平流层爆发性增温过程中臭氧的垂直分布特征     

邓淑梅  陈月娟  罗涛 《大气科学》2009,33(3):459-467

利用ECMWF资料分析了平流层爆发性增温 (SSW) 过程中臭氧体积混合比的垂直分布的变化, 结果表明: 平流层爆发性增温过程中臭氧体积混合比增大, 而其极大值大多数形成在增温盛期。同时臭氧体积混合比的高值区在爆发性增温过程中随高度发生一定的变化, 据此对其变化分为两类: (1) 下传型: 在增温初期臭氧体积混合的高值区随高度下传至一定高度, 在增温盛期形成极大值然后随高度抬升到大致增温前的高度。 (2) 增厚型: 在增温过程中臭氧体积混合比的高值区厚度增加, 同时附近区域的臭氧体积混合比也增大, 而且在增温前臭氧体积混合比高值区在高度上没有多大变化, 增温开始后有所抬升。平流层爆发性增温过程中臭氧高值区随高度变化的这两种类型, 是由于平流层爆发性增温期间剩余环流对臭氧输送的结果。臭氧变化的下传型是由于在爆发性增温前剩余环流存在着中纬度向极地的明显输送, 并且伴随着极地强烈的下沉运动, 这就使得中纬度输送来的臭氧向下输送, 因此出现了臭氧高值区的下传; 而臭氧变化的增厚型是由于在爆发性增温期间剩余环流不但有中纬度向极地的输送, 而且在极地附近5 hPa高度处出现了上下两支输送气流, 向上的输送气流使中纬度输送来的臭氧向上输送, 而向下的输送气流使中纬度输送来的臭氧向下输送, 进而使增温期间极地附近的臭氧的高值区增厚。同时分析还表明: 平流层爆发性增温过程中中纬度臭氧体积混合比减少。  相似文献   

利用卫星资料分析我国北方东西部臭氧分布差异   总被引：2，自引：0，他引：2       下载免费PDF全文

杨景梅  邱金桓 《应用气象学报》2009,20(1):1-7

利用SAGE Ⅱ和HALOE臭氧垂直分布资料和TOMS臭氧总量资料, 研究我国北方(45°~55°N和35°~45°N范围), 东部(105°~135°E) 和西部(75°~105°E) 大气臭氧总量和垂直分布特征和差异。结果表明:我国北方东部冬季、春季和秋季臭氧总量明显大于西部, 主要表现在平流层臭氧极大值附近及其以下高度臭氧含量东部比西部明显偏大, 这种差异在冬、春季尤为明显; 随着纬度的降低, 冬季和秋季臭氧总量东、西部差异减小, 但春季臭氧总量东、西部差异没有明显改变; 夏季, 在45°~55°N范围, 东、西部臭氧分布没有明显差异, 但在35°~45°N范围, 臭氧分布东、西部差异较明显, 臭氧总量东、西部差异达到20.6 DU, 16 km以下臭氧柱总量东、西部差异达到12.8 DU。该文还对导致我国东、西部臭氧分布差异的原因进行了分析。  相似文献   

蒙特卡罗不确定性分析在O3模拟中的初步应用     

唐晓  王自发  朱江  吴其重  GBAGUIDI Alex 《气候与环境研究》2010,15(5):541-550

利用蒙特卡罗不确定性分析方法,分析了嵌套网格空气质量模式系统(NAQPMS/IAP)中154个模式输入变量不确定性对臭氧模拟的影响,量化了模式在北京奥运会期间臭氧模拟的不确定性,并确定出了主要不确定性因子。结果表明:(1)在奥运会期间(2008年8月8日～2008年8月24日),北京城区臭氧模拟的平均不确定性为19ppb,不确定性存在明显的日变化特征,白天不确定性大,夜间不确定性小。(2)在白天,北京城区近地层臭氧模拟最重要的不确定性来源是局地前体物排放,其次是NO2光解系数、风向、北京周边前体物排放和垂直扩散系数。另外,地面约150m以上,对臭氧模拟影响最大的不确定性因子是风向和北京周边前体物排放;夜间,北京城区近地层臭氧模拟的最大不确定性来源是局地NOx排放和垂直扩散系数。  相似文献   

北京奥运会期间CBM-Z化学机制的模拟应用   总被引：1，自引：0，他引：1  

向伟玲  安俊岭  王自发  吴其重  唐晓 《气候与环境研究》2010,15(5):551-559

利用CBM-Z化学机制模拟了中国科学院大气物理研究所气象塔站在北京奥运会期间高臭氧时段O3浓度的日变化,评估了气象条件、北京奥运会加强控制措施以及O3前体物浓度对近地面O3生成的影响。结果表明:(1)CBM-Z化学机制较好地模拟了北京奥运会期间典型时段气象塔站O3、NO、NO2日变化特征。(2)有利于局地高臭氧事件发生的气象条件非常相似;北京奥运会加强控制措施的实施显著减少了NOx及VOCs的排放量,导致近地面O3浓度的明显下降。(3)奥运会期间VOCs和CO是影响气象塔站O3生成量的关键因素。  相似文献   

地面臭氧的变化规律和计算方法的初步研究Ⅱ.可见光波段   总被引：7，自引：0，他引：7  

白建辉  王庚辰  陈辉  徐永福  石立庆  黄忠良  孔国辉  孟泽 《气候与环境研究》2002,7(3):311-320

通过对广州鼎湖山近地面O3、NOx、太阳辐射,气象参数等项目的观测和理论分析,研究了地面O3与NOx等微量气体及太阳可见光辐射的变化规律,详细讨论了可见光波段、不同天气条件地面O3与NOx、光化学反应、气溶胶、可见光辐射等之间复杂的关系.提出以光能量传输与守恒的观点来考虑大气中与可见光辐射有关的主要过程,并以此来研究大气光化学过程中所遵循的能量规律,建立了一个简单、实用、省时的统计模式,用于计算地面O3浓度.结果表明:不同情况下,计算值与观测值吻合得均比较一致.  相似文献   

1979～2020年北极和青藏高原臭氧低值区的动力输送特征比较     

王启璐  徐雯雯  涂静怡  于淑洋  饶建  郭栋 《大气科学》2023,(3):866-880

基于ERA5月平均再分析资料,利用Lorenz环流分解方法从定常和瞬变以及基流和涡旋的角度对比了北极与青藏高原臭氧低值区的动力输送特征。结果表明：动力总输送在两地上平流层作用最强,均使其臭氧浓度降低,且定常输送均强于瞬变输送,纬向与经向输送的作用均大致相反。然而,动力输送在北极地区的作用强度远大于青藏高原地区。北极地区纬向输送使得平流层中上层臭氧浓度降低,平流层下层臭氧浓度升高,经向输送的作用与之相反且强度明显偏弱,二者均主要作用于上平流层。青藏高原地区纬向和经向输送除在上平流层均使得臭氧浓度降低外,二者作用大致相反且强度相当,输送大值区在垂直方向上存在双中心结构,分别位于上平流层与上对流层—下平流层（Upper Troposphere–Lower Stratosphere,简称UTLS）区。两地区纬向和经向输送的差异均主要由定常涡旋输送所造成。青藏高原地区定常与瞬变输送的强度差异没有北极地区大。此外,两地定常和瞬变输送中涡旋对臭氧纬向平均的输送均起到主要作用,体现出涡旋输送在两地臭氧浓度变化的动力输送过程中发挥着至关重要的作用。  相似文献   

Climatology of Ozone, PAN, CO, and NMHC in the Free Troposphere Over the Southern North Atlantic   总被引：1，自引：0，他引：1  

Rainer Schmitt  Andreas Volz-Thomas 《Journal of Atmospheric Chemistry》1997,28(1-3):245-262

Free tropospheric measurements of ozone, peroxyacetylnitrate andprecursors (CO, NMHC) that were made within the framework of the EUROTRACsub-project TOR (Tropospheric Ozone Research) between 1990 and 1995 at theGAW station Izana, Tenerife (28°18N, 16°30W) arediscussed. The average annual cycles reveal the importance of transport fromnorthern mid-latitudes and the role of photo-chemistry. According toair-mass trajectories, which were supplied to us from AEROCE(Atmosphere/Ocean Chemistry Experiment), transport from northernmid-latitudes is associated with high precursor concentrations in winter,whereas ozone concentrations in winter are not much influenced by transportpatterns, suggesting a rather uniform distribution over the northern part ofthe Northern Hemisphere around mean value of 43 ± 5 ppb. In summer,high ozone concentrations of up to 90 ppb are often encountered duringtransport from north, while the levels of precursors are much lower than inwinter, because of photochemical destruction. Trajectories from southerlylatitudes and the Sahara usually have the lowest ozone concentrationsassociated with them.  相似文献   

From highly polluted inland city of China to “Lanzhou Blue”: The air-pollution characteristics     

SuPing Zhao  Ye Yu  DaHe Qin 《寒旱区科学》2018,10(1):12-26

Air quality was improved considerably and the so-called "Lanzhou Blue" appeared frequently in Lanzhou due to implementation of some strict emission-control measures in recent years. To better understand whether the concentration of each air pollutant had decreased significantly and then give some suggestions as to urban air-quality improvement in the near future, the variations of the Air Quality Index (AQI) and six criterion air pollutants (PM_2.5, PM₁₀, CO, SO₂, NO₂, and O₃) at five state-controlled monitoring sites of Lanzhou were studied from 2013 to 2016. The AQI, PM_2.5, PM₁₀, and SO₂ gradually decreased from 2013 to 2016, while CO and NO₂ concentrations had slightly increasing trends, especially in urban areas, due to the large number of motor vehicles, which had an annual growth rate of 30.87%. The variations of the air pollutants in the no-domestic-heating season were more significant than those in the domestic-heating season. The increase of ozone concentration for the domestic-heating season at a background station was the most significant among the five monitoring sites. The vehicle-exhaust and ozone pollution was increasingly severe with the rapid increase in the number of motor vehicles. The particulate-matter pollution became slight in the formerly highly polluted Lanzhou City. Some synergetic measures in urban and rural areas of Lanzhou should be taken by the local government in the near future to control fine particulate-matter (PM_2.5) and ozone pollution.  相似文献   

基于定量化植物防御效应的臭氧通量模型的优化     

印晓飞  郑有飞  徐振亚  周琦  韩湘云 《南京气象学院学报》2018,10(4):480-485

继SUM06、AOT40之后,基于气孔臭氧累计吸收通量（AFstY）的研究方法被广泛应用于臭氧风险评估中.然而通量模型中的阈值Y并不能很好地代表植物对臭氧的抗氧化能力以及自我修复能力,如何动态模拟植物自身的防御机制对于提高臭氧风险评估的准确性尤为重要.本文基于前人的研究成果探讨如何定量化植物对臭氧的防御效应,运用光合定量方法动态模拟伤害阈值并计算臭氧有效吸收通量,运用SODA模型从气孔吸收和质外体解毒两个方面探讨细胞内抗坏血酸对臭氧原生质膜通量的影响,旨在为臭氧通量模型研究开辟一个新的视角,并为后续的臭氧胁迫效应研究打下基础.  相似文献   

Impact of Taihu Lake on City Ozone in the Yangtze River Delta     

Liang ZHANG  Bin ZHU  Jinhui GAO  Hanqing KANG 《大气科学进展》2017,34(2):226-234

The lake-breeze at Taihu Lake generates a different specific heat capacity between the water body and the surrounding land. Taihu Lake has a significant impact on the atmospheric conditions and the air quality in the Yangtze River Delta. This phenomenon is referred to as the Taihu Lake effect. In this study, two simulations were conducted to determine the impact of the Taihu Lake effect in the reference experiment(R-E) and sensitivity experiments(NO TH). The control simulations demonstrated that the meteorological field and the spatial distribution of ozone(O3) concentrations over Taihu lake obviously changed once the land-use type of water body was substituted by cropland. The surface temperature of Taihu Lake was reduced under the impact of Taihu Lake, and a huge temperature difference caused a strong lake-breeze effect. The results also showed that the difference in the average concentrations of O3 between the R-E and NO TH experiments reached 12 ppbv in most areas of Taihu Lake, all day, on 20 May 2014. During daytime(0800–1600 LST, LST=UTC+8), the influence of the Taihu Lake effect on O3 in the Suzhou region was not significant. However, the influence of the Taihu Lake effect on O3 in the Suzhou region was obvious during nighttime(1800–2400 LST). The larger changes in the physical and chemical processes were horizontal and vertical advections under the influence of the Taihu Lake effect in Taihu Lake.  相似文献