A numerical study of mechanical behavior of a cement paste under mechanical loading and chemical leaching          下载免费PDF全文

Y. Jia  H.B. Bian  S.Y. Xie  N. Burlion  J.F. Shao 《国际地质力学数值与分析法杂志》2017,41(18):1848-1869

Based on relevant experimental data of a petroleum cement paste under mechanical loading and chemical leaching, an elastic‐plastic model is first proposed by taking into account plastic shearing and pore collapse. The degradation of mechanical properties induced by the chemical leaching is characterized by a chemical damage variable which is defined as the increase of porosity. Both elastic and plastic properties of the cement paste are affected by the chemical damage. The proposed model is calibrated from and applied to describe mechanical responses in triaxial compression tests respectively on sound and fully leached samples. In the second part, a phenomenological chemical model is defined to establish the relationship between porosity change and calcium dissolution process. The dissolution kinetics is governed by a diffusion law taking into account the variation of diffusion coefficient with calcium concentration. The chemical model is coupled with the mechanical model, and both are applied to describe mechanical response of cement paste samples subjected to progressive chemical leaching and compressive stresses. Comparisons between experimental data and numerical results are presented.  相似文献   

Using monazite and zircon petrochronology to constrain the P–T–t evolution of the middle crust in the Bhutan Himalaya          下载免费PDF全文

D. Regis  C. J. Warren  C. M. Mottram  N. M. W. Roberts 《Journal of Metamorphic Geology》2016,34(6):617-639

The growth and dissolution behaviour of accessory phases (and especially those of geochronological interest) in metamorphosed pelites depends on, among others, the bulk composition, the prograde metamorphic evolution and the cooling path. Monazite and zircon are arguably the most commonly used geochronometers for dating felsic metamorphic rocks, yet crystal growth mechanisms as a function of rock composition, pressure and temperature are still incompletely understood. Ages of different growth zones in zircon and monazite in a garnet‐bearing anatectic metapelite from the Greater Himalayan Sequence in NW Bhutan were investigated via a combination of thermodynamic modelling, microtextural data and interpretation of trace‐element chemical ‘fingerprint’ indicators in order to link them to the metamorphic stage at which they crystallized. Differences in the trace‐element composition (HREE, Y, Eu_N/Eu*_N) of different phases were used to track the growth/dissolution of major (e.g. plagioclase, garnet) and accessory phases (e.g. monazite, zircon, xenotime, allanite). Taken together, these data constrain multiple pressure–temperature–time (P–T–t) points from low temperature (<550 °C) to upper amphibolite facies (partial melting, >700 °C) conditions. The results suggest that the metapelite experienced a cryptic early metamorphic stage at c. 38 Ma at <550 °C, ≥0.85 GPa during which plagioclase was probably absent. This was followed by a prolonged high‐T, medium‐pressure (~600 °C, 0.55 GPa) evolution at 35–29 Ma during which the garnet grew, and subsequent partial melting at >690 °C and >18 Ma. Our data confirm that both geochronometers can crystallize independently at different times along the same P–T path and that neither monazite nor zircon necessarily provides timing constraints on ‘peak’ metamorphism. Therefore, collecting monazite and zircon ages as well as major and trace‐element data from major and accessory phases in the same sample is essential for reconstructing the most coherent metamorphic P–T–t evolution and thus for robustly constraining the rates and timescales of metamorphic cycles.  相似文献   

A probabilistic approach for computing water retention of particulate systems from statistics of grain size and tessellated pore network     

Richard Wan  Mehdi Pouragha  Mahdad Eghbalian  Jérôme Duriez  Tai Wong 《国际地质力学数值与分析法杂志》2019,43(5):956-973

The paper offers an analytical determination of the hydraulic properties of an unsaturated soil with reference to its retention curve, which describes the relationship between the volumetric water content and capillarity through matric suction. The analysis combines a particulate approach focused on the physics at the pore scale, including microstructural aspects, with a probabilistic approach where the void space and grain size are considered as random variables. In the end, the soil water characteristic curve of an unsaturated granular medium along a drying path can be derived analytically based on the sole information of particle size distribution. The analysis hinges on the tessellation of a wet granular system into an assemblage of tetrahedral unit cells revealing a pore network upon which capillary physics are computed with respect to pore throat invasion by a non-wetting fluid with evolving pendular capillary bridges. The crux of the paper is to pass from particle size probability distribution to a matching void space distribution to eventually reveal key information such as void cell and solid volume statistics. Making reasonable statistically based assumptions to render calculations tractable, the water retention curve can be readily constructed. Model predictions compare quite favourably with experimental data available for actual soils, especially in the high saturation range. Having a sound scientific basis, the model can be made amenable to address a variety of soils with a wider range of particle sizes.  相似文献   

Dissolved organic matter in surface runoff in the Loess Plateau of China: The role of rainfall events and land-use     

Zhongwu Li  Hao Peng  Binggeng Xie  Chun Liu  Xiaodong Nie  Danyang Wang  Mei Huang  Haibing Xiao  Lin Shi  Xuqin Zhang  Jieyu Jiang 《水文研究》2020,34(6):1446-1459

Exploring the chemical characterization of dissolved organic matter (DOM) is important for understanding the fate of laterally transported organic matter in watersheds. We hypothesized that differences in water-extractable organic matter (WEOM) in soils of varying land uses and rainfall events may significantly affect the quality and the quantity of stream DOM. To test our hypotheses, characteristics of rainfall-runoff DOM and WEOM of source materials (topsoil from different land uses and gullies, as well as typical vegetation) were investigated at two adjacent catchments in the Loess Plateau of China, using ultraviolet–visible absorbance and excitation emission matrix fluorescence with parallel factor analysis (PARAFAC). Results indicated that land-use types may significantly affect the chemical composition of soil WEOM, including its aromaticity, molecular weight, and degree of humification. The PARAFAC analysis demonstrated that the soils and stream water were dominated by terrestrial/allochthonous humic-like substances and microbial transformable humic-like fluorophores. Shifts in the fluorescence properties of stream DOM suggested a pronounced change in the relative proportion of allochthonous versus autochthonous material under different rainfall patterns and land uses. For example, high proportions of forestland could provide more allochthonous DOM input. This study highlights the relevance of soils and hydrological dynamics on the composition and fluxes of DOM issuing from watersheds. The composition of DOM in soils was influenced by land-use type. Precipitation patterns influenced the proportion of terrestrial versus microbial origins of DOM in surface runoff. Contributions of allochthonous, terrestrially derived DOM inputs were highest from forested landscapes.  相似文献   

基于地性线分级的DEM信息量计算方法研究   总被引：1，自引：0，他引：1  

张萍  江文萍  邓晓龙  李伟 《测绘与空间地理信息》2016,(7)

主要对基于DEM提取的地性线进行信息量的定量分析,探讨地性线的信息量与分辨率、地形单元的关系。这个过程中首先利用河网的自相似理论研究与当前DEM所代表的地貌详细程度相适宜的地性线提取的阈值区间,并讨论此阈值下地性线的分级,以此为基础通过以该分级为权重进行DEM地形信息量的计算。实践证明,这种顾及地性线等级的DEM信息量计算方法能较准确地反映地性线的分布规律和不同等级的要素造成的信息量度量差异。  相似文献   

重庆市滑坡灾害时空特征分析     

蒲娉璠  吴健平 《测绘与空间地理信息》2016,(10):130-133

重庆市是滑坡灾害高发的城市,滑坡灾害每年都会造成大量的人员伤亡和经济损失。本文结合历年滑坡统计资料,基于GIS平台,分析重庆市滑坡灾害的时空分布特征。自1980年起,重庆发生滑坡的次数明显增加,且集中发生在5~9月,尤其是7月。80%以上的滑坡为降雨引发,其次是自然灾害和人类活动,人类活动诱发滑坡灾害增长速度最快。重庆滑坡密度大的地区为市区以及万州区、忠县等三峡库区核心地带,滑坡高发地区有东北向西南方向变化的趋势。  相似文献   

土壤样品镉同位素分析中Cd与Sn有效分离方法的改进     

段桂玲  段瑞春  谭娟娟  顾涛  邵长生  路韬 《岩矿测试》2016,35(1):10-16

保证Cd的高回收率以及彻底的Sn干扰去除是获得精确镉同位素组成的前提,目前报道的多种Cd分离与纯化方法获得的Cd回收率有较大差异(42.6%~99.8%),且去除Sn干扰的效果也不同(去除率在87.8%~97.4%之间),Cd回收率和Sn去除率均不理想。本文对前人报道的分离方法进行对比实验,发现0.1 mol/L氢溴酸-0.5 mol/L硝酸是分离Cd和Sn的有效试剂,增加该组混合酸的用量可淋洗出样品中更多的Sn且不会损失Cd,当混合酸的淋洗用量增加至30 mL时,Sn的淋洗率达到99.8%以上,Cd的回收率亦达到99.0%±0.5%,可满足土壤样品镉同位素的测定要求。本工作为获得高精度的镉同位素组成奠定了基础,为研究土壤环境中镉的污染来源提供了技术手段。  相似文献   

武威市初、终霜日气候特征   总被引：2，自引：0，他引：2  

丁文魁  杨晓玲  殷玉春  马玉山 《气象科技》2016,44(4):647-652

为了因地制宜,合理调整种植结构和布局,有效利用农业气候资源。利用1961—2014年武威市4个气象站点初、终霜日(最低地温≤0℃)观测资料,采用现代气候诊断分析方法,系统分析了该市年初、终霜日的时空变化特征。结果表明:受海拔高度、地形地势以及植被覆盖情况的影响,在空间分布上,武威市初霜日为山区早于荒漠区早于绿洲平原区,终霜日为山区晚于荒漠区晚于绿洲平原区,各地初、终霜日存在一定的异常性,正常初、终霜日均在60%左右,对农业生产造成危害的偏早和特早初霜日、偏晚和特晚终霜日的概率均在20%左右。在时间变化上,武威市初霜日呈显著推迟趋势,终霜日呈显著提早趋势,霜期呈显著缩短趋势,终霜日提早的幅度比初霜日推迟的幅度更大。初霜日和终霜日的时间序列均分别存在着8~10年和9~11年的准周期变化。初霜日在1998年发生了气候突变,终霜日在1996年发生了气候突变。  相似文献   

闽西北5月雨量特多年份环流特征及其成因分析     

章达华  张家斌  邝美清  沈永生  卜银军  吴姗 《气象科技》2016,44(1):61-66

利用闽西北三明市的11个县、市1961—2014年5月降雨量资料、常规气象观测资料和NCEP 2.5×2.5°再分析资料等对闽西北历史上5月雨量特多年的降雨量时空分布特征和大气环流特征及其成因进行了分析,结果表明:5月区域性、全区性雨量特多年的环流异常特征是500hPa欧亚中高纬度自西向东环流呈"+-+"的波列分布,鄂霍次克海北侧高度正距平区的稳定少动,起到阻挡冷空气东移的作用,冷空气沿乌拉尔山西侧高度正距平中心前的偏北气流不断南下,使萨彦岭一带高度负距平中心加强,其底部不断分裂小槽东移影响闽西北。925hPa华南北部维持一条稳定切变线;对于2014年5月特例的环流形势分析结果可知,500hPa东亚大槽明显偏东,引导冷空气南下与强大副高西北侧西南暖湿气流交绥在闽西北上空。925hPa闽西北处于气旋式辐合区内。北支槽、南支槽均非常活跃,东移影响闽西北,是导致该地5月区域性降雨量特多的主要原因。  相似文献   

华北陆块晋冀Al- Fe- Au- Pb- Zn- Ag- Cu- 煤成矿带主要地质成矿特征及潜力分析   总被引：1，自引：0，他引：1  

李俊建  党智财  付超  肖克炎  丁建华  赵泽霖  任树祥  侯占国  方同明  杨俊泉  李磊 《地质学报》2016,90(7):1482-1503

华北陆块晋冀成矿带是我国重要的金属和能源矿产资源基地,近年来新的找矿进展和预测成果不断涌现,使之成为我国重点找矿地区之一,需要对其开展系统的成矿区划和部署研究工作。本文以新的研究成果和找矿突破为基础,通过综合分析,在该地区划分新的重要成矿部署区带,厘定边界并将其命名为"华北陆块晋冀Al-Fe-Au-Pb-Zn-Ag-Cu-煤成矿带"。结合区域成矿地质背景的综合研究,在区内划分了10个成矿亚带,初步建立了Al-Fe-Au-Pb-Zn-Ag-Cu-煤成矿带成矿谱系,其成矿作用具有多期次发育和多系统控制的特点,在时间演化上表现为多旋回性、继承性、新生性和叠加性特点,主要成矿期有前寒武纪,寒武纪-晚二叠世,晚三叠世-晚白垩世和新生代,其中晚侏罗-早白垩世是内生金属矿床成矿大爆发期。该带产出的矿床类型复杂多样,与岩浆有关成矿作用有岩浆岩型、斑岩型、矽卡岩型、海(陆)相火山岩型、岩浆热液型和石英脉型,变质成矿作用有沉积变质型、绿岩建造型,层控成因矿床有碳酸盐岩中热液型,沉积成矿作用有海(陆)相沉积型、砂矿型、风化壳型矿床等。结合区域找矿进展和潜力评价最新成果,认为本区铝土矿、铁、金、锰、钼、铜、铅锌、煤矿潜力巨大,为下一步勘查部署的主攻矿种,同时在本区划分了26个重点远景区,对研究区下一步矿产勘查部署工作有一定指导意义。  相似文献