. Snowdon  L. Custals  C. G. Sanderson 《Journal of Atmospheric Chemistry》1993,17(2):95-122

High volume bulk aerosol samples were collected continuously at three Antarctic sites: Mawson (67.60° S, 62.50° E) from 20 February 1987 to 6 January 1992; Palmer Station (64.77° S, 64.06° W) from 3 April 1990 to 15 June 1991; and Marsh (62.18° S, 58.30° W) from 28 March 1990, to 1 May 1991. All samples were analyzed for Na⁺, SO ₄ ^2– , NO ₃ ^– , methanesulfonate (MSA), NH ₄ ⁺ ,²¹⁰Pb, and⁷Be. At Mawson for which we have a multiple year data set, the annual mean concentration of each species sometimes vary significantly from one year to the next: Na⁺, 68–151 ng m^–3; NO ₃ ^– , 25–30 ng m^–3; nss SO ₄ ^2– , 81–97 ng m^–3; MSA, 19–28 ng m^–3; NH ₄ ⁺ , 16–21 ng m^–3;²¹⁰Pb, 0.75–0.86 fCi m^–3. Results from multiple variable regression of non-sea-salt (nss) SO ₄ ^2– with MSA and NO ₃ ^– as the independent variables indicates that, at Mawson, the nss SO ₄ ^2– /MSA ratio resulting from the oxidation of dimethylsulfide (DMS) is 2.80±0.13, about 13% lower than our earlier estimate (3.22) that was based on 2.5 years of data. A similar analysis indicates that the ratio at Palmer is about 40% lower, 1.71±0.10, and more comparable to previous results over the southern oceans. These results when combined with previously published data suggest that the differences in the ratio may reflect a more rapid loss of MSA relative to nss SO ₄ ^2– during transport over Antarctica from the oceanic source region. The mean²¹⁰Pb concentrations at Palmer and Marsh and the mean NO ₃ ^– concentration at Palmer are about a factor of two lower than those at Mawson. The²¹⁰Pb distributions are consistent with a²¹⁰Pb minimum in the marine boundary layer in the region of 40°–60° S. These features and the similar seasonalities of NO ₃ ^– and²¹⁰Pb at Mawson support the conclusion that the primary source regions for NO ₃ ^– are continental. In contrast, the mean concentrations of MSA, nss SO ₄ ^2– , and NH ₄ ⁺ at Palmer are all higher than those at Mawson: MSA by a factor of 2; nss SO ₄ ^2– by 10%; and NH ₄ ⁺ by more than 50%. However, the factor differences exhibit substantial seasonal variability; the largest differences generally occur during the austral summer when the concentrations of most of the species are highest. NH ₄ ⁺ /(nss SO ₄ ^2– +MSA) equivalent ratios indicate that NH₃ neutralizes about 60% of the sulfur acids during December at both Mawson and Palmer, but only about 30% at Mawson during February and March.  相似文献   

Application of objective analysis to metallic traces in the atmospheric aerosol     

Christophe Migon  Bernard Gentili 《Journal of Atmospheric Chemistry》1993,16(3):277-284

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气态SO_2转化及其数值模型研究     

杨礼荣  任阵海  林子瑜 《大气科学》1993,17(3):328-337

本文基于对室外烟雾箱实验,探讨了SO_2的转化机制及影响SO_2转化的因素,由此并借助于烟团模型,建立了SO_2转化和硫酸盐气溶胶细粒子生成的数值模型,用于估算从排放源排入大气的SO_2浓度及其转化成硫酸盐细粒子的浓度以及它们的空间分布,与实测结果相比,两者有较好的一致性.同时指出,由于大气中细粒子(粒径小于1μm)可通过人体呼吸进入并沉积在肺泡中而对健康有不利影响,从而说明研究大气中细粒子污染的迫切性.  相似文献   

长春台磁暴特征研究     

岳庆祥 《东北地震研究》1993,(1)

依据长春地震台记录的磁暴资料,系统总结了第19、20、21三个太阳活动周磁暴特征,并对全球M_s≥7.8级地震的发生与太阳黑子活动、磁暴的关系进行了初步探讨。  相似文献   

COMPARISON OF AEROSOL CHARACTERISTICS OVER MAINLAND OF CHINA AND WESTERN PACIFIC AND ITS LONG-RANGE TRANSPORT          下载免费PDF全文

Wen Yupu  Yang Shaojin  Yang Yinan  Chen Bingru  Zhou Mingyu  Zheng Yueming  Zhang Ziyu  Yu Hongjian 《Acta Meteorologica Sinica》1991,5(2):160-170

Based on the aerosol data obtained at Shangdianzi regional background monitoring station together withthe air trajectory analysis,the chemical constituents of the aerosol from the different sources are discussed andcompared with the aerosol samples collected over the western Pacific.The results show that the relative massconcentrations of the crustal and pollutant elements in the aerosol collected over the ocean are higher than thosebeing observed at Shangdianzi in particle size above 4.7 μm and below 0.65μm in diameter.The variationsof the enrichment factors of these elements in marine aerosol with particle size are different from those in shang-dianzi's samples.The former enrichment factors are evidently higher than the latter above 1.1 μm in diameter.On the basis of the comparative research,the long-range transport processes of aerosol particles are discussed.  相似文献   

低Peclet数下剪切流中气溶胶粒子的传质率     

温景嵩  曾庆存  王永光 《大气科学》1994,18(1):105-112

本文研究了低Péclet数下剪切流中气溶胶粒子的传质率。Péclet数(Pe)是物质浓度的对流输送项对分子扩散项的比。它等于Reynolds数(Re)与Schmidt数的(Sc)之积。本文应用奇异扰动方法得到了无因次传质率Nu(Nusselt数)在小Péclet数条件下的四项渐近展式，因而?改进了前人的结果。  相似文献   

The impact of high altitude aircraft on the ozone layer in the stratosphere     

Xue Xi Tie  Guy Brasseur  Xing Lin  Pierre Friedlingstein  Claire Granier  Philip Rasch 《Journal of Atmospheric Chemistry》1994,18(2):103-128

The paper discusses the potential effects on the ozone layer of gases released by the engines of proposed high altitude supersonic aircraft. The major problem arises from the emissions of nitrogen oxides which have the potential to destroy significant quantities of ozone in the stratosphere. The magnitude of the perturbation is highly dependent on the cruise altitude of the aircraft. Furthermore, the depletion of ozone is substantially reduced when heterogeneous conversion of nitrogen oxides into nitric acid on sulfate aerosol particles is taken into account in the calculation. The sensitivity of the aerosol load on stratospheric ozone is investigated. First, the model indicates that the aerosol load induced by the SO₂ released by aircraft is increased by about 10–20% above the background aerosols at mid-high latitude of the Northern Hemisphere at 15 km for the NASA emission scenario A (the NASA emission scenarios are explained in Tables I to III). This increase in aerosol has small effects on stratospheric ozone. Second, when the aerosol load is increased following a volcanic eruption similar to the eruption of El Chichon (Mexico, April 1982), the ozone column in spring increases by as much as 9% in response to the injection of NO _x from the aircraft with the NASA emission scenario A. Finally, the modeled suggests that significant ozone depletion could result from the formation of additional polar stratospheric clouds produced by the injection of H₂O and HNO₃ by the aircraft engines.  相似文献   

The influence of aerosol particle composition on cloud droplet formation     

A. Hallberg  J. A. Ogren  K. J. Noone  K. Okada  J. Heintzenberg  I. B. Svenningsson 《Journal of Atmospheric Chemistry》1994,19(1-2):153-171

A difference in partitioning between cloud droplets and interstitial air for two chemical species (elemental carbon and sulphur) with different expected behaviour in nucleation scavenging was observed in clouds at Mt. Kleiner Feldberg (825 m asl), near Frankfurt, Germany. The fraction of sulphur incorporated in cloud droplets was always higher than the fraction of elemental carbon. This difference in partitioning has also been observed in fog but under different pollution conditions in the Po Valley, Italy. Both these studies were based on bulk samples. In the present study at Kleiner Feldberg, impactor samples of the particles in the interstitial air and the cloud droplet residuals were taken and a single particle analysis was done on the samples. It was found that, for a given particle size, the majority of particles forming cloud droplets were soluble and that insoluble particles preferentially remained in the interstitial air.  相似文献   

大气有机污染分析和评价I．采样方法及采样误差     

郎庆勇 《岩矿测试》1994,(3)

对近１０年来国外有关大气污染物的采样方法、有机污染物在气、固相中的分配以及采样误差的主要文献做了简要回顾。对不同采样器的采样效率、误差来源及误差校正方法进行了讨论。列举了一些富有指导意义的研究成果和结论。可以看出，在消除或限制了采样误差后，所得分析结果为客观评价环境污染问题提供了更可靠的依据。  相似文献   

BALLOON-BORNE MEASUREMENTS OF AEROSOL VERTICAL DISTRIBUTIONS OVER BEIJING DURING THE SUMMER AND AUTUMN OF 1993          下载免费PDF全文

Zhou Jun  Tan Kun  Shao Shisheng  Gong Zhiben  Shi Guangyu  Guo Jiandong  Wang Biao  Zhang Baowu  Sun Baolai  Yasunobu Iwasak  Masahiko Hayashi  Masahiro Hase 《Acta Meteorologica Sinica》1994,8(4):478-487

The results of two balloon soundings during the summer and autumn of 1993 from the Xianghe Observation Station are being utilized in a study of the temporal and spatial distribution of the atmospheric aerosols.The balloon,gondola,instrumentation and atmospheric conditions during the observation period are described.The temporal and spatial characteristics of aerosol concentration,size ratio,mixing ratio,and size distribution for both troposphere and strato-sphere are presented and analyzed.  相似文献