Assessing the Comparability of Ammonium,Nitrate and Sulfate Concentrations Measured by Three Air Quality Monitoring Networks     

Edith L Gego  P. Steven Porter  John S. Irwin  Christian Hogrefe  S. Trivikrama Rao 《Pure and Applied Geophysics》2005,162(10):1919-1939

Airborne fine particulate matter across the United States is monitored by different networks, the three prevalent ones presently being the Clean Air Status and Trend Network (CASTNet), the Interagency Monitoring of PROtected Visual Environment Network (IMPROVE) and the Speciation and Trend Network (STN). If combined, these three networks provide speciated fine particulate data at several hundred locations throughout the United States. Yet, differences in sampling protocols and samples handling may not allow their joint use. With these concerns in mind, the objective of this study is to assess the spatial and temporal comparability of the sulfate, nitrate and ammonium concentrations reported by each of these networks. One of the major differences between networks is the sampling frequency they adopted. While CASTNet measures pollution levels on seven-day integrated samples, STN and IMPROVE data pertain to 24-hour samples collected every three days. STN and IMPROVE data therefore exhibit considerably more short-term variability than their CASTNet counterpart. We show that, despite their apparent incongruity, averaging the data with a window size of four to six weeks is sufficient to remove the effects of differences in sampling frequency and duration and allow meaningful comparison of the signals reported by the three networks of concern. After averaging, all the sulfate and, to a lesser degree, ammonium concentrations reported are fairly similar. Nitrate concentrations, on the other hand, are still divergent. We speculate that this divergence originates from the different types of filters used to collect particulate nitrate. Finally, using a rotated principal component technique (RPCA), we determined the number and the geographical organization of the significant temporal modes of variation (clusters) detected by each network for the three pollutants of interest. For sulfate and ammonium, the clusters’ geographical boundaries established for each network and the modes of variations within each cluster seem to correspond. RPCA erformed on nitrate concentrations revealed that, for the CASTNet and IMPROVE networks, the modes of variation do not correspond to unified geographical regions but are found more sporadically. For STN, the clustered areas are unified and easily delineable. We conclude that the possibility of jointly using the data collected by CASTNet, IMPROVE and STN has to be weighed pollutant by pollutant. While sulfate and ammonium data show some potential for joint use, at this point, combining the nitrate data from these monitoring networks may not be a judicious choice.  相似文献   

Assessment of regional air pollution distribution by point cumulative semivariogram method at Erzurum urban center, TURKEY     

F. S. Turalioglu  H. Bayraktar 《Stochastic Environmental Research and Risk Assessment (SERRA)》2005,19(1):41-47

In the assessment of air quality, regional distribution and dispersion with distance are important, together with the variations of pollutants in time. On this occasion, the point cumulative semi-variogram (PCSV) method is used in order to find simply regional distribution of pollutants of Erzurum urban centre. This method is based simply on the summation of square differences in air pollutant concentrations between different sites. Monthly regional variation maps of Erzurum are constructed by finding radius of influence (for SO₂, from 1000 m to 3500 m and, for TSP, 1000–2000 m) and PCSV scattering diagram data at different levels by using monthly average sulphur dioxide (SO₂) and total suspended particulate (TSP) matter concentrations in 2001–2002 winter season. Consequently, the air pollution distribution of Erzurum is assessed.  相似文献   

A Possible Detection of the 26 December 2004 Great Sumatra-Andaman Islands Earthquake with Solution Products of the International GNSS Service   总被引：1，自引：0，他引：1  

J. Kouba 《Studia Geophysica et Geodaetica》2005,49(4):463-483

The main goal of this work is to critically review the IGS solution products and Precise Point Positioning (PPP) in order to demonstrate their potential to contribute to studies of large earthquakes such as the one that devastated Southeast Asia on December 26th, 2004. In view of a possible detection of the Mw 9.0 Sumatra-Andaman Islands Earthquake of December 26, 2004, position solutions, ranging from intervals of years to one second, of four International GNSS Service (IGS) stations within 3000 km of the epicenter were examined. The IGS combined, cumulative solution product (IGS04P51), consisting of epoch and station velocity solutions and based on data spans of several years prior to the earthquake, was used as a reference. Four IGS combined weekly position solutions (igs04P1301-4), two weeks before and after the earthquake, were utilized for the weekly solution resolution. PPP static and kinematic solutions with IGS Final combined orbits and clocks were used for the mean daily and instantaneous 5-min and 1-sec epoch solutions, respectively. The most significant changes, detected by both weekly and daily solutions occurred in longitude. The nearest IGS station ntus, about 1000 km east of the epicenter, moved westward about 15 mm, while the more distant Indian station iisc (∼ 2300 km NW from the epicenter), shifted about 15 mm eastward. In spite of position errors caused by interpolation of the 5-min IGS clocks, the 1-sec solutions, based on separate data sets, available only for two stations (iisc, dgar), still showed seismic surface waves, in particular at the Indian station iisc. Precise daily IGS combined polar motion and length-of-day products, after correcting for the atmospheric effects, also likely detected, statistically significant, anomalistic excitations on December 26, 2004 that could be caused by this great earthquake.  相似文献   

Profondeur d'extraction racinaire et signature isotopique de l'eau prélevée par les racines des couverts végétaux     

Zakaria Boujamlaoui  Thierry Bariac  Philippe Biron  Laurent Canale  Patricia Richard 《Comptes Rendus Geoscience》2005,337(6):589-598

We seek to identify the depth to which water is extracted by the roots in the soil. Indeed, in an isotopic steady-state condition of leaf water, transpiration introduces into the atmosphere a vapour whose isotopic signature is identical to that of root water. In the isotopic models of atmospheric general circulation, it is classically allowed that the signature of transpiration belongs to the meteoric water line. This supposes that the water taken by the roots has escaped with the evaporation of the soil and comes thus from the deep layers of the soil. At the time of experimentation carried out on maize plants (Nemours, Seine-et-Marne, France), this extraction depth was inferred from the comparison between the signature of the water measured on the level of the first internode of the stems of the plants and the isotopic profile of water in the soil. When the flow of transpiration reaches a maximum value, the plant uptakes water resulting from precipitations and which preserves its non-evaporating character after having quickly infiltrated in the deep layers of the soil. This relates to only 55% of the flux transpired by the canopy, the remainder presenting an evaporating character more or less marked according to ambient conditions. This experiment invalidates the classical hypothesis used in isotopic models of general atmospheric circulation in temperate regions. In fact, only half the amount of water vapour transpired by the canopy during the day presents a signature similar to that of the rainwater sampled in deep soil layers. To cite this article: Z. Boujamlaoui et al., C. R. Geoscience 337 (2005).  相似文献   

“雪龙号”2003北极航次气相多环芳烃纬度分布观测          下载免费PDF全文

丁翔  谢周清  向彩红  麦碧娴  王新明  孙立广  盛国英  傅家谟 《极地研究》2005,17(4):272-278

2003年“雪龙号”北极科学考察期间,对沿途海洋大气进行采样,分析其中气相多环芳烃的空间分布。结果显示,气相中主要是2-4环的多环芳烃,其中菲为主要的化合物,平均占到总多环芳烃的55.1%。在整个航程的广泛区域尺度内,气相总多环芳烃浓度在1043.9-92993.1pg/m3。空间分布上,远东亚的海面>北太平洋海面>北极圈以内海面;总多环芳烃的浓度随纬度升高呈现显著降低的趋势。通过Clausius-Clapeyron方程对浓度和温度相互关系的分析表明,温度是控制气相多环芳烃长距离传输的主要因素。  相似文献   

The 2019 Brumadinho tailings dam collapse: Possible cause and impacts of the worst human and environmental disaster in Brazil     

《International Journal of Applied Earth Observation and Geoinformation》2020

On 25th January 2019, the tailings dam of the Brumadinho iron mine operated by Vale S/A failed catastrophically. The death toll stood at 259 and 11 people remained missing as of January 2020. This tragedy occurred three years after Mariana’s tailings dam rupture – the most significant tailing dam disaster in Brazilian history. Thus far, a systematic investigation on the cause and effect of the failure has yet to be conducted. Here, we use satellite-driven soil moisture index, multispectral high-resolution imagery and Interferometric Synthetic Aperture Radar (InSAR) products to assess pre-disaster scenarios and the direct causes of the tailings dam collapse. A decreasing trend in the moisture content at the surface and the full evanescence of pond water through time (2011–2019) suggest that the water was gradually penetrating the fill downwards and caused the seepage erosion, saturating the tailings dam. Large-scale slumping of the dam (extensional failure) upon the rupture indicates that the materials of the fill were already saturated. InSAR measurements reveal a dramatic, up to 30 cm subsidence in the dam (at the rear part) within the past 12 months before the dam collapse, signifying that the sediments had been removed from the fill. Although the information on the resistance level of the tailings dam to infiltrations is not available, these pieces of evidence collectively indicate that the seepage erosion (piping) is the primary cause for the chronic weakening of the structure and, hence, the internal “liquefaction” condition. Upon the collapse, the fully saturated mud tailings flowed down the gentle slope area (3.13 × 10⁶ m²), where 73 % were originally covered by tree, grass or agricultural tracts. The toxic mud eventually reached the Paraopeba River after travelling 10 km, abruptly increasing the suspended particulate matter (SPM) concentration and the toxic chemical elements in the river, immediately affecting the local livelihoods that depend on its water. The Paraopeba River is a major tributary of the San Francisco River, the second-longest river in Brazil reaching the Atlantic Ocean. We anticipate that the environmental repercussions of this toxic seepage will be felt throughout the entire basin, especially riverine communities located downstream.  相似文献   

Combining two filter paper‐based analytical methods to monitor temporal variations in the geochemical properties of fluvial suspended particulate matter          下载免费PDF全文

R. J. Cooper  B. G. Rawlins  B. Lézé  T. Krueger  K. M. Hiscock 《水文研究》2014,28(13):4042-4056

Many of the commonly used analytical techniques for assessing the properties of fluvial suspended particulate matter (SPM) are neither cost effective nor time efficient, making them prohibitive to long‐term high‐resolution monitoring. We present an in‐depth methodology utilizing two types of spectroscopy which, when combined with automatic water samplers, can generate accurate, high‐temporal resolution SPM geochemistry data, inexpensively and semi‐destructively, directly from sediment covered filter papers. A combined X‐ray fluorescence spectroscopy and diffuse reflectance infrared Fourier transform spectroscopy approach is developed to estimate concentrations for a range of elements (Al, Ca, Ce, Fe, K, Mg, Mn, Na, P, Si, Ti) and compounds (organic carbon, Al_dithionate, Al_oxalate, Fe_dithionate, and Fe_oxalate) within SPM trapped on quartz fibre filters at masses as low as 3 mg. Calibration models with small prediction errors are derived, along with mass correction factor models to account for variations in retained SPM mass. Spectral pre‐processing methods are shown to enhance the reproducibility of results for some compounds, and the importance of filter paper selection and homogeneous sample preparation in minimizing spectral interference is emphasized. The geochemical signal from sediment covered filter papers is demonstrated to be time stable enabling samples to be stored for several weeks prior to analysis. Example results obtained during a heavy precipitation event in October 2012 demonstrate the methodology presented here has considerable potential to be utilized for high‐resolution monitoring of SPM geochemistry under a range of in‐stream hydrological conditions. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

巴芬湾西部和格陵兰岛东部大气经向热量输送协同变化对夏季北极海冰的影响     

王乐  张录军  杨文发 《海洋学报(英文版)》2020,39(8):14-23

利用欧洲中心气候再分析资料和美国国家冰雪数据中心北极海冰面积资料，分析了夏季北极海冰面积与前期大气经向热量输送年际变化的联系。结果表明：6月北半球中高纬大气的经向热量输送以瞬变热量形式为主，其中巴芬湾西部（B区）和格陵兰岛东部（G区）是瞬变热量向极区传输的两个通道，二者之间存在反位相的协同变化，且这种协同变化与夏季北极海冰面积变化密切相关。可能的机制为：6月，AD、AO和NAO三种北极大气环流型能够引起巴芬湾西部和格陵兰岛东部瞬变热量输送的协同变化，这种协同变化通过涡旋动力作用激发夏季极区大气表现为AD异常，同时影响途经区域的气温，从而通过热动力作用影响夏季北极海冰。将向极区输送的热量称为暖输送，从极区输出的热量为冷输送，则上述两个区域的瞬变热量协同输送可分为三种情况：B暖G冷、B冷G暖、B和G均冷，而B和G均暖的情况十分罕见。当B区向极区输入、G区输出热量时，有利于太平洋扇区和喀拉海的海冰偏少；当G区输入、B区输出热量时，利于喀拉海和拉普捷夫海海冰偏少；当B区和G区均输出热量时，利于波佛特海南部、喀拉海和拉普捷夫海海冰偏多，反之则相反。  相似文献   

2016与1998年春季北大西洋海表温度异常的差异及成因     

薛文璟  余锦华  陈林 《热带海洋学报》2020,39(3):19-30

利用再分析资料以及混合层海温诊断方程, 研究1997—1998与2015—2016年超级厄尔尼诺次年北大西洋海表温度异常(sea surface temperature anomalies, SSTA)的差异及成因。结果显示, 北大西洋SSTA在1998年春季呈明显正负正三极型式分布, 而在2016年呈弱的负正负型态。诊断热带北大西洋SSTA的影响因素表明, 1998年春季暖SSTA除了之前研究强调的海洋表面向大气的潜热输送异常减少, 以及吸收太阳辐射的增加外, 海洋动力过程即Ekman纬向漂流也起着重要的作用。热力过程与厄尔尼诺峰值后出现的北大西洋涛动(North Atlantic Oscillation, NAO)负位相有关, 其可引起亚速尔高压减弱, 产生西南风异常, 通过风-蒸发-海表温度(sea surface temperature, SST)反馈机制使热带北大西洋蒸发减弱, 海表增暖, 沃克环流下沉支的东移对这一增暖也有贡献。与1997—1998厄尔尼诺事件不同, 2015—2016厄尔尼诺事件没有强迫出负位相NAO, 而是出现弱NAO正位相, 热带北大西洋为弱的东风异常, 使海表发生一定的冷却, 形成2016春季北大西洋SSTA与1998年的明显差异。  相似文献   

Using stable isotopes to understand seasonal and interannual dynamics in moisture sources and atmospheric circulation in precipitation          下载免费PDF全文

Yu Tang  Xianfang Song  Yinghua Zhang  Dongmei Han  Likun Ai  Tianbao Zhao  Yajun Wang 《水文研究》2017,31(26):4682-4692

Stable isotopes in precipitation are useful tracers to strengthen understanding of climate change and hydrological processes. In this study, the moisture sources of 190 precipitation events in Beijing were analysed using the Hybrid Single‐particle Lagrangian Integrated Trajectory model, based on which we studied the relation between variations in precipitation δ¹⁸O and dynamics in moisture sources and atmospheric circulation in seasonal and interannual timescales. Categorization of 7 groups of moisture sources was performed, among which oceanic moisture sources presented lower δ¹⁸O in precipitation than continental moisture sources. The results show that seasonal variations of precipitation δ¹⁸O were caused by changes of moisture sources. In summer, moisture from proximal oceans dominated vapour transport to Beijing due to increasing monsoon strength and resulted in a relatively small variation of precipitation δ¹⁸O. At the interannual timescale, the variations of δ¹⁸O in summer precipitation were related to dynamics in oceanic moistures, showing depleted values when the contribution of oceanic moistures, especially the proportion of long‐distance oceanic moisture, was high. Further analysis indicated that changes of oceanic moisture sources were controlled by the strength of summer monsoons. These findings address the complexity of moisture sources in midlatitude monsoon areas and suggest that isotopic signals in precipitation have the potential to deduce changes in moisture sources and atmospheric circulation and can therefore serve for palaeoclimate reconstruction.  相似文献