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551.
Classical turbulent K closure theory of the atmospheric boundary layer assumes that the vertical turbulent transport flux of any macroscopic quantity is equivalent to that quantity‘s vertical gradient transport flux. But a cross coupling between the thermodynamic processes and the dynamic processes in the atmospheric system is demonstrated based on the Curier-Prigogine principle of cross coupling of linear thermodynamics. The vertical turbulent transportation of energy and substance in the atmospheric boundary layer is related not only to their macroscopic gradient but also to the convergence and the di-vergence movement. The transportation of the convergence or divergence movement is important for the atmospheric boundary layer of the heterogeneous underlying surface and the convection boundary layer.Based on this, the turbulent transportation in the atmospheric boundary layer, the energy budget of the heterogeneous underlying surface and the convection boundary layer, and the boundary layer parameteri-zation of land surface processes over the heterogeneous underlying surface are studied. This research offers clues not only for establishing the atmospheric boundary layer theory about the heterogeneous underlying surface, but also for overcoming the difficulties encountered recently in the application of the atmospheric boundary layer theory.  相似文献   
552.
The High Himalayan Crystallines (HHC) of Bhutan were penetratively deformed, intruded by leucogranite and metamorphosed during the collision of the Indian and Asian plates. Metamorphic reaction textures in the HHC show that it experienced decompression while maintaining a laterally heterogeneous, and locally inverted, internal temperature range of c. 600–750  °C. This thermal structure was produced by thrusting hot, migmatitic rocks over lower-grade rocks within the HHC and by the advection of heat from the intrusion of leucogranite dykes and sills during decompression. A variable velocity field within the HHC during exhumation and extrusion between India and Tibet caused the inversion of top to the south sense of shear present throughout most of the HHC to top down to the north shear near its top.  相似文献   
553.
The average layered structure of the intracratonic Paraná Basin, SE Brazil, is investigated with surface-wave group velocities from a small regional earthquake recorded by two broadband stations. Rayleigh and Love waves in the period range 1–4.2 s are used to infer average properties down to about 4 km. Genetic algorithm techniques are used to find the best fitting 1-D S-wave model. The inverted 1-D models show fair correlation with the average properties of the propagation paths as expected from geology and borehole information. However, different S-wave velocity models are obtained for the different inversion parameterizations. Since lateral heterogeneities are expected along the paths, several synthetic tests are performed with heterogeneous propagation paths. For approximately homogenous path (i.e., little lateral variation), the main features of the average synthetic model can be retrieved for different model parameterizations. For strong lateral variations, however, the average dispersion curve can produce very different 1-D inverted models depending on the parameterization. Also, the 1-D inverted models may differ significantly from the average properties of the inhomogeneous path, and wrong depths to interfaces may be inferred. For real data inversions, it is then suggested that various different parameterizations should be tested. If the resulting models show consistent features, this probably indicates homogeneity in the propagation path. But, if very different and unstable features are obtained in the 1-D inversions, then strong lateral variation may be present in the propagation path, and the average 1-D model may not represent average properties along the path.  相似文献   
554.
Chloritized annite from the Irizar granite has been used for laser-heating experiments, following the procedures used for 40Ar–39Ar dating (heating steps in the 600–1080 °C temperature range). Four runs, at different temperatures, have been characterized using transmission electron microscopy, electron diffraction, micro-Raman and micro-IR spectroscopies. The water loss was evaluated by thermogravimetry. The chlorite domains break down first forming (001) amorphous layers, that later coalesce to rounded, equant inclusions and finally recrystallize to olivine and spinels plus silica glass. These phases occur within negative crystals hosted in ordered dehydrated annite, produced by dehydration and annealing of the starting annite. Dehydrated annite, olivine and spinels display topotactic relationships, determined by the common orientation of closely packed oxygen layers.  相似文献   
555.
This work presents the application of a Monte Carlo simulation method to perform an statistical analysis of transient variably saturated flow in an hypothetical random porous media. For each realization of the stochastic soil parameters entering as coefficients in Richards' flow equation, the pressure head and the flow field are computed using a mixed finite element procedure for the spatial discretization combined with a backward Euler and a modified Picard iteration in time. The hybridization of the mixed method provides a novel way for evaluating hydraulic conductivity on interelement boundaries. The proposed methodology can handle both large variability and fractal structure in the hydraulic parameters. The saturated conductivity K s and the shape parameter vg in the van Genuchten model are treated as stochastic fractal functions known as fractional Brownian motion (fBm) or fractional Gaussian noise (fGn). The statistical moments of the pressure head, water content, and flow components are obtained by averaging realizations of the fractal parameters in Monte Carlo fashion. A numerical example showing the application of the proposed methodology to characterize groundwater flow in highly heterogeneous soils is presented.  相似文献   
556.
An investigation of the influence of mineral dust ontrace gas cycles in the troposphere is carried out inthis study. A 3D regional scale atmospheric chemistrymodel (STEM-III) which includes aerosol processes isused for the numerical simulations for May 1987.Heterogeneous interactions between gaseous species(SO2, N2O5, HNO3, HO2andH2O2) and the dust particles are considered.Emissions of dust behind convective cold fronts aremodeled. The transport and distribution of mineraldust predicted from the model is compared withsatellite measurements (aerosol index from TOMS). Themodel is shown to capture the synoptic variability inthe observed aerosol index. Calculations show twomajor dust events in May 1987, during which thedust levels close to the source reach more than500 g/m3. The transport of dust is mostlyrestricted towards the north, with the net continentaloutflow of 6 Tg for the entire month. Results showthat the presence of mineral aerosol can greatlyimpact sulfate and nitrate distributions. Averagedover the month of May, the presence of dust isestimated to increase particulate sulfate and nitratelevels in east Asia by 40%. Furthermore, the sulfateand nitrate on the dust particles are predicted to beassociated with the coarse mode (3–5 m particlediameter), consistent with observations over Japan.The influence of mineral dust on the photochemicaloxidant cycle is also investigated. For the entiremonth, a5–10% decrease in boundary layer ozone ispredicted by the model closer to regions of higherdust levels. The ratio of nitric acid to NOx overmarine regions is reduced by a factor between 1 and 2in the boundary layer to more than 2 in the freetroposphere as a result of aerosol processes.  相似文献   
557.
Microstructural evidence commonly is used to infer metamorphic reactions, which are used to infer pressure–temperature–time ( P–T–t ) paths. However, this approach in low- P /high- T  (LPHT) granulite facies metamorphic terranes has two main problems. (1) Microstructural evidence may be inconclusive, so that reactions cannot be inferred with confidence. In particular, relative timing of mineral growth inferred from inclusions, moulding relationships and foliation–porphyroblast relationships is commonly ambiguous or invalid. The most reliable indicators of metamorphic reactions are partial pseudomorphs and corona structures, especially if symplectic intergrowths (indicating simultaneous growth of two or more minerals) are involved. (2) Even reactions that can be inferred with confidence do not indicate unique P–T  trends, owing to P–T  slopes of reaction curves. Where successive reactions can be shown to have occurred in the same rock, a line or curve joining reaction-curve intersections gives an apparent single-event path. However, isotopic evidence is needed to prove that polymetamorphism (involving more complex paths making fortuitous intersections with the apparent single-event path) did not occur. Although these problems are well known, their importance is not always emphasized in metamorphic investigations.
The difficulties are illustrated by published work on P–T–t paths for Proterozoic LPHT granulite facies rocks of central Australia and Antarctica. Recent work in Antarctica has shown that P–T–t paths may be episodic and more complex than the simple, single-event paths commonly inferred from microstructural evidence alone.  相似文献   
558.
559.
本文根据迄今为止对南极臭氧洞研究的成果,综述了南极臭氧洞形成的诸种原因。研究表明人类排放到大气中的污染物氟里昂,通过发生在极地平流层云表面上的非均相化学反应所分解出的活跃的氯基,经过光化学反应过程大量分解臭氧是出现南极臭氧洞的内部原因;太阳活动、大气长波辐射及大气环流造成南极平流层环极涡旋中出现的极地平流层云,可能是形成南极臭氧洞的外部条件。南极臭氧洞的闭合很可能是南半球春季逐渐增强的行星波活动往南极平流层输送的臭氧增多的结果。同时讨论了南极臭氧洞未来的可能趋势,估计南极臭氧洞可能会持续下去,并随着大气环流的波动,其程度和范围也会出现波动。  相似文献   
560.
Redox and nonredox reactions of magnetite and hematite in rocks   总被引:1,自引:0,他引:1  
Redox and nonredox reactions causing pseudomorphic replacement of hematite by magnetite and magnetite by hematite are compared.Pseudomorphic replacements resulting from redox reactions are known as martitization [replacement of magnetite by hematite due to oxidation; reaction (1)] and mushketovitization [replacement of hematite by magnetite due to reduction; reaction (2)]. These two replacements cause characteristic ore textures and volume changes (reaction (1): increase of 1.66%; reaction (2): decrease of 1.64%). These small volume changes are the reason that martitization and mushketovitization are widespread in many rocks under condition, however, that oxidizing or reducing fluids (solutions) are present.The same initial and end products may also be involved in nonredox reactions. Reaction (3) is the replacement of hematite by magnetite due to simple addition of Fe2+ atoms under basic conditions. This reaction causes an increase of the volume of 47.6%. Reaction (4), causing a volume decrease of 32.2%, is the replacement of magnetite by hematite due to leaching of Fe2+ atoms under acidic conditions. From these volume changes it is concluded that reaction (4) may occur in many rock types, whereas reaction (3) is restricted to unlithified sediments only. However, ore textures caused by nonredox reactions are unknown and therefore their occurrence in rocks is hypothetical.  相似文献   
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