饱和软土压缩曲线的“反常”现象     

冯铭璋  王兴涛 《上海国土资源》1990,(3):30-37

饱和软土压缩试验时,经常出现压缩曲线“反常”、压缩系数“倒大”的现象。它是土的原始结构发生破坏前后的不同压缩性的客观反映。饱和软土的结构力很微弱,唯质量好的原状土才能见到这种“反常”。应从成孔、取样、测试及资料整理等多个环节保证其工程意义。  相似文献   

Periodicities in natural remanent magnetization and palaeoclimatic records detected by walsh spectra     

J. G. Negi  R. K. Tiwari 《Pure and Applied Geophysics》1990,132(4):757-769

The time series consisting of nonsinusoidal Natural Remanent Magnetization (NRM) and palaeoclimatic variations for the past two million years have been spectrally examined by using a new Walsh transform technique. The results show statistically significant periodicities (at 95% confidence level) of approximately 92,000 years; 43,000 years and 21,000 years in the ensemble spectra of the NRM intensity (mineralogic) variations. These NRM periodicities are remarkably close to the well-known Milankovitch cycles. The ensemble spectra of palaeoclimatic records reveal only 41,000 years statistically significant (95%) periodicity corresponding to the obliquity cycle. The study suggests that NRM variations in deep sea sediments probably are more sensitive recorders of palaeoclimatic memory than the oxygen isotope variations.  相似文献   

Natural siliceous dust and human health： Pathways, toxicity, and impact     

Edward Derbyshire 《中国地球化学学报》2006,25(B08):219-219

Fine atmospheric dust includes mineral particles and aggregates, fibrous minerals and fibrous organic material. Generation, dislodgement and transport （deflation） of natural dust with the finer （〈4 microns） components suspended as silt-size aggregates, is widespread in and adjacent to the world＇s drylands, as well as deriving from volcanic vents. Silica is a highly fibrogenic agent in lung tissue. Long-term inhaling of siliceous dusts can lead to a number of fibrotic lung diseases, including natural （non-occupational） pneumoconioses （notably silicosis, but including asbestosis and others）. Different polymorphs of silica show different levels of toxicity in interaction with lung tissue. Particles with highly active surfaces may release radicals, causing cell damage. Some types of inhaled particulates are degraded by macrophages, but many are highly resistant and persist in the lungs, some stimulating fibroblastic cells to deposit collagen. Silicosis is an inflammation of the lung commonly caused by silicate mineral particles, leading to fibrosis. Three types are recognized： nodular pulmonary fibrosis （simple or chronic silicosis）, acute silicosis, and accelerated silicosis. Generally, finer particulates have greater oxidative capacity than the coarser fractions. They contain more reactive oxygen species, their greater bioreactivity making them more toxic to pulmonary tissue. Nevertheless, inhalation of large dust particles （〉 10μm） may constitute a health risk if the mineralogy is toxic, regardless of where the grains lodge in the respiratory system. Dust may absorb harmful gases, disease-generating bacteria and carcinogenic hydrocarbon compounds. Silica-related respiratory disease may also an exacerbate cardiac problem, and epidemiology suggests a link with tuberculosis. Quantification of dust loading and exposure requires study of spatial and temporal patterns, supported by meteorological analysis, airflow modeling and satellite-borne imagery. Some acute, short-term health impacts have been assessed using atmospheric and health records both before and after a dust storm or by comparison of populations within and outside such events. Analysis of the size, shape, mineralogy and geochemistry of ambient dust particulates provides information on natural dust sources, dust concentrations, and potential particulate toxicity, as well as providing a datum for assessment of human exposure levels.  相似文献   

Total gaseous mercury emissions from mercury-enriched soil in Guizhou, China     

Xinbin FENG Shaofeng WANG Guangle QIU Yamin HOU Shunlin TANG 《中国地球化学学报》2006,25(B08):243-244

Guizhou is located in the Circum-Pacific Global Mercuriferous Belt, and mercury concentrations in soil in this area are enriched. In-situ total gaseous mercury （TGM） exchange fluxes between air and soil surface were intensively measured at four sampling sites in Guiyang from 21 May to 16 June, 2003, and five sites in the Lanmuchang mercury mining area in December 2002 and May 2003, respectively. The in-situ Hg flux measurement was conducted with a dynamic flux chamber （DFC） of quartz. Overall, net emissions were obtained from all sampling sites. Soil mercury concentration and solar radiation have been proved to be the two most important parameters to control mercury emissions from soil. Meanwhile, rain events can enhance mercury emission rate significantly.  相似文献   

Heavy metals in freshly deposited sediments of the river Subernarekha, India: an example of lithogenic and anthropogenic effects   总被引：1，自引：0，他引：1  

A. K. Upadhyay  K. K. Gupta  J. K. Sircar  M. K. Deb  G. L. Mundhara 《Environmental Geology》2006,50(3):397-403

Heavy metal distribution patterns in river sediments aid in understanding the exogenic cycling of elements as well as in assessing the effect of anthropogenic influences. In India, the Subernarekha river flows over the Precambrian terrain of the Singhbhum craton in eastern India. The rocks are of an iron ore series and the primary rock types are schist and quartzite. One main tributary, the Kharkhai, flows through granite rocks and subsequently flows through the schist and quartzite layers. The Subernarekha flows through the East Singhbhum district, which is one of India’s industrialised areas known for ore mining, steel production, power generation, cement production and other related activities. Freshly deposited river sediments were collected upstream and downstream the industrial zone. Samples were collected from four locations and analysed in <63-μm sediment fraction for heavy metals including Zn, Pb, Cd and Cu by anodic stripping voltammetry. Enrichment of these elements over and above the local natural concentration level has been calculated and reported. Sediments of the present study are classified by Muller’s geo-accumulation index (I _geo) and vary from element to element and with climatic seasons. During pre-monsoon period the maximum I _geo value for Zn is moderately to highly polluted and for Cu and Pb is moderately polluted, respectively, based on the Muller’s standard. Anthropogenic, lithogenic or cumulative effects of both components are the main reasons for such variations in I _geo values. The basic igneous rock layer through which the river flows or a seasonal rivulet that joins with the main river may be the primary source for lithogenic components.  相似文献   

The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt   总被引：4，自引：0，他引：4  

J. Sánchez España  E. López Pamo  E. Santofimia Pastor  J. Reyes Andrés  J. A. Martín Rubí 《Aquatic Geochemistry》2006,12(3):269-298

This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD) waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO₄⁼) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5 (stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO₄⁼ anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous free cations (Pb²⁺, Zn²⁺, Cu²⁺, Cd²⁺, Mn²⁺, Co²⁺, Ni²⁺) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10⁻¹) of the SO ₄⁼ ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH < 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co, Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB.  相似文献   

土壤天然热释光测量在寻找滑坡体边界中的应用研究   总被引：1，自引：1，他引：1  

张丽娇  叶树林  刘庆成 《工程地质学报》2006,14(6):815-818

土壤天然热释光测量方法是一种累积型测氡方法。由于累积测氡时间长,其灵敏度和异常的重现性远比一般累积测氡及其子体方法好,因此,在地质领域得到了广泛的应用。在寻找滑坡体边界的应用中,取得的测量效果明显,表明该方法经济有效。  相似文献   

土壤天然热释光法在相山火山岩型铀矿床中的应用   总被引：1，自引：0，他引：1  

许军才  黄临平  刘庆成  董业才  魏海  龙期华 《物探与化探》2005,29(3):224-226

介绍了天然热释光法在火山岩铀矿床上的应用效果,表明矿体上方热释光异常较大,无矿区域异常较小,矿体的分布范围与高值异常范围一致,还发现在一些构造薄弱带,裂隙、断层处出现大的异常,试验证明土壤天然热释光测量可以为评价火山岩铀资源提供线索。  相似文献   

西北地区的自然环境类型   总被引：3，自引：0，他引：3  

何芳  李英  徐友宁  张江华  陈社斌 《西北地质》2005,38(3):93-99

自然环境区划是国土规划的重要基础，是自然环境综合特征的基本反映.以西北地区的气候分区、地貌分区、植被分区（生态分区）为基础，将西北地区的自然环境类型划分为5个自然分区：阿尔泰-准噶尔区，塔克拉玛干-毛乌素沙漠区，青藏高原东北缘区，黄土高原区，秦巴山地与汉水谷地区.这5个区有完全不同的自然环境特征和资源优势特征，因而开发对策和环境对策是不同的，应予以分别对待.正确认识各区的自然环境特征，才能实现西北地区社会经济及环境的可持续发展。  相似文献   

磷灰石结晶法降低天然水体中磷浓度Ⅰ.不同反应物对降磷效果的影响     

胡明月  黄怀曾 《岩矿测试》2005,24(4):249-253

利用矿物磷灰石低溶度积特征,以晶体磷灰石作晶胞,引入氟、钙等离子,诱使水中溶解性磷酸盐在磷灰石晶体上沉淀、结晶,使水溶液中磷浓度明显降低。探讨了钙、磷灰石、氟、氯的加入对降磷效果的影响,初步分析了生成产物的结构。实验溶液中磷初始浓度约为5 mg/L,经磷灰石结晶后,最低可降至10μg/L以下,除磷效率可达99%以上。  相似文献