Photochemistry of N2O4 Adsorbed on Ice Surfaces at 193 nm     

Akio Susa  Seiichiro Koda 《Journal of Atmospheric Chemistry》2003,45(2):197-217

A multi-layer deposited ice film was prepared through water vapor deposition on a Ni plate in a vacuum chamber at 90 K, and was used as it was or after annealing at 140 K. NO₂ was adsorbed as N₂O₄ approximately 90 K on the ice film prepared as above, and irradiated by 193 nm excimer laser light. The time-of-flight (TOF) spectra of the desorbed species, i.e., NO₂, NO, O₂ and O, were measured by a quadrupole mass spectrometer. The photochemical process obeyed an one-photon process. The relative yields of the products and their TOF spectra were dependent on the preparation condition of the ice film and also varied with the continuation of the laser irradiation. From the ice film annealed at 140 K, NO₂, NO and O₂ were desorbed with an approximate ratio of 1:1:0.01. From the non-annealed film, the relative yield of NO₂ was much smaller than that of NO. The TOF spectrum of NO from the non-annealed ice film consisted of distinctly different two components corresponding to the 1700 and 100 K translational temperature, respectively. The fast component was lost when additional ice was deposited on the adsorbed N₂O₄. NO was supposed to be a predissociation product from the electronically excited NO₂ prepared through the photodissociation of N₂O₄.  相似文献   

A Case Study of Satellite Synthetic Aperture Radar Signatures of Spatially Evolving Atmospheric Convection over the Western Atlantic Ocean     

Steven M. Babin  Todd D. Sikora  Nathaniel S. Winstead 《Boundary-Layer Meteorology》2003,106(3):527-546

A case study of a particularly intense cold air outbreak over the northAtlantic Ocean extending from the northeast coast of the UnitedStates to the Gulf Stream is described. A RADARSAT satellite synthetic apertureradar (SAR) image of this outbreak dramatically illustrates the spatialevolution of convection. Nearly coincident images from the National Oceanic and Atmospheric Administration's Advanced Very HighResolution Radiometer are used to compare many interesting features.In addition, National Weather Service rawinsonde data, National Data Buoy Center buoy data, and Woods Hole Oceanographic Institute Coastal Mixing and Optics mooring data arepresented. We use these data to help describe the spatial evolution of the atmospheric boundary-layer processes involved in this outbreak.Rows of cellular convective clouds begin to appear some distance offshore and then slowly increase in horizontal diameter and wavelength in the downwind direction, with a subsequent jump in cloud diameter downwind of the Gulf Stream North Wall (GSNW). The SAR image shows a similar evolution of sea-surface footprints of these boundary-layer features. This change in boundary-layer structure is attributed to corresponding changes in static stability. About 300 km south of the GSNW in the SAR image, an even larger jump in cell diameter appears and the cells becomenon-uniform with bright crescents and filled semi-circles on thedownwind sides of the cells. These are believed to be surface effectsof gust fronts induced by the mesoscale cellular convection and enhanced by the overall northwesterly flow.  相似文献   

卫星云图、雷达回波在人工增雨时机选择中的应用   总被引：7，自引：2，他引：7       下载免费PDF全文

张晰莹  金风岭 《气象》2003,29(8):52-54

概述了干旱期间选择飞机和高炮人工增雨作业时机的方法，以2000年6～7月哈尔滨地区特大干旱期间进行的飞机和高炮人工增雨作业为例，利用卫星云图和雷达回波资料选择的作业时间和作业区域应是比较有利的。因为从卫星云图中的水汽图、红外和可见光云图上可分析出云系中的含水量、云顶温度、云系强度，在此基础上利用天气雷达跟踪订正，可直接指挥飞机和高炮在有利的区域和时间内进行作业，获得了明显的效果。  相似文献   

用机载多普勒雷达资料进行三维风场解析反演 II. 多重解析多普勒方法应用于在CaPE现场实验中获取的机载雷达实测资料          下载免费PDF全文

窦贤康  G. Scialom  Y. Lemaitre 《大气科学》1997,21(4):426-436

模拟结果证明，在机载雷达的技术参数下，多重解析多普勒（MANDOP）方法能够提供误差可以接受的三维风场反演。 1991年夏在美国的佛罗里达州举行的CaPE现场实验中首次应用了机载双束多普勒雷达，并获取了珍贵的雷达实测资料。用MANDOP方法分析1991年8月9日观测到的一个飑线，取得类似于以往用地基雷达资料得到飑线内部大气环流结构。另外，机载雷达资料与 地基雷达资料联合反演的结果与纯粹用机载雷达资料反演的结果之间很好的相关性证明了机载雷达资料的可靠性。  相似文献   

一次暴雨过程多普勒天气雷达风场资料分析   总被引：1，自引：2，他引：1       下载免费PDF全文

俞莲芬  陈大任  张代平 《气象》1997,23(2):25-28

通过对１９９御７月１４日的大－暴雨天气过程所获取的３８２４多普勒天气雷达平均径向风场资料的分析，发现边界层急流与较强的降水相伴。表明多普勒天气雷达对中小尺度天气系统和灾害性天气预报有预警作用。  相似文献   

用光盘转录航空物探数据     

戚巧俊  雍卫华 《物探与化探》1997,21(3):225-227

航空物探数据具有较高的保存开发价值,由于磁带保存的有效年限较短,航空物探勘查所获资料存在着丢失的危险。航空物探数据光盘转录将解决这些难题,为航空物探资料的二次开发和利用创造条件。本光盘数据从任一与RICOHRS-5060E型光盘机兼容的光盘机上均可读出。  相似文献   

激光探针质谱及单颗粒矿物^40Ar／^39Ar法年龄的测定     

蒲志平  许景荣  邱华宁  张永良  胡世玲 《岩矿测试》1997,16(1):1-6

将掺钕的钇铝榴石（Ｎｄ：ＹＡＧ）激光器与高精密ＭＭ１２００质谱计、电子倍增器联网，应用连续激光质谱对单颗粒矿物、光片样品进行微区４０Ａｒ／３９Ａｒ测年、坪年龄和等时线年龄研究。在光片上测定南极乔治王岛北海岸玄武岩等时线年龄（５２．３８±１．０５）Ｍａ和贵州绿豆岩年龄（２３９．１６±１４．１３）Ｍａ，两者与实际地质背景吻合。对两个中生代和太古代单颗粒黑云母进行连续激光质谱阶段升温４０Ａｒ／３９Ａｒ坪年龄谱测定，获得与常规法相一致的坪年龄谱  相似文献   

天山地区SAR数据雪盖制图研究   总被引：1，自引：2，他引：1  

李震  曾群柱 《冰川冻土》1996,18(4):366-372

在分析合成孔径雷达（ＳＡＲ）成像机理及雪盖参数散射特性的基础上，利用航天飞机搭载的成像雷达（ＳＩＲ－Ｃ）获取的天山Ｃ波段、多极化ＳＡＲ数据，进行提取雪盖信息的实验。数据通过预处理、散射系数图像的计算、去噪、入射角改正等处理后，利用ＢＡＹＥＳ监督分类方法产生该地区的雪盖分类图。实验结果表明，利用多波段、多极化ＳＡＲ进行雪盖制图是可行的。  相似文献   

吐哈盆地及二连盆地侏罗系煤微类脂组分的共聚焦激光扫描显微镜（CLSM）研究及油气意义   总被引：7，自引：1，他引：7  

刘德汉  孙永革  申家贵  傅家谟  盛国英  王昌桂  龙道江 《地球化学》1996,(4)

吐哈盆地产出有比较丰富的侏罗系煤成油气田，本文用共聚焦激光扫描显微镜和热解分析等手段研究了煤中类脂组及微类脂组的类型、含量、分布与煤成烃性能和产出的关系。观察分析结果表明：在一般煤岩组分观测中主要含煤的西山窑组和八道湾组煤层类脂组含量很少超过１０％，但是一些煤样的热解分析中Ｓ＿１可高达５－２３ｍｇ／ｇ，Ｓ＿２可达１５０─２００ｍｇ／ｇ，ＨＩ（烃／有机碳）可高达１５０─３５０ｍｇ／ｇ生烃、含烃性能较好。进一步用共聚焦激光显微镜观测结果表明：本区一些薄层状、条带状煤层的基质镜质体和叶结构镜质体中微类脂组含量比较丰富，微区定量统计含量在３％─１８％左右。这种富含微类脂组的基质镜质体和结构镜质体在煤成油气中有重要意义，而且由于多数微类脂体在煤中常成点线状、似层状、充填状、网络状分布，可能有利于煤成油气的运移和聚集。  相似文献   

探地雷达地下界面成像   总被引：3，自引：1，他引：3  

肖兵  宋守根  何继善 《物探与化探》1996,20(4):304-308

由Maxwell方程,根据雷达波在介质中的高频传播特性,导出雷达波满足的波动方程。由此求出波速扰动量的成像公式,利用小波变换分析下界面的奇异性,从而达到雷达信号地下界面成像的目的。  相似文献